Reactive flow static mixer with cross-flow obstructions

Patent metadata

Field	Value
Publication number	US-9975094-B2
Application number	US-201715472424-A
Country	US
Kind code	B2
Filing date	Mar 29, 2017
Priority date	Sep 28, 2010
Publication date	May 22, 2018
Grant date	May 22, 2018

Abstract

Embodiments of the present invention relate to a mixing apparatus. Particularly, embodiments of the present invention provide a mixing apparatus for mixing fluid components such as phosgene and amine during a highly reactive chemical reaction. One embodiment provides a mixing conduit comprising a cylindrical sidewall defining an inner volume, wherein one or more jets are formed through the cylindrical sidewalls and connect to the inner volume and one or more flow obstructions disposed in the inner volume, wherein each flow obstruction is positioned upstream from an associated aperture.

First claim

What is claimed is:

1. A method for mixing phosgene with at least one of methylene diphenyl diamine, toluene diamine, and hexamethylene diamine in a mixing conduit, the method comprising:
a) providing a mixing conduit comprising
i) a cylindrical sidewall defining an inner volume;
ii) plurality of apertures formed through the cylindrical sidewall along a circumference of the cylindrical sidewall, said apertures connecting to the inner volume of the cylindrical sidewall;
iii) a plurality of spokes inserted into the inner volume along the circumference of the cylindrical sidewall, and wherein each of the plurality of spokes is aligned with and entirely upstream of an associated aperture to create a flow obstruction upstream of said associated aperture, said spokes being characterized in that each spoke has a cross-section in the shape of one of a circle, oval, triangle, diamond, non-symmetrical diamond, or tear-drop; and wherein the plurality of spokes are coupled to a disk substantially concentric to the cylindrical sidewall of the mixing conduit;
b) flowing a first flow comprising phosgene through the inner volume, along a longitude of the mixing conduit and sequentially past said spokes and then past said apertures; and
c) flowing a second flow comprising at least one of methylene diphenyl diamine, toluene diamine, and hexamethylene diamine though said apertures and into said inner volume to form jets of said second flow into said first flow.

2. The method of claim 1 , wherein each spoke is tapered having a large end coupled to the cylindrical sidewall and a small end near a central axis of the mixing conduit.

3. The method of claim 1 , wherein said apertures comprise at least one tapered aperture having a large opening outside the mixing conduit and a small opening inside the mixing conduit.

4. The method of claim 1 , wherein an additional aperture is disposed adjacent is disposed adjacent each of the plurality of apertures downstream on a longitudinal axis of the cylindrical sidewall.

5. The method of claim 1 , wherein said plurality of apertures comprises at least one aperture tilted at an angle relative to a plane perpendicular to a longitudinal axis of the mixing conduit.

6. The method of claim 1 , wherein the spokes are mounted at an angle relative to a plane perpendicular to a longitudinal axis of the mixing conduit.

Assignees

• Dow Global Technologies Llc

Inventors

• Gillis Paul A
• Mukherjee Joydeep
• Cooper John B
• Flores Arthur C
• Reed Daniel J

Classifications

• C07C263/10

  by reaction of amines with carbonyl halides, e.g. with phosgene · CPC title

• B01F5/061

  Operations & Transport · mapped topic

• B01F5/0485 Primary

  Operations & Transport · mapped topic

• B01F2005/0623

  Operations & Transport · mapped topic

• B01F2005/0636

  Operations & Transport · mapped topic