Paper laminates made from decor paper having improved optical performance comprising treated inorganic particles

Patent metadata

Field	Value
Publication number	US-9975318-B2
Application number	US-201314372542-A
Country	US
Kind code	B2
Filing date	Jan 9, 2013
Priority date	Jan 16, 2012
Publication date	May 22, 2018
Grant date	May 22, 2018

Abstract

The disclosure provides a paper laminate comprising a décor paper prepared from a dispersion having improved optical performance without negatively impacting mechanical strength, wherein the dispersion comprises a TiO 2 particle slurry comprising a treated TiO 2 particle having a surface area of at least about 30 m 2 /g, and a cationic polymer; wherein the treatment comprises an oxide of silicon, aluminum, phosphorus or mixtures thereof; and the treatment is present in the amount of at least 15% based on the total weight of the treated titanium dioxide particle; paper pulp; and a cationic polymer; wherein the cationic polymer in the slurry and the cationic polymer in the dispersion are compatible; wherein for equal optical performance, the amount of treated TiO 2 particle in the dispersion is reduced by about 10% when compared to a dispersion not comprising the treated TiO 2 particle of (a).

First claim

What is claimed is:

1. A paper laminate comprising a décor paper prepared from a dispersion having improved optical performance without negatively impacting mechanical strength, wherein the dispersion is made by a process comprising:
(1) first contacting a treated TiO 2 particle having a surface area of at least about 30 m 2 /g, and a cationic polymer to form a cationized TiO 2 particle slurry (a); wherein the treatment comprises an oxide of silicon, aluminum, or mixtures thereof; and the treatment is present in the amount of at least 15% based on the total weight of the treated titanium dioxide particle; and
(2) subsequently contacting the cationized TiO 2 particle slurry with (b) paper pulp; and (c) a cationic polymer;

wherein the cationic polymer in the slurry (a) and the cationic polymer in the dispersion (c) are compatible; wherein for equal optical performance, the amount of treated TiO 2 particle in the dispersion is reduced by about 10% when compared to a dispersion not comprising the treated TiO 2 particle of (a).

2. The paper laminate of claim 1 wherein the TiO 2 particle is a pigment.

3. The paper laminate of claim 1 wherein the cationic polymer in the slurry is a urea-formaldehyde resin, a melamine-formaldehyde resin, a cationic polyacrylamide polymer, a polydialkyllammonium polymer, a polyamide-polydialkylammonium polymer, or a polyimide-polyamine-epichlorhydrin resin.

4. The paper laminate of claim 1 wherein the cationic polymer (c) in the paper laminate is a urea-formaldehyde resin, a melamine-formaldehyde resin or a polyimide-polyamine-epichlorhydrin resin.

5. The paper laminate of claim 1 wherein the silica treatment level is at least about 6% by weight, based on the total weight of the treated TiO 2 particle.

6. The paper laminate of claim 1 wherein the alumina treatment level is about 4 to about 8%, based on the total weight of the treated TiO 2 particle.

7. The paper laminate of claim 1 wherein the TiO 2 particle has a particle size of about 0.02 to about 0.95 microns.

8. The paper laminate of claim 1 wherein the TiO 2 particle has a particle size of about 0.5 to about 0.75 microns.

9. The paper laminate of claim 1 wherein the TiO 2 particle is a pyrogenic TiO 2 particle.

10. The paper laminate of claim 9 wherein the silica is applied by deposition of pyrogenic silica onto a pyrogenic TiO 2 particle, co-oxygenation of silicon tetrachloride with titanium tetrachloride or by deposition via condensed phase aqueous oxide.

11. The paper laminate of claim 10 wherein the silica is applied by deposition via condensed phase aqueous oxide.

12. The paper laminate of claim 10 wherein the silica, alumina or both are substantially homogenous on the surface of the TiO 2 particle.

13. The paper laminate of claim 1 wherein the silica is applied by deposition via condensed phase aqueous oxide.

14. The paper laminate of claim 1 further comprising an opaque, cellulose pulp-based sheet.

15. The paper laminate of claim 14 wherein the opaque, cellulose pulp-based sheet is kraft paper.

16. The paper laminate of claim 1 further comprising an impregnating resin.

17. The paper laminate of claim 16 wherein the impregnating resin is a phenolic resin or a melamine resin.

18. The paper laminate of claim 1 wherein the cationic polymer (c) is present in the amount of about 0.5 to about 1.5% by weight, based on the total dry weight of the pulp used in the paper.

19. A process for making a paper laminate comprising:
(1) first contacting a treated TiO 2 particle having a surface area of at least about 30 m 2 /g, and a cationic polymer to form a cationized TiO 2 particle slurry (a); wherein the treatment comprises an oxide of silicon, aluminum, or mixtures thereof; and the treatment is present in the amount of at least 15% based on the total weight of the treated titanium dioxide particle; and
(2) subsequently contacting the cationized TiO 2 particle slurry with (b) paper pulp; and (c) a cationic polymer to make a décor paper dispersion having improved optical performance without negatively impacting mechanical strength;
(3) forming a décor paper from the décor paper dispersion; and
(4) contacting a décor paper with a resin to form a paper laminate;
wherein the cationic polymer in the slurry (a) and the cationic polymer in the dispersion (c) are compatible; wherein for equal optical performance, the amount of treated TiO 2 particle in the dispersion is reduced by about 10% when compared to a dispersion not comprising the treated TiO 2 particle of (a).

Assignees

• Chemours Company Tt Llc
• Chemours Co Fc Llc

Inventors

• Chinn Mitchell Scott
• Vanhecke Franck Andre

Classifications

• Y10T428/256

  Heavy metal or aluminum or compound thereof · CPC title

• B32B2305/076

  Prepregs · CPC title

• B32B29/00 Primary

  Layered products comprising {a layer of} paper or cardboard · CPC title

• D21H27/26

  characterised by the overlay sheet or the top layers of the structures (decorative panels B44C5/04; wood grain effects B44F9/02) · CPC title

• B32B2419/00

  Buildings or parts thereof · CPC title