Method for separating olefins with gentle cleavage

Patent metadata

Field	Value
Publication number	US-9969662-B2
Application number	US-201314390922-A
Country	US
Kind code	B2
Filing date	Apr 2, 2013
Priority date	Apr 5, 2012
Publication date	May 15, 2018
Grant date	May 15, 2018

Abstract

In a process for producing olefins, a hydrocarbon-containing feed is fed into a cracking furnace where relatively long-chain hydrocarbons of the hydrocarbon-containing feed are cracked at least partly to form shorter-chain olefins, encompassing ethylene and propylene. Cracking gas ( 1 ) formed during cracking is conveyed in succession through an upper section ( 11 ) and a lower section ( 12 ) of a scrubbing column ( 10 ) in countercurrent to a liquid scrubbing medium ( 43, 31 ), is proposed. A fraction ( 43 ) rich in petroleum spirit is used in the lower section ( 11 ) of the scrubbing column ( 10 ) and a water-rich fraction ( 31 ) is used in the upper section ( 11 ) of the scrubbing column ( 10 ) as scrubbing medium ( 43, 31 ). A plant configured for carrying out the process is likewise provided by the present invention.

First claim

The invention claimed is:

1. A process for producing olefins, comprising:
feeding a hydrocarbon-containing feed into a cracking furnace where hydrocarbons of the hydrocarbon-containing feed are at least partly cracked to form a cracking gas encompassing ethylene and propylene, and
passing said cracking gas ( 1 ) in succession through a lower section ( 11 ) and an upper section ( 12 ) of a scrubbing column ( 10 ), wherein a fraction ( 43 ) rich in petroleum spirit is used in said lower section ( 11 ) of the scrubbing column ( 10 ) as liquid scrubbing medium in countercurrent flow to said cracking gas, and a water-rich fraction ( 31 ) is used in said upper section ( 12 ) of the scrubbing column ( 10 ) as liquid scrubbing medium in countercurrent flow to said cracking gas, wherein said fraction ( 43 ) rich in petroleum spirit is a hydrocarbon fraction of which 80% boils at a temperature of 130° C. at atmospheric pressure,
wherein said scrubbing column ( 10 ) is divided into said lower section ( 11 ) and said upper section ( 12 ) by a tray ( 14 ),
wherein a liquid petroleum spirit-water phase ( 51 ) is taken off from said tray ( 14 ) of said scrubbing column ( 10 ), and said liquid petroleum spirit-water phase ( 51 ) is separated into a liquid petroleum spirit fraction and a liquid water fraction and,
wherein said liquid petroleum spirit fraction is at least partly introduced into the lower section ( 11 ) of said scrubbing column ( 10 ) as said fraction ( 43 ) rich in petroleum spirit, and said liquid water fraction is at least partly introduced as said water-rich fraction ( 31 ) into the upper section ( 12 ) of said scrubbing column ( 10 ).

2. The process as claimed in claim 1 , wherein said cracking furnace is operated under conditions such that the cracking gas ( 1 ) contains propylene and ethylene in a propylene to ethylene ratio of at least 0.7 kg/kg.

3. The process as claimed claim 1 , wherein said cracking gas ( 1 ), directly at the output of the cracking furnace, has a temperature in the range from 720° C. to 800° C. and/or a pressure in the range from 1 barg to 4 barg.

4. The process as claimed in claim 1 , wherein a liquid phase ( 4 ) containing heavy oils and particles of carbonaceous material is taken off from the bottom of said scrubbing column