Apparatus, method and system for detecting salt in a hydrocarbon fluid

Patent metadata

Field	Value
Publication number	US-9970895-B2
Application number	US-201615332555-A
Country	US
Kind code	B2
Filing date	Oct 24, 2016
Priority date	Jul 13, 2012
Publication date	May 15, 2018
Grant date	May 15, 2018

Abstract

A method for determining a salt concentration of a hydrocarbon fluid using a conductivity sensor and a hydrocarbon testing solution includes forming the hydrocarbon testing solution. The electropolymerizable monomer is operable to form a resultant associated polymer at a peak potential of the electropolymerizable polymer. The method includes introducing the hydrocarbon testing solution into the conductivity sensor. The method includes inducing a range of potential across the hydrocarbon testing solution such that at least a portion of the electropolymerizable monomer polymerizes. The range of induced potential includes the peak potential of the electropolymerizable polymer. The method includes detecting a range of electrical current associated with the range of potential induced. The method also includes the step of determining the salt concentration of the hydrocarbon fluid using the range of potential induced and the range of electrical current detected.

First claim

What is claimed is:

1. A system for determining a salt concentration of a hydrocarbon fluid using a conductivity sensor and a hydrocarbon testing solution, comprising:
a sampling line coupled to a hydrocarbon fluid supply line and configured to divert a portion of hydrocarbon fluid from the hydrocarbon fluid supply line;
a solvent injection line coupled to the sampling line and configured to introduce a non-aqueous solvent into the sampling line to mix with the portion of hydrocarbon fluid;
a monomer injection line coupled to the sampling line and configured to introduce an electropolymerizable monomer into the sampling line to mix with the portion of hydrocarbon fluid and the non-aqueous solvent to from a hydrocarbon testing solution
a conductivity sensor coupled to the sample line, wherein the sample line is further configured to introduce the hydrocarbon testing solution to the interior of the conductivity sensor, the conductivity sensor comprising a working electrode, a counter electrode and a reference electrode; and
a computer controller comprising computer-accessible memory, the computer-accessible memory having computer-readable instructions stored thereon that, when executed, cause the computer controller to:
induce a sweeping potential in the hydrocarbon testing solution between a first pre-set potential value and a pre-set second potential value using the working electrode and the reference electrode, such that at least a portion of the electropolymerizable monomer in the hydrocarbon testing solution polymerizes into a resultant associated polymer; and
determine the concentration of salt in the hydrocarbon fluid in the hydrocarbon fluid supply line.

2. The system of claim 1 , comprising:
a polymer solvent line coupled to the conductivity sensor and configured to introduce a polymer solvent into the conductivity sensor; and
a polymer solvent flow control valve coupled to the polymer solvent line and in signal communication with the computer controller.

3. The system of claim 2 , the computer-accessible memory having computer-readable instructions stored thereon that, when executed, cause the computer controller to:
periodically introduce an amount of polymer solvent into the conductivity sensor by transmitting a signal to the polymer solvent flow control valve, the amount of polymer solvent sufficient to remove the resultant associated polymer from the conductivity sensor.

4. The system of claim 1 , comprising a sampling return line coupled to the conductivity sensor and configured to convey exhausted hydrocarbon testing solution from the conductivity sensor to the hydrocarbon fluid supply line.

5. The system of claim 1 , comprising a display monitor, the computer-accessible memory having computer-readable instructions stored thereon that, when executed, cause the computer controller to provide computer-processed information of conductivity testing on the display monitor.

6. The system of claim 1 , comprising a hydrocarbon fluid flow sensor configured to detect a rate of fluid flow through the hydrocarbon fluid supply line, wherein the hydrocarbon fluid flow sensor is in signal communication with the computer controller.

