Formulations containing conductive polymers and use thereof in organic electronic devices

Patent metadata

Field	Value
Publication number	US-9972782-B2
Application number	US-201314429890-A
Country	US
Kind code	B2
Filing date	Sep 5, 2013
Priority date	Sep 25, 2012
Publication date	May 15, 2018
Grant date	May 15, 2018

Abstract

The invention relates to formulations containing doped conductive polymers, which due to outstanding hole injection characteristics and high conductivity are very suitable for use in organic electronic devices, preferably in organic electroluminescent devices, in particular in the buffer layers thereof. Thus the invention further relates to the use of the formulations according to the invention in organic electronic devices, preferably in electroluminescent devices, in particular in the buffer layers thereof.

First claim

The invention claimed is:

1. A formulation consisting essentially of at least one doped, conductive polymer, at least one oxidant and at least one solvent, wherein the at least one solvent is water, wherein the content of water in the formulation is in the range from 65 to 99.99% by weight, and wherein the content of the at least one oxidant in the formulation is in the range from 0.05 to 5% by weight.

2. The formulation according to claim 1 , wherein the conductive polymer is selected from the group consisting of polythiophene, polythiophene derivative, polyaniline, polyaniline derivative, polypyrrole, and oligoaniline.

3. The formulation according to claim 1 , wherein the content of the at least one doped, conductive polymer in the formulation is in the range from 0.001 to 30% by weight.

4. The formulation according to claim 1 , wherein at least one oxidant is selected from the group consisting of organic and inorganic peroxides, peracids, persulfates, perborates, metal salts, derivatives of halogen oxyacid, nitrates, halogens, ozone, nitrogen oxides, nitroso compounds, and oxygen.

5. The formulation according to claim 1 , wherein the weight ratio of doped, conductive polymer to oxidant in the formulation is in the range from 1000:1 to 1:10.

6. A method comprising incorporating the formulation according to claim 1 in organic, electronic devices.

7. The method according to claim 6 , wherein the organic, electronic device is an electroluminescent device.

8. The formulation according to claim 1 , wherein the conductive polymer is polyaniline, and wherein at least one oxidant is hydrogen peroxide or sodium hypochlorite.

9. A formulation consisting essentially of at least one doped, conductive polymer, at least one oxidant selected from the group consisting of organic and inorganic peroxides, peracids, persulfates, perborates, metal salts, derivatives of halogen oxyacid, nitrates, halogens, ozone, nitrogen oxides, nitroso compounds, and oxygen, and at least one solvent, wherein the at least one solvent is water, wherein the content of water in the formulation is in the range from 65 to 99.99% by weight, and wherein the content of the at least one oxidant in the formulation is in the range from 0.05 to 5% by weight.

Assignees

• Merck Patent Gmbh

Inventors

• Becker Heinrich
• Heun Susanne

Classifications

• C08L79/02

  Polyamines · CPC title

• C08G2261/794

  with polymeric dopants · CPC title

• C08G61/126

  with a five-membered ring containing one sulfur atom in the ring · CPC title

• C08L65/00

  Compositions of macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain (C08L7/00 - C08L57/00, C08L61/00 take precedence); Compositions of derivatives of such polymers · CPC title

• C08L79/04

  Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors · CPC title