Foam materials

Patent metadata

Field	Value
Publication number	US-9969854-B2
Application number	US-201415107351-A
Country	US
Kind code	B2
Filing date	Dec 18, 2014
Priority date	Dec 23, 2013
Publication date	May 15, 2018
Grant date	May 15, 2018

Abstract

A foamable composition comprising from 60 to 99.88% by weight (% wt.) of at least one poly(aryl ether sulfone), from 0.10 to 10.00% by weight (% wt.) of at least one olefinic polymer, from 0.01 to 5.00% by weight (% wt.) of at least one tetrazole compound and from 0.01 to 2.50% by weight (% wt.) of at least one additive selected from the group of titanium dioxide (TiO2), clays, talc, silicates, silica, aluminates, barites, titanates, borates, nitrides, carbon-based materials or combinations thereof, all % wt. are relative to the total weight of the composition (C). Foam materials made from said foamable compositions and articles made from said foam materials.

First claim

The invention claimed is:

1. A foamable composition (C) comprising:
(i) from 60 to 99.88 wt. % of at least one poly(aryl ether sulfone) (PAES) polymer, wherein more than 50% by moles of the recurring units of the poly(aryl ether sulfone) (PAES) polymer are recurring units (R PAES ) selected from the group consisting of those of formulae (S-A) to (S-C):

wherein:
each of R′, equal to or different from each other, is selected from the group consisting of halogen, alkyl, alkenyl, alkynyl, aryl, ether, thioether, carboxylic acid, ester, amide, imide, alkali or alkaline earth metal sulfonate, alkyl sulfonate, alkali or alkaline earth metal phosphonate, alkyl phosphonate, amine, and quaternary ammonium;
j′ is zero or is an integer from 0 to 4;
T is a bond or a divalent group optionally comprising one or more than one heteroatom;

(ii) from 0.10 to 10.00 wt. % of at least one olefinic polymer selected from the group consisting of a very low density polyethylene, a linear low density polyethylene, a low density polyethylene, a high density polyethylene, a propylene homopolymer, a propylene copolymer, a linear homogeneous ethylene/alpha-olefin copolymer, a homogeneous ethylene/alpha-olefin copolymer having long chain branching,
(iii) from 0.01 to 5.00 wt. % of at least one tetrazole compound selected from the group consisting of those of formulae T-1, T-2, T-3 and T-4:

wherein:
R 1 is selected from a group consisting of alkyl, cycloalkyl, arylalkyl, and aryl group,
R 2 is selected from a group consisting of hydrogen, alkyl, cycloalkyl, hydroxyalkyl, polyhydroxyalkyl, aryl, alkylaryl, aralkylene, alkenyl, alkenylaryl, and alkenylaralkylene group,
R 1′ and R 2′ , equal to or different from each other and at each occurrence, is independently selected from a group consisting of a bond or a divalent group optionally comprising one or more than one heteroatom,
n is a number 2 or 3, M is a metal cation selected from the group consisting of barium, calcium, zinc lead, or aluminium, and

(iv) from 0.01 to 2.50 wt. % of at least one additive selected from the group of titanium dioxide (TiO 2 ), clays, talc, silicates, silica, aluminates, barites, titanates, borates, nitrides, carbon-based materials or combinations thereof,
all wt. % are relative to the total weight of the composition (C).

2. The foamable composition (C) according to claim 1 , wherein the poly(aryl ether sulfone) (PAES) polymer is a bisphenol A polysulfone wherein more than 50% by moles of the recurring units of said bisphenol A polysulfone are recurring units (R a ) of formula (A):

3. The foamable composition (C) according to claim 1 , wherein the olefinic polymer is selected from the group consisting of a very low density polyethylene, a linear low density polyethylene, a low density polyethylene, a propylene homopolymer, or a propylene copolymer.

4. The composition (C) according to claim 1 , wherein the tetrazole compound is of formula T-1:

wherein:
R 1 is selected from a group consisting of phenyl, naphthyl and substituted phenyl groups of formula:

wherein:
each of R, equal to or different from each other, is selected from the group consisting of halogen, alkyl, haloalkyl, alkenyl, alkynyl, aryl, ether, thioether, carboxylic acid, ester, amide, imide, alkali or alkaline earth metal sulfonate, alkyl sulfonate, alkali or alkaline earth metal phosphonate, alkyl phosphonate, amine, and quaternary ammonium, nitro and nitroso, 5-tetrazolyl;
k is zero or is an integer from 0 to 4; and
R 2 is selected from a group consisting of hydrogen, C 1 -C 10 -alkyl, C 3 -C 6 -cycloalkyl, phenyl, naphthyl and substituted phenyl groups of formula:

wherein:
each of R′, equal to or different from each other, is selected from the group consisting of halogen, alkyl, haloalkyl, alkenyl, alkynyl, aryl, ether, thioether, carboxylic acid, ester, amide, imide, alkali or alkaline earth metal sulfonate, alkyl sulfonate, alkali or alkaline earth metal phosphonate, alkyl phosphonate, amine, and quaternary ammonium, nitro and nitroso, 5-tetrazolyl; and
j is zero or is an integer from 0 to 4.

5. The foamable composition (C) according to claim 1 , wherein the additive is selected from the group of TiO 2 , silicates, and talc.

6. The composition (C) according to claim 1 comprising from 0.01 to 1.00 wt. % of the additive.

7. The composition (C) according to claim 1 further comprising one or more additional ingredient (I) other than the poly(aryl ether sulfone) PAES polymer, the olefinic polymer, the tetrazole compound, and the additive, selected from the group consisting of (i) colorants, (ii) pigments, (iii) light stabilizers, (iv) heat stabilizers, (v) antioxidants, (vi) acid scavengers, (vii) processing aids, (viii) internal lubricants and/or external lubricants, (ix) flame retardants, (x) smoke-suppressing agents, (xi) anti-static agents, (xii) anti-blocking agents, (xiii) conductivity additives, (xiv) surfactants, (xv) reinforcing fillers additives, (xvi) impact modifiers, and (xvii) release agents.

8. A process for manufacturing the foamable composition (C) according to claim 1 , which comprises mixing:
the at least one poly(aryl ether sulfone) (PAES) polymer,
the at least one olefinic polymer,
the at least one tetrazole compound, and
the at least one additive, and
optionally, one or more than one additional ingredient (I).

9. The process according to claim 8 , wherein the mixing is carried out by dry blending, melt mixing, or a combination of dry blending and melt mixing.

10. A foam material made from the foamable composition (C) according to claim 1 .

11. A process for making the foam material of claim 10 by foaming the foamable composition (C), wherein the foaming process is selected from a group consisting of pressure cell processes, autoclave processes, extrusion processes, direct injection processes, and bead foaming.

12. An article comprising at least one component comprising the foam material according to claim 10 .

13. The article of according to claim 12 , wherein said article is an aircraft structural component, an automotive structural component, an oil and gas structural component, a medical structural component, or a wire and cable component.

14. The article of according to claim 13 , wherein the article is a wire and cable component.

15. The foamable composition according to claim 1 , wherein T is selected from the group consisting of a bond, —CH 2 —, —C(O)—, —C(CH 3 ) 2 —, —C(CF 3 ) 2 —, —C(═CCl 2 )—, —C(CH 3 )(CH 2 CH 2 COOH)—, —SO 2 —, and a group of formula:

Assignees

• Solvay Specialty Polymers Usa
• Solvay Specialty Polymers Usa

Inventors

• Kenkare Nirupama
• Kwan Kermit S

Classifications

• C08J9/0066

  Use of inorganic compounding ingredients · CPC title

• C08J2207/06

  Electrical wire insulation · CPC title

• C08J2201/03

  Extrusion of the foamable blend · CPC title

• C08L81/06

  Polysulfones; Polyethersulfones · CPC title

• C08J9/12

  by a physical blowing agent · CPC title