Gas diffusion electrode medium for fuel cell

Patent metadata

Field	Value
Publication number	US-9972847-B2
Application number	US-201314418336-A
Country	US
Kind code	B2
Filing date	Aug 9, 2013
Priority date	Aug 24, 2012
Publication date	May 15, 2018
Grant date	May 15, 2018

Abstract

A fuel cell gas diffusion electrode medium has exceptional anti-flooding characteristic and anti-dry-out characteristic, the capability to achieve high cell performance across a wide temperature range from low to high temperatures, and exceptional mechanical properties, electrical conductivity, and thermal conductivity, a microporous layer being arranged on one surface of an electrode base material; wherein the fuel cell gas diffusion electrode medium is characterized in that linear carbon having an aspect ratio of 30-5000 is included in the microporous layer, and the areal weight of the gas diffusion electrode medium is 30-60 g/m2.

First claim

The invention claimed is:

1. A gas diffusion electrode medium for a fuel cell in which a microporous layer is arranged at one surface of an electrode base material, wherein the microporous layer contains a linear carbon having an aspect ratio of 30 to 5000, and an areal weight of the gas diffusion electrode medium is 30 to 57 g/m 2 .

2. The gas diffusion electrode medium according to claim 1 , wherein thickness of the gas diffusion electrode medium is 70 to 190 μm.

3. The gas diffusion electrode medium according to claim 1 , wherein gas permeation resistance in a direction perpendicular to a plane is 15 to 190 mmAq.

4. The gas diffusion electrode medium according to claim 1 , wherein a ratio of fluorine to carbon is different between one surface and an opposite surface of the electrode base material to be used for the gas diffusion electrode medium, and the microporous layer is arranged on the surface on a side where the ratio of fluorine to carbon is higher.

5. The gas diffusion electrode medium according to claim 1 , wherein a microporous region having an areal ratio of 5 to 70% is arranged on the opposite surface from the surface of the electrode base material on which the microporous layer is arranged.

6. A gas diffusion electrode medium for a fuel cell in which a microporous layer is arranged at one surface of an electrode base material, wherein the microporous layer contains a linear carbon having an aspect ratio of 30 to 5000, the areal weight of the microporous layer is 10 to 35 g/m 2 , and an areal weight of the gas diffusion electrode medium is 30 to 60 g/m 2 .

7. The gas diffusion electrode medium according to claim 6 , wherein gas permeation resistance in a direction perpendicular to a plane is 15 to 190 mmAq.

8. The gas diffusion electrode medium according to claim 2 , wherein gas permeation resistance in a direction perpendicular to a plane is 15 to 190 mmAq.

9. The gas diffusion electrode medium according to claim 6 , wherein a ratio of fluorine to carbon is different between one surface and an opposite surface of the electrode base material to be used for the gas diffusion electrode medium, and the microporous layer is arranged on the surface on a side where the ratio of fluorine to carbon is higher.

10. The gas diffusion electrode medium according to claim 2 , wherein a ratio of fluorine to carbon is different between one surface and an opposite surface of the electrode base material to be used for the gas diffusion electrode medium, and the microporous layer is arranged on the surface on a side where the ratio of fluorine to carbon is higher.

11. The gas diffusion electrode medium according to claim 3 , wherein a ratio of fluorine to carbon is different between one surface and an opposite surface of the electrode base material to be used for the gas diffusion electrode medium, and the microporous layer is arranged on the surface on a side where the ratio of fluorine to carbon is higher.

12. The gas diffusion electrode medium according to claim 6 , wherein the microporous layer contains carbon black and a mixing mass ratio of the carbon black to the linear carbon having an aspect ratio of 30 to 5000 is 0.5 to 20.

13. The gas diffusion electrode medium according to claim 2 , wherein the microporous layer contains carbon black and a mixing mass ratio of the carbon black to the linear carbon having an aspect ratio of 30 to 5000 is 0.5 to 20.

14. The gas diffusion electrode medium according to claim 3 , wherein the microporous layer contains carbon black and a mixing mass ratio of the carbon black to the linear carbon having an aspect ratio of 30 to 5000 is 0.5 to 20.

15. The gas diffusion electrode medium according to claim 4 , wherein the microporous layer contains carbon black and a mixing mass ratio of the carbon black to the linear carbon having an aspect ratio of 30 to 5000 is 0.5 to 20.

16. The gas diffusion electrode medium according to claim 6 , wherein a microporous region having an areal ratio of 5 to 70% is arranged on the opposite surface from the surface of the electrode base material on which the microporous layer is arranged.

17. The gas diffusion electrode medium according to claim 2 , wherein a microporous region having an areal ratio of 5 to 70% is arranged on the opposite surface from the surface of the electrode base material on which the microporous layer is arranged.

18. The gas diffusion electrode medium according to claim 3 , wherein a microporous region having an areal ratio of 5 to 70% is arranged on the opposite surface from the surface of the electrode base material on which the microporous layer is arranged.

19. A gas diffusion electrode medium for a fuel cell in which a microporous layer is arranged at one surface of an electrode base material, wherein the microporous layer contains a linear carbon having an aspect ratio of 30 to 5000, the microporous layer contains carbon black and a mixing mass ratio of the carbon black to the linear carbon fiber having an aspect ratio of 30 to 5000 is 0.5 to 20, and an areal weight of the gas diffusion electrode medium is 30 to 60 g/m 2 .

20. The gas diffusion electrode medium according to claim 6 , wherein thickness of the gas diffusion electrode medium is 70 to 190 μm.

Assignees

• Toray Industries

Inventors

• Utsunomiya Masamichi
• Hashimoto Masaru
• Kamae Toshiya

Classifications

• H01M8/0243

  in the form of mixtures · CPC title

• H01M4/8657 Primary

  layered · CPC title

• H01M4/926

  on carbon or graphite · CPC title

• H01M8/0245

  in the form of layered or coated products · CPC title

• H01M4/96 Primary

  Carbon-based electrodes · CPC title