System for producing oxygenate and method for producing oxygenate

Patent metadata

Field	Value
Publication number	US-9975105-B2
Application number	US-201314416374-A
Country	US
Kind code	B2
Filing date	Jul 23, 2013
Priority date	Jul 23, 2012
Publication date	May 22, 2018
Grant date	May 22, 2018

Abstract

A system for producing an oxygenate, comprising: a desulfurization apparatus for contacting a raw material gas comprising hydrogen and carbon monoxide with a desulfurizing agent comprising copper; and a synthesis apparatus for contacting the raw material gas treated by the desulfurizing apparatus with an oxygenate-synthesis catalyst comprising rhodium.

First claim

The invention claimed is:

1. A method for producing an oxygenate, comprising:
a desulfurizing agent-preparation step, wherein:
(1) a copper compound, zinc compound and optionally a compound of at least one metal selected from the group consisting of aluminum and chromium are dissolved in water to obtain an aqueous solution of metals,
(2) the obtained aqueous solution of metals and an aqueous solution of a precipitant are dropwise added to a purified water having a temperature of 60 to 90° C. while stirring to thereby form a precipitate, or the aqueous solution of metals is dropwise added to an aqueous solution of a precipitant having a temperature of 60 to 90° C. while stirring to thereby form a precipitate,
(3) the obtained precipitate is washed with a purified water, followed by drying at 100 to 150° C. to obtain a dried product, and
(4) the obtained dried product is calcined at 250 to 350° C. to obtain a desulfurizing agent having a molar ratio of copper/zinc of 1/2.3 to 1/1;

a desulfurization step wherein a raw material gas comprising hydrogen and carbon monoxide is contacted with the desulfurizing agent at a temperature of 120 to 180° C.; and
a synthesis step wherein the raw material gas treated in the desulfurization step is contacted with an oxygenate-synthesis catalyst of the following formula (I):
aA·bB·cC·dD   (I)

wherein A represents rhodium, B represents manganese, C represents an alkali metal, and D represents titanium, and
a, b, c and d represent molar ratios wherein a is 0.053 to 0.98, b is 0.0006 to 0.67, c is 0.00056 to 0.51, and d is 0.0026 to 0.94, with the proviso that a+b+c+d=1.

2. The method according to claim 1 , wherein in the desulfurization step, the raw material gas is contacted with the desulfurizing agent at a temperature of from 150 to 180° C.

Assignees

• Sekisui Chemical Co Ltd
• Renaissance Energy Res Corp

Inventors

• Miyama Toshihito
• Nishino Tomoaki
• Okada Osamu
• Nonouchi Tamotsu

Classifications

• B01J35/1019

  Operations & Transport · mapped topic

• C07C29/158 Primary

  containing rhodium or compounds thereof · CPC title

• B01J23/80

  with zinc, cadmium or mercury · CPC title

• B01J2219/24

  Stationary reactors without moving elements inside · CPC title

• B01J35/1038

  Operations & Transport · mapped topic