Polymer composites and fabrications thereof

Patent metadata

Field	Value
Publication number	US-9976011-B2
Application number	US-201113183221-A
Country	US
Kind code	B2
Filing date	Jul 14, 2011
Priority date	Jul 14, 2010
Publication date	May 22, 2018
Grant date	May 22, 2018

Abstract

The present invention provides polymer composites reinforced with high aspect ratio reinforcing fillers selected from calcium phosphate nanofibers, nanoplates, submicron fibers, submicron plates, and combinations thereof. The mechanical and biological properties of the inventive composites are enhanced significantly over current polymer composites and may be employed in various biomedical applications, such as dental restorations.

First claim

What is claimed is:

1. A polymer composite, comprising: a polymer matrix and a reinforcing filler wherein the reinforcing filler comprises calcium phosphate nanofibers, submicron fibers, or combinations thereof, wherein the reinforcing filler has a gelatin coated surface comprising amine moieties, carboxylic acid moieties, or combinations thereof, and wherein the reinforcing filler has a diameter or thickness ranging between about 10 nm and about 1 μm and an aspect ratio ranging between about 50 and about 5,000 and is present in an amount ranging from about 0.6 wt. % to about 15 wt. %.

2. The polymer composite of claim 1 , wherein the amine moieties, carboxylic acid moieties, or combinations thereof on the gelatin coated surface are modified with a reagent selected from the group consisting of alkyls, amines, carboxylic acids, peroxides, and silanes.

3. The polymer composite of claim 1 , wherein the reinforcing filler is present in an amount ranging from about 0.6 wt. % to about 6 wt. %.

4. The polymer composite of claim 1 , wherein the reinforcing filler is bundled.

5. The polymer composite of claim 1 , wherein the diameter or thickness of the reinforcing filler is between about 50 nm and about 500 nm.

6. The polymer composite of claim 1 , wherein the aspect ratio is between about 100 and about 500.

7. The polymer composite of claim 1 , wherein the polymer matrix comprises a mixture of bisphenol A glycidyl methacrylate and triethylene glycol dimethacrylate.

8. The polymer composite of claim 1 , wherein the polymer matrix comprises poly(L-lactide).

9. The polymer composite of claim 4 , wherein the bundles have a diameter less than about 5 μm.

10. The polymer composite of claim 4 , wherein the bundles have a diameter less than about 2 μm.

11. The polymer composite of claim 1 , wherein the polymer composite further comprises an additional filler selected from the group consisting of calcium phosphates, strontium glass, barium glass, quartz, borosilicate glass, ceramics, silica, silicon nitride, silicon carbide, zirconia, medical grade ceramics, poly(L-lactide), poly(e-caprolactone), poly(lactide-co-glycolide), chitosan, cellulose, collagen, gelatin, and mixtures thereof.

Assignees

• Li Hao
• Yu Qingson
• Chen Liang
• Chen Meng
• Univ Missouri

Inventors

• Li Hao
• Yu Qingson
• Chen Liang
• Chen Meng

Classifications

• C08K2201/016

  Additives defined by their aspect ratio · CPC title

• C08K9/04

  Ingredients treated with organic substances {(treated with macromolecular compounds C08K9/08)} · CPC title

• C08K2201/011

  Nanostructured additives · CPC title

• A61L27/46 Primary

  with phosphorus-containing inorganic fillers · CPC title

• C08K7/08 Primary

  Oxygen-containing compounds · CPC title