Methods for constructing parts using metallic glass alloys, and metallic glass alloy materials for use therewith

Patent metadata

Field	Value
Publication number	US-9970079-B2
Application number	US-201514690253-A
Country	US
Kind code	B2
Filing date	Apr 17, 2015
Priority date	Apr 18, 2014
Publication date	May 15, 2018
Grant date	May 15, 2018

Abstract

Described herein are methods of constructing a three-dimensional part using metallic glass alloys, layer by layer, as well as metallic glass-forming materials designed for use therewith. In certain embodiments, a layer of metallic glass-forming powder or a sheet of metallic glass material is deposited to selected positions and then fused to a layer below by suitable methods such as laser heating or electron beam heating. The deposition and fusing are then repeated as need to construct the part, layer by layer. One or more sections or layers of non-metallic glass material can be included as needed to form composite parts. In one embodiment, the metallic glass-forming powder is a homogenous atomized powder. In another embodiment, the metallic glass-forming powder is formed by melting a metallic glass alloy to an over-heat threshold temperature substantially above the T liquidus of the alloy, and quenching the melt at a high cooling rate such that the cooling material is kept substantially amorphous during cooling to form the metallic glass. In various embodiments, the melt is atomized during cooling to form the metallic glass-forming powder.

First claim

The invention claimed is:

1. A method of forming a metallic glass part comprising:
heating a metallic glass-forming alloy powder to a temperature over the T liquidus of the alloy to form a metallic glass-forming alloy melt;
quenching the metallic glass-forming alloy melt to a temperature below the glass-transition temperature;
forming a heat-treated metallic glass-forming alloy powder;
heating at least a portion of the heat-treated metallic glass-forming powder with an electron beam or laser to a temperature above the glass transition temperature of the alloy to form a fused metallic glass; and
cooling the fused metallic glass to form the metallic glass part.

2. The method of claim 1 wherein the quenching and forming steps are simultaneous.

3. The method of claim 1 wherein the heat-treated metallic glass-forming alloy powder is heated to above the T liquidus in a time of less than 5 seconds.

4. The method of claim 2 wherein the metallic glass-forming alloy melt is gas atomized to form a heat-treated metallic glass-forming powder.

5. The method of claim 1 wherein the quenching and forming steps are consecutive.

6. The method of claim 1 wherein the metallic glass-forming alloy powder is heated to a temperature at least 25% greater than the T liquidus of the alloy.

7. The method of claim 1 wherein the metallic glass-forming alloy powder is heated to a temperature at least 40% greater than the T liquidus of the alloy.

8. The method of claim 1 wherein the metallic glass-forming alloy powder is heated to a temperature over the T GFA of the alloy, wherein the T GFA is the temperature associated with substantial improvement in glass-forming ability compared to the glass-forming ability demonstrated by heating the alloy melt above T liquidus of the alloy.

9. The method of claim 2 wherein the metallic glass-forming alloy melt is liquid atomized to form a heat-treated metallic glass-forming powder.

10. The method of claim 1 , wherein the quenching is at a cooling rate sufficiently rapid to create an amorphous alloy.

11. The method of claim 1 , wherein the heat-treated metallic glass-forming alloy powder is crystalline.

12. The method of claim 1 , wherein the heat-treated metallic glass-forming alloy powder is amorphous.

13. The method of claim 1 , wherein the heat-treated metallic glass-forming alloy powder is a combination of crystalline and amorphous.

14. The method of claim 1 wherein forming a heat-treated metallic glass alloy powder comprises milling the quenched metallic glass-forming alloy melt.

15. The method of claim 1 , further comprising:
depositing a layer of heat-treated metallic glass-forming alloy powder onto a metallic glass layer prior to heating at least a portion of the metallic glass-forming powder.

16. A method of forming a metallic glass composite comprising:
depositing a layer of metallic powder, a portion of which is a metallic glass-forming alloy and a portion of which is a non-metallic glass-forming material;
locally heating the metallic glass-forming alloy portion at a first temperature and heating the non-metallic glass-forming material portion at a second temperature, and
cooling the heated metallic glass-forming alloy portion and non-metallic glass-forming powder material to fuse the layer of metallic powder and form the metallic glass composite.

17. The method of claim 16 , where the non-metallic glass-forming material is a magnetic alloy.

18. The method of claim 16 , where the non-metallic glass-forming material is a ductile alloy.

Assignees

• Apple Inc

Inventors

• Poole Joseph C
• Waniuk Theodore A
• Mattlin Jeffrey L
• Nashner Michael S
• Prest Christopher D

Classifications

• B22F7/02

  of composite layers {(B22F7/002 takes precedence)} · CPC title

• C22C45/00

  Amorphous alloys (making amorphous non-ferrous alloys C22C1/11) · CPC title

• C21D2251/00

  Treating composite or clad material · CPC title

• C23C24/106 Primary

  Coating with metal alloys or metal elements only · CPC title

• C22C1/11 Primary

  Making amorphous alloys · CPC title