Fuel synthesis catalyst and fuel synthesis system

Patent metadata

Field	Value
Publication number	US-9975099-B2
Application number	US-201715457449-A
Country	US
Kind code	B2
Filing date	Mar 13, 2017
Priority date	Mar 16, 2016
Publication date	May 22, 2018
Grant date	May 22, 2018

Abstract

A fuel synthesis catalyst of an embodiment for hydrogenating a gas includes at least one selected from the group consisting of; carbon dioxide and carbon monoxide, the catalyst comprising, a base material containing at least one oxide selected from the group consisting of; Al 2 O 3 , MgO, TiO 2 , and SiO 2 , first metals containing at least one metal selected from the group consisting of; Ni, Co, Fe, and Cu and brought into contact with the base material, and a first oxide containing at least one selected from the group consisting of; CeO 2 , ZrO 2 , TiO 2 , and SiO 2 and having an interface with each of the first metals and the base material. The first metals exist on an outer surface of the base material, and on a surface of the base material in fine pores having opening ends on the outer surface of the base material and inside the base material. The first metals and the first oxide exist in the fine pores. The first metals have interfaces with the base material in the fine pores. The first metals exist inside the base material.

First claim

What is claimed is:

1. A fuel synthesis catalyst for hydrogenating a gas containing at least one selected from the group consisting of; carbon dioxide and carbon monoxide, the catalyst comprising:
a base material containing at least one oxide selected from the group consisting of; Al 2 O 3 , MgO, TiO 2 , and SiO 2 ;
first metals containing at least one metal selected from the group consisting of; Ni, Co, Fe, and Cu and brought into contact with the base material; and
a first oxide containing at least one selected from the group consisting of; CeO 2 , ZrO 2 , TiO 2 , and SiO 2 and having an interface with each of the first metals and the base material, wherein
the first metals exist on an outer surface of the base material, and on a surface of the base material in fine pores having opening ends on the outer surface of the base material and inside the base material,
the first metals and the first oxide exist in the fine pores,
the first metals have interfaces with the base material in the fine pores, and
the first metals exist inside the base material.

2. The catalyst according to claim 1 , wherein the first oxide has an interface with the first metals in the fine pores, and
the first oxide partially or entirely covers the outer surface of the base material.

3. The catalyst according to claim 1 , wherein a content of the first metals is 5% by mass or more and 20% by mass or less.

4. The catalyst according to claim 1 , wherein an average particle diameter of the first metals is 2 nm or more and 200 nm or less, and
an average particle diameter of the fuel synthesis catalyst is 2 mm or more and 10 mm or less.

5. The catalyst according to claim 1 , wherein the first oxide contains a solid-solubilized product with a second oxide containing a rare-earth oxide.

6. The catalyst according to claim 5 , wherein the rare-earth oxide contains at least one element selected from the group consisting of; La, Sm, Gd, and Y.

7. The catalyst according to claim 5 , wherein the rare-earth oxide solid-solubilized in the first oxide is contained in 10 mol % or more and 60 mol % or less of the first oxide.

8. The catalyst according to claim 1 , being a hydrocarbon fuel synthesis catalyst or an alcohol fuel synthesis catalyst.

9. A fuel synthesis system comprising:
a reaction column provided with the fuel synthesis catalyst according to claim 1 ;
a first raw material supply line supplying one or both of carbon dioxide and carbon monoxide to the reaction column;
a second raw material supply line supplying hydrogen to the reaction column; and
a recovery unit recovering a fuel generated by reacting one or both of the carbon dioxide and the carbon monoxide with the hydrogen using the catalyst in the reaction column.

10. The system according to claim 9 , wherein a temperature of reaction of the carbon dioxide or carbon monoxide with the hydrogen using the catalyst is 250° C. or higher but 400° C. or lower.

11. A fuel synthesis catalyst for hydrogenating a gas containing at least one selected from the group consisting of; carbon dioxide and carbon monoxide, the catalyst comprising:
a base material containing at least one oxide selected from the group consisting of; Al 2 O 3 , MgO, TiO 2 , and SiO 2 ;
first metals containing at least one metal selected from the group consisting of; Ni, Co, Fe, and Cu and brought into contact with the base material;
a first oxide containing at least one selected from the group consisting of; CeO 2 , ZrO 2 , TiO 2 , and SiO 2 and having an interface with each of the first metals and the base material; and
second metals containing a metal different from a metal included in the first metals among the at least one metal selected from the group consisting of; Ni, Co, Fe, and Cu, wherein
the first metals exist on an outer surface of the base material, and on a surface of the base material in fine pores having opening ends on the outer surface of the base material and inside the base material,
the first metals, the first oxide, and the second metals exist in the fine pores,
the first metals have interfaces with the base material in the fine pores,
the second metals have interfaces with the first metals in the fine pores, and
the first metals exist inside the base material.

12. The catalyst according to claim 11 , wherein a particle diameter of the first metals in which a cumulative volume curve in particle size distribution is 16% is larger than a particle diameter of the second metals in which a cumulative volume curve in particle size distribution is 84%.

13. The catalyst according to claim 11 , wherein a proportion of the first metals and the second metals contained in the fuel synthesis catalyst is 5% by mass or more and 40% by mass or less.

14. The catalyst according to claim 11 , wherein the first oxide has an interface with the first metals in the fine pores, and
the first oxide partially or entirely covers the outer surface of the base material.

15. The catalyst according to claim 11 , wherein an average particle diameter of the first metals is 2 nm or more and 200 nm or less,
an average particle diameter of the second metals is 2 nm or more and 100 nm or less, and
an average particle diameter of the fuel synthesis catalyst is 2 mm or more and 10 mm or less.

16. The catalyst according to claim 11 , wherein the first oxide contains a solid-solubilized product with a second oxide containing a rare-earth oxide.

17. The catalyst according to claim 16 , wherein the rare-earth oxide contains at least one element selected from the group consisting of; La, Sm, Gd, and Y.

18. The catalyst according to claim 16 , wherein the rare-earth oxide solid-solubilized in the first oxide is contained in 10 mol % or more and 60 mol % or less of the first oxide.

19. A fuel synthesis system comprising:
a reaction column provided with the fuel synthesis catalyst according to claim 11 ;
a first raw material supply line supplying one or both of carbon dioxide and carbon monoxide to the reaction column;
a second raw material supply line supplying hydrogen to the reaction column; and
a recovery unit recovering a fuel generated by reacting one or both of the carbon dioxide and the carbon monoxide with the hydrogen using the catalyst in the reaction column.

20. The system according to claim 19 , wherein a temperature of reaction of the carbon dioxide or carbon monoxide with the hydrogen using the catalyst is 250° C. or higher but 400° C. or lower.

Assignees

• Toshiba Kk

Inventors

• Fukasawa Takayuki
• Essaki Kenji
• Matsuno Shinsuke
• Kuboki Takashi
• Goto Yasuhiro
• Suenaga Seiichi

Classifications

• B01J23/755 Primary

  Nickel · CPC title

• B01J21/08

  Silica · CPC title

• B01J21/063

  Titanium; Oxides or hydroxides thereof · CPC title

• B01J21/04

  Alumina · CPC title

• B01J37/0244

  Coatings comprising several layers · CPC title