Catalyst system based on spherical activated carbon as a carrier and use thereof

Patent metadata

Field	Value
Publication number	US-9975109-B2
Application number	US-201415103065-A
Country	US
Kind code	B2
Filing date	Nov 25, 2014
Priority date	Dec 9, 2013
Publication date	May 22, 2018
Grant date	May 22, 2018

Abstract

The invention relates to a method for producing a catalyst system having at least one catalytically active component, wherein the catalytically active component comprises at least one metal, wherein first a spherical activated carbon used as a catalyst carrier is subjected to an oxidation. Subsequently, the catalytically active component is applied, optionally followed by a reduction of the catalyst system obtained in said manner.

First claim

The invention claimed is:

1. A method of preparing a catalyst system comprising at least one catalytically active component, wherein at least one catalytically active component is fixed on a catalyst carrier, wherein the catalytically active component comprises at least one metal,
wherein said method comprises the following steps in the hereinbelow defined sequence (a) to (d):
(a) providing a spherical activated carbon as a catalyst carrier, wherein the spherical activated carbon is a polymer-based spherical activated carbon, wherein the activated carbon has a Gurvich total pore volume in the range from 0.5 cm 3 /g to 4 cm 3 /g, wherein 10% to 85% of the Gurvich total pore volume of the activated carbon is formed by pores having pore diameters in the range from 2 nm to 50 nm, and wherein the activated carbon has a specific BET surface area in the range from 800 m 2 /g to 3500 m 2 /g and a particle size in the range from 0.05 mm to 2 mm; then
(b) surface-oxidizing the spherical activated carbon provided in step (a), wherein the surface oxidation of the activated carbon leads to a formation of oxygen-containing functional groups on the surface of the activated carbon, wherein the surface oxidation of the activated carbon is performed via at least one oxidizing agent, wherein the oxidizing agent is selected from the group of hydrogen peroxide, nitric acid and sulfuric acid and their combinations and wherein the oxidizing agent is applied in liquid form in the form of solutions or dispersions, and wherein the surface oxidation is followed by a cleanup via at least one washing operation in a liquid and a drying operation of the oxidized activated carbon; then
(c) providing the surface-oxidized activated carbon of step (b) with at least one catalytically active component to obtain a catalyst system by fixing the catalytically active component on the catalyst carrier; then
(d) reducing the catalyst system obtained in step (c) in the form of the activated carbon endowed with the catalytically active component.

2. The method as claimed in claim 1 , wherein the activated carbon has a fractal dimension of open porosity of at least 2.7.

3. The method as claimed in claim 1 , wherein the oxygen-containing functional groups are selected from acidic and basic oxygen-containing functional groups and their combinations.

4. The method as claimed in claim 1 , wherein the oxygen-containing functional groups are selected from hydroxyl, carboxyl, carbonyl, anhydride, lactone, quinone, pyrone, chromene and ether groups and their combinations.

5. The method as claimed in claim 1 , wherein the catalytically active component includes at least one metal in the form of a metal compound or in elemental form.

6. The method as claimed in claim 1 , wherein the catalytically active component includes at least one metal selected from the group of Cu, Ag, Au, Zn, Hg, Sn, Ce, Ti, Zr, V, Nb, Cr, Mo, W, Mn, Fe, Bi, Ru, Os, Co, Rh, Re, Ir, Ni, Pd and Pt.

7. The method as claimed in claim 1 , wherein the catalytically active component includes at least one metal compound which is soluble or dispersible in an aqueous-based solvent or dispersant medium.

8. The method as claimed in claim 1 , wherein the catalytically active component includes at least one metal halide.

9. The method as claimed in claim 1 , wherein the catalytically active component includes at least one metal compound selected from the group of palladium chloride, hexachloroplatinic acid, ruthenium chloride, copper chloride, iron chloride, vanadium chloride and lead chloride.

10. The method as claimed in claim 1 , wherein the catalytically active component is in the form of an aqueous-based solution or dispersion of the catalytically active component, wherein the solution or dispersion contains the catalytically active component in amounts ranging from 0.01 wt % to 80 wt %, based on the solution or dispersion and reckoned as metal.

11. The method as claimed in claim 1 , wherein the step of providing the surface-oxidized activated carbon with the catalytically active component comprises fixing the surface-oxidized activated carbon with the catalytically active component, wherein the fixing is effected by at least one of immersing, wetting, spraying and spray-dispensing the surface-oxidized activated carbon in or with the catalytically active component; and
wherein outer and inner surfaces of the surface-oxidized activated carbon are provided with the catalytically active component.

12. The method as claimed in claim 1 , wherein the reduction of the catalyst system is effected by using at least one liquid or gaseous reducing agent.

13. The method as claimed in claim 1 , wherein the catalyst system includes the catalytically active component in amounts ranging from 0.001 wt % to 30 wt %, reckoned as metal and based on the total weight of the catalyst system.

14. The method as claimed in claim 1 , wherein the activated carbon has a Gurvich total pore volume in the range from 0.5 cm 3 /g to 3.5 cm 3 /g, wherein 20% to 80% of the Gurvich total pore volume of the activated carbon is formed by pores having pore diameters in the range from 2 nm to 50 nm.

Assignees

• Bluecher Gmbh
• Friedrich Alexander Univ Erlangen Nurnberg
• Bluecher Gmbh

Inventors

• Bohringer Bertram
• Fichtner Sven
• Schrage Christian
• Giebelhausen Jann-Michael
• Wasserscheidt Peter
• Etzold Bastian
• Klefer Heiko

Classifications

• B01J23/70

  of the iron group metals or copper · CPC title

• B01J21/18

  Carbon · CPC title

• B01J20/3204

  Inorganic carriers, supports or substrates · CPC title

• B01J20/0225

  Compounds of Fe, Ru, Os, Co, Rh, Ir, Ni, Pd, Pt · CPC title

• C07C51/36

  by hydrogenation of carbon-to-carbon unsaturated bonds · CPC title