Use of turbidimeter for measurement of solid catalyst system component in a reactor feed

Patent metadata

Field	Value
Publication number	US-9970869-B2
Application number	US-201514809147-A
Country	US
Kind code	B2
Filing date	Jul 24, 2015
Priority date	Jul 24, 2015
Publication date	May 15, 2018
Grant date	May 15, 2018

Abstract

A method of monitoring a solid component of a reactor feed stream in a polymer production system, comprising (a) measuring a turbidity of the reactor feed stream, wherein the reactor feed stream comprises a solid component of a polymerization catalyst system, and (b) translating the turbidity of the reactor feed stream into a concentration of the solid component in the reactor feed stream. A method of monitoring a solid component of a reactor feed stream in a polymer production system, comprising (a) measuring a turbidity of a precontactor feed stream, wherein the precontactor feed stream comprises a solid component of a polymerization catalyst system, and (b) translating the turbidity of the precontactor feed stream into a concentration of the solid component in a precontactor effluent stream, wherein the precontactor effluent stream comprises the reactor feed stream.

First claim

We claim:

1. A method of monitoring a solid component of a reactor feed stream in a polymer production system, comprising:
(a) measuring a turbidity of the reactor feed stream, wherein the reactor feed stream comprises a solid component of a polymerization catalyst system, wherein the solid component comprises an activator support, wherein the activator support is fed to a precontactor, wherein the precontactor is configured to receive the polymerization catalyst system via one or more precontactor feed streams, and wherein at least one of the precontactor feed streams comprises at least a portion of the activator support; and
(b) translating the turbidity of the reactor feed stream into a concentration of the solid component in the reactor feed stream, wherein a mass balance is calculated across the precontactor to yield an amount of activator support in the precontactor.

2. The method of claim 1 , wherein (b) translating the turbidity of the reactor feed stream into a concentration of the solid component in the reactor feed stream comprises using a calibration curve with known solid component concentration values as a function of measured turbidity.

3. The method of claim 1 , wherein (b) translating the turbidity of the reactor feed stream into a concentration of the solid component in the reactor feed stream further comprises subtracting a background signal from the measured turbidity of the reactor feed stream.

4. The method of claim 1 , wherein (a) measuring a turbidity of the reactor feed stream comprises passing at least a portion of the feed stream through a turbidimeter, and obtaining an output signal representing turbidity from the turbidimeter.

5. The method of claim 4 , wherein the turbidimeter is located downstream of a solid component delivery device, wherein the solid component delivery device provides for intermittent delivery of the solid component into the reactor feed stream.

6. The method of claim 1 , wherein the turbidity of the reactor feed stream, the concentration of the solid component in the reactor feed stream, or both are averaged over a time period to yield an averaged turbidity, an averaged concentration, or both.

7. The method of claim 6 , wherein the time period is from about 10 seconds to about 4 hours.

8. The method of claim 6 , wherein the time period is a residence time of the solid component in a reactor.

9. The method of claim 6 , wherein the time period is a residence time of the solid component in the precontactor.

10. The method of claim 9 , wherein the turbidity is measured upstream of the precontactor, downstream of the precontactor, or both.

11. The method of claim 9 , wherein the activator support is characterized by a precontactor residence time of from about 1 minute to about 60 minutes.

12. The method of claim 11 , wherein the reactor feed stream comprises at least a portion of a precontactor feed stream comprising at least a portion of the activator support, and wherein a turbidity of a precontactor feed stream comprising at least a portion of the activator support is averaged over the precontactor residence time to yield an averaged turbidity of the activator support, an averaged concentration of the activator support, or both.

13. The method of claim 1 , wherein the activator support is stored in a storage tank upstream of a reactor, and wherein the turbidity of the reactor feed stream is measured downstream of the storage tank.

14. The method of claim 13 , wherein a mass balance is calculated across the storage tank to yield an amount of the activator support in the storage tank.

15. The method of claim 13 , wherein measuring the turbidity of the reactor feed stream downstream of the storage tank provides near real-time data about the storage tank running empty.

16. The method of claim 1 , wherein the concentration of the solid component is used for calculating one or more ratios of components of the polymerization catalyst system; and wherein the one or more ratios of components of the polymerization catalyst system are compared to one or more target ratios.

17. The method of claim 16 , wherein the one or more ratios of components of the polymerization catalyst system are different when compared to the one or more target ratios, and wherein an amount of at least one component of the polymerization catalyst system is adjusted to meet the target ratios.

18. A method of monitoring a solid component of a reactor feed stream in a polymer production system, comprising:
(a) measuring a turbidity of a precontactor feed stream, wherein the precontactor feed stream comprises a solid component of a polymerization catalyst system, wherein the solid component comprises an activator support, wherein the activator support is fed to a precontactor; and
(b) translating the turbidity of the precontactor feed stream into a concentration of the solid component in a precontactor effluent stream, wherein the precontactor effluent stream comprises the reactor feed stream, and wherein a mass balance is calculated across the precontactor to yield an amount of activator support in the precontactor.

19. The method of claim 18 further comprising calculating a ratio of activator support/at least one metallocene, a ratio of activator support/organoaluminum compound, or both; and comparing the ratio of activator support/at least one metallocene to a target ratio of activator support/at least one metallocene, the ratio of activator support/organoaluminum compound to a target ratio of activator support/organoaluminum compound, or both.

20. A method of monitoring a solid component of a reactor feed stream in a polymer production system, comprising:
(a) measuring a turbidity of a precontactor effluent stream, wherein the precontactor effluent stream comprises the reactor feed stream, wherein a precontactor effluent stream is recovered from a precontactor; and
(b) translating the turbidity of the precontactor effluent stream into a concentration of the solid component in the reactor feed stream, wherein the solid component comprises an activator support, and wherein a mass balance is calculated across the precontactor to yield an amount of activator support in the precontactor.

21. The method of claim 20 , wherein the polymerization catalyst system comprises at least one metallocene and an organoaluminum compound, and wherein the concentration of the at least one metallocene and organoaluminum compound are measured upstream of a precontactor.

Assignees

• Chevron Phillips Chemical Co Lp

Inventors

• Schwerdtfeger Eric D
• Hert Daniel G
• Mcdaniel Max P

Classifications

• G01N21/85

  Investigating moving fluids or granular solids · CPC title

• G01N21/82

  producing a precipitate or turbidity · CPC title

• C08F2/00

  Processes of polymerisation · CPC title

• B01J21/16

  Clays or other mineral silicates · CPC title

• B01J2219/0024

  other than of the reactor or heat exchange system · CPC title