Battery with extractible air electrode

Patent metadata

Field	Value
Publication number	US-9972874-B2
Application number	US-201415038101-A
Country	US
Kind code	B2
Filing date	Nov 21, 2014
Priority date	Nov 22, 2013
Publication date	May 15, 2018
Grant date	May 15, 2018

Abstract

A rechargeable battery including a casing containing therein: an air electrode; a negative electrode; and an electrolyte, in which the air electrode can be taken out of the casing. The rechargeable battery also relates to a cathode compartment for an air electrode battery, where the compartment includes an air electrode and is insertable into a casing of the battery without being part of the casing, and the compartment is removably movable.

First claim

The invention claimed is:

1. A cathode compartment for an air electrode battery, comprising an air electrode,
wherein said cathode compartment:
is suitable to be inserted into a battery case in an extractible way,
in which the air electrode is in the form of a plate,
is liquid-tight,
comprises an electrical connection for connecting said air electrode to a positive terminal of a battery,
comprises a hollow cartridge having an air inlet and an air outlet, and
comprises at least one flat face formed at least partially by the air electrode.

2. The cathode compartment according to claim 1 , comprising a rim on its face, formed at least partially by the air electrode of the cartridge.

3. The cathode compartment according to claim 1 , comprising an additional air electrode in the form of a plate at least partially forming another face of the hollow cartridge, the other face being opposite to the face formed at least partially by the air electrode.

4. The cathode compartment according to claim 1 , comprising a honeycombed mechanical reinforcement arranged inside the cartridge resting against the air electrode.

5. The cathode compartment according to claim 1 , wherein said cathode compartment has a lower part and an upper part, the lower part comprising the air electrodes and the upper part having at least one section perpendicular to the plane of the air electrodes below the section of the lower part.

6. A rechargeable battery comprising a case and inside said case:
an air electrode;
a negative electrode; and
an electrolyte;
wherein the air electrode is extractible from the case and incorporated into the cathode compartment according to claim 1 .

7. The battery according to claim 6 , wherein:
the negative electrode is a metal electrode,
the electrolyte is a liquid electrolyte,
said battery comprises an electrically insulating separator between the air electrode and the metal electrode and a flexible element,
the cathode compartment further comprises a rim on its face, formed at least partially by the air electrode of the cartridge, and is moveable within the case, and
the separator, the cathode compartment and the metal electrode are arranged so that said flexible element acts on said cathode compartment so that said cathode compartment compresses the metal electrode via said cathode compartment face formed at least partially by the air electrode.

8. The battery according to claim 7 , wherein the flexible element is formed by the case or is a compression system arranged against a wall of the case.

9. The battery according to claim 7 , comprising:
a second air electrode incorporated into a second moveable cathode compartment, said second moveable cathode compartment being extractible, and
a second separator between the second air electrode and the metal electrode,
wherein the two cathode compartments, the metal electrode the separators and the flexible element are arranged so that the metal electrode is compressed between the two cathode compartments via their faces formed at least partially by the air electrodes.

10. The battery according to claim 6 , comprising a second positive electrode for charging the battery.

11. The battery according to claim 10 , wherein:
the second positive electrode is arranged between the cathode compartment and the negative electrode, and
said battery also comprises at least one spacer placed in contact with said second positive electrode in order to facilitate the removal of oxygen bubbles produced on the second positive electrode during charging.

12. The battery according to claim 11 , comprising two spacers placed one on either side of the positive electrode.

13. The battery according to claim 11 wherein:
at least one spacer is provided against a face of the second positive electrode turned towards the negative electrode, respectively towards the air electrode, and
said battery also comprises at least one mechanical protection arranged between the spacer and the negative electrode, respectively the air electrode.

Assignees

• Electricite De France

Inventors

• Toussaint Gwenaelle
• Stevens Philippe
• Deshayes Sophie

Classifications

• H01M6/5077

  Regeneration of reactants or electrolyte · CPC title

• H01M4/86

  Inert electrodes with catalytic activity, e.g. for fuel cells · CPC title

• Y02W30/84

  Recycling of batteries or fuel cells · CPC title

• H01M2004/024

  Insertable electrodes · CPC title

• H01M12/065 Primary

  with plate-like electrodes or stacks of plate-like electrodes · CPC title