7. The system of claim 6 , comprising:
a steam injection line coupled to the hydrocarbon fluid supply line and configured to introduce steam into the hydrocarbon fluid supply line to mix with the hydrocarbon fluid;
a steam flow control valve coupled to the steam injection line and in signal communication with the computer controller; and
a steam flow sensor configured to provide a signal in response to the detected rate of steam flow through the steam injection line, wherein the steam flow sensor is in signal communication with the computer controller;
a steam pressure sensor configured to provide a signal in response to the pressure of the steam in the steam injection line, wherein the steam pressure sensor is in signal communication with the computer controller; and
a steam temperature sensor configured to provide a signal in response to the temperature of the steam in the steam injection line, wherein the steam pressure sensor is in signal communication with the computer controller.

8. The system of claim 7 , the computer-accessible memory having computer-readable instructions stored thereon that, when executed, cause the computer controller to:
determine an amount of steam to introduce to the hydrocarbon fluid in the hydrocarbon fluid supply line to for downstream salt extraction, the determination based on a flow signal from the hydrocarbon fluid flow sensor, a flow signal from the steam flow sensor, a pressure signal from the steam pressure sensor and a temperature signal from the steam temperature sensor.

9. The system of claim 1 , comprising:
a sampling line flow control valve coupled to the sampling line and in signal communication with the computer controller; and
a sampling line flow sensor configured to provide a signal in response to the detected rate of fluid flow through the sampling line, wherein the sampling line flow sensor is in signal communication with the computer controller.

10. The system of claim 1 , comprising:
a solvent injection line flow control valve coupled to the solvent injection line and in signal communication with the computer controller; and
a solvent injection line flow sensor configured to provide a signal in response to the detected rate of fluid flow through the solvent injection line, wherein the solvent injection line sensor is in signal communication with the computer controller.

11. The system of claim 1 , comprising:
a monomer injection line flow control valve coupled to the monomer injection line and in signal communication with the computer controller; and
a monomer injection line flow sensor configured to provide a signal in response to the detected rate of fluid flow through the monomer injection line, wherein the monomer injection line flow sensor is in signal communication with the computer controller.

12. The system of claim 1 , the computer-accessible memory having computer-readable instructions stored thereon that, when executed, cause the computer controller to:
detect a range of electrical current associated with the range of sweeping potential induced using the working electrode and the counter electrode.

13. The system of claim 12 , wherein determine the concentration of salt in the hydrocarbon fluid in the hydrocarbon fluid supply line comprises determine the salt concentration of the hydrocarbon fluid using the range of sweeping potential induced across the hydrocarbon testing solution and the range of electrical current detected by the conductivity sensor.

14. The system of claim 1 , wherein the range of sweeping potential includes the peak potential of the resultant polymer.

15. The system of claim 1 , wherein the sweeping potential is induced at a linear sweep rate in a range of about 5 millivolts per second (mV/sec) to about 0.5 volts per second.

16. The system of claim 1 , wherein the electropolymerizable monomer is selected from the group consisting of thiophene, thiophene-derivatives, aniline, aniline-derivatives, crown ethers and combinations thereof.

17. The system of claim 1 , wherein the conductivity sensor comprises a mixing apparatus, the computer-accessible memory having computer-readable instructions stored thereon that, when executed, cause the computer controller to transmit a signal to the mixing apparatus to provide continuous stirring of the hydrocarbon testing solution.

18. The system of claim 1 , wherein the working elect

Assignees

• Saudi Arabian Oil Co

Inventors

• Akmal Naim
• Aleisa Rashed
• Vaidya Milind

Classifications

• G01N33/2835

  Specific substances contained in the oils or fuels · CPC title

• G01N27/4163

  checking the operation of, or calibrating, the measuring apparatus (G01N27/3274, G01N27/4175 and G01N33/0006 take precedence) · CPC title

• G01N27/301

  Reference electrodes · CPC title

• G01N27/413 Primary

  Concentration cells using liquid electrolytes {measuring currents or voltages in voltaic cells} · CPC title

• G01N27/26 Primary

  by investigating electrochemical variables; by using electrolysis or electrophoresis · CPC title