Non-aqueous sound-absorbing compound with a solvent-free polyacrylate binder

Patent metadata

Field	Value
Publication number	US-9969860-B2
Application number	US-201314400674-A
Country	US
Kind code	B2
Filing date	Apr 25, 2013
Priority date	May 22, 2012
Publication date	May 15, 2018
Grant date	May 15, 2018

Abstract

A description is given of a nonaqueous sound deadener composition comprising (a) a nonpulverulent, solvent-free polyacrylate binder having a K value in the range from 10 to 35, measured as a 1% strength solution in tetrahydrofuran; and (b) inorganic fillers. Also described is a method for damping oscillations or vibrations of components of vehicles and machines, using the sound deadener composition of the invention.

First claim

The invention claimed is:

1. A nonaqueous sound deadener composition, comprising
(a) at least one nonpulverulent, solvent-free polyacrylate binder having a K value in the range from 10 to 35, measured as a 1% strength solution in tetrahydrofuran at 21° C., wherein the polyacrylate binder consists of reacted units of methyl (meth)acrylate, a C2 to C4 alkyl acrylate, and (meth)acrylic acid, and, optionally, one or more monomers selected from the group consisting of a vinylaromatic having up to 20 C atoms, an ethylenically unsaturated nitrile, a vinyl halide, a vinyl ether of an alcohol comprising 1 to 10 C atoms, an aliphatic hydrocarbon having 2 to 8 C atoms and one or two double bonds, and mixtures of these monomers, wherein the polyacrylate binder is at least 60% by weight of C 1 to C 10 alkyl (meth)acrylates; and
(a1) one or more crosslinkers; and
(b) one or more inorganic fillers wherein the inorganic filler is present in an amount of 40% to 90% by weight based on the total weight of the nonaqueous sound deadener composition;
wherein the K value of the polyacrylate binder is measured as a 1% solution in THF at 21° C. before the polyacrylate binder is reacted with the crosslinkers.

2. The sound deadener composition according to claim 1 , wherein the polyacrylate binder has a glass transition temperature in the range from −60 to +80° C.

3. The sound deadener composition according to claim 1 , wherein the polyacrylate binder does not have a core-shell morphology.

4. The sound deadener composition according to claim 1 , wherein the polyacrylate binder at 130° C. has a zero-shear viscosity of not more than 40 Pas.

5. The sound deadener composition according to claim 1 , wherein the polyacrylate binder consists of methyl (meth)acrylate, C 2 to C 4 alkyl acrylate, and
0.5% to 15% by weight of (meth)acrylic acid.

6. The sound deadener composition according to claim 1 , comprising
(a) 5% to 35% by weight of the polyacrylate binder, and
(c) 0% to 50% by weight of auxiliaries.

7. The sound deadener composition according to claim 6 , wherein the inorganic fillers are selected from the group consisting of kaolin, chalk, barium sulfate, carbon black, graphite, talc, clay minerals, microdolomite, finely ground quartz, and mica, and the auxiliaries are present to an extent of at least 0.1% by weight and are selected from the group consisting of thickeners, rheological additives, resins, plasticizers, cosolvents, defoamers, preservatives, antifreeze agents, and pigment dispersants.

8. The sound deadener composition according to claim 1 , wherein the sound deadener composition is solvent-free.

9. The sound deadener composition according to claim 1 , further comprising a pulverulent binder and optionally a plasticizer for the pulverulent binder.

10. The sound deadener composition according to claim 1 , wherein the crosslinker is reactive with acid groups.

11. The sound deadener composition according to claim 1 , wherein the crosslinker is selected from the group consisting of isocyanate crosslinkers.

12. The sound deadener composition according to claim 1 , wherein the polyacrylate binder has a K value of less than or equal to 25 and the sound deadener composition comprises at least one plasticizer.

13. The sound deadener composition according to claim 1 , wherein the crosslinker is a polymeric epoxy crosslinker and/or an oligomeric epoxy crosslinker.

14. The sound deadener composition according to claim 1 , wherein the crosslinker is an epoxide-modified acrylic polymer, the K value of the polyacrylate binder is from 14.4 to 32.1, measured as a 1% strength solution in tetrahydrofuran at 21° C., wherein the inorganic filler is present in an amount of 70% to 85% by weight based on the total weight of the nonaqueous sound deadener composition.

15. The nonaqueous sound deadener composition of claim 1 , wherein the nonpulverulent, solvent-free polyacrylate binder consists of reacted units of the methyl (meth)acrylate, the C2 to C4 alkyl acrylate, and the (meth)acrylic acid.

16. A method of damping vibrations of bodywork parts of a vehicle, comprising applying the sound deadener composition according to claim 1 to the bodywork parts.

17. A method for damping oscillations or vibrations of components of vehicles or machines, comprising
(1) providing the sound deadener composition according to claim 1 , and
(2) applying the sound deadener composition to a component of a vehicle or of a machine, and optionally subjecting the component to drying and/or to crosslinking.

18. A substrate at least partly coated with the sound deadener composition according to claim 1 .

19. An automotive vibration dampening system, comprising:
an automotive bodywork comprising a metal substrate and a layer of the sound deadener composition of claim 1 adhered to the metal substrate.

Assignees

• Basf Se

Inventors

• Wulff Dirk
• Licht Ulrike
• Preishuber-Pfluegl Peter
• Weiss Axel

Classifications

• C08K2003/3045

  Sulfates · CPC title

• C08K2003/265

  Calcium, strontium or barium carbonate · CPC title

• C09J133/14 Primary

  of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen · CPC title

• C08K3/34 Primary

  Silicon-containing compounds · CPC title

• C08K3/26

  Carbonates; Bicarbonates · CPC title