Method and apparatus for co-production of methanol and hydrogen

Patent metadata

Field	Value
Publication number	US-9969666-B1
Application number	US-201715637189-A
Country	US
Kind code	B1
Filing date	Jun 29, 2017
Priority date	Mar 13, 2017
Publication date	May 15, 2018
Grant date	May 15, 2018

Abstract

A method for the co-production of hydrogen and crude methanol, including; a hydrocarbon processing reforming or gasification process generating a syngas stream comprising hydrogen, carbon monoxide and carbon dioxide; introducing at least a portion of the syngas stream to a once-through methanol synthesis reactor: introducing at least a portion of the stream from methanol reactor to a separation device separating this stream into a crude methanol stream and methanol synthesis off gas stream; introducing at least a portion of the methanol synthesis off gas to a hydrogen separation device, thereby producing a pure hydrogen stream.

First claim

What is claimed is:

1. A method for the co-production of hydrogen and crude methanol, comprising; a hydrocarbon processing reforming or gasification process generating a syngas stream comprising hydrogen, carbon monoxide and carbon dioxide; introducing at least a portion of the syngas stream to a once-through methanol synthesis reactor: introducing at least a portion of the stream from methanol reactor to a separation device separating this stream into a crude methanol stream and methanol synthesis off gas stream; introducing at least a portion of the methanol synthesis off gas to a hydrogen separation device, thereby producing a pure hydrogen stream, wherein at least a fraction of the syngas stream undergoes a water gas shift reaction prior to introduction into the once-through methanol synthesis reactor.

2. The method of claim 1 , further comprising introducing the crude methanol stream into a methanol distillation device, thereby producing a pure methanol stream.

3. The method of claim 1 , wherein the at least a portion of the syngas stream is introduced into the once-through methanol synthesis reactor without prior compression of the syngas.

4. The method of claim 1 , wherein at least a portion of the syngas stream is introduced into the once-through methanol synthesis reactor after compression of the syngas.

5. The method of claim 2 , wherein the hydrocarbon processing reforming or gasification process generating a syngas stream comprises a fuel gas stream, and wherein at least a portion of the methanol distillation off-gas stream is returned to the fuel gas stream.

6. The method of claim 2 , wherein the hydrocarbon processing reforming or gasification process generating a syngas stream comprises a process feed stream, and wherein at least a portion of the methanol distillation off-gas stream is returned to the process feed stream.

7. The method of claim 1 , wherein the hydrogen separation device is a pressure swing adsorption unit.

8. The method of claim 1 , wherein the hydrogen separation device is a membrane separation unit.

9. The method of claim 1 , where the hydrogen from the hydrogen purification device purifying the methanol synthesis off gas is further compressed by a hydrogen compressor.

10. The method of claim 1 , where the synthesis gas generating device is an autothermal reformer or a partial oxidation reactor.

11. The method of claim 1 , where the synthesis gas generation device is a steam methane reformer.

12. The method of claim 1 , where at least a portion of methanol off gas is utilized as fuel in the steam methane reformer or any other combustion system such as fired process heater or fired steam boilers.

13. The method of claim 1 , wherein at least a portion of the produced syngas is bypassing the methanol reactor system and is directly introduced to the hydrogen purification.

14. The method of claim 1 , wherein at least a fraction of the methanol synthesis off gas is recycled back to the feed stream of the synthesis gas reactor.

15. The method of claim 1 , wherein at least a fraction the methanol synthesis off gas is recycled back to the inlet of the methanol reactor system.

16. The method of claim 1 , wherein at least a fraction of the PSA off gas is recycled back to the feed stream of the synthesis gas reactor.

17. The method of claim 1 , wherein at least a fraction of the PSA off gas is recycled back to the inlet of the methanol reactor system.

Assignees

• Air Liquide
• Air Liquide

Inventors

• Roesch Alexander
• Guillard Alain
• Castillo-Welter Frank
• Schuhmann Timm P
• Schmid Mcguinness Teja
• Oelmann Tobias

Classifications

• C01B3/56

  by contacting with solids; Regeneration of used solids · CPC title

• C01B3/501

  by diffusion · CPC title

• C01B2203/1241

  Natural gas or methane · CPC title

• C01B2203/0883

  by indirect heat exchange · CPC title

• C01B3/48

  followed by reaction of water vapour with carbon monoxide · CPC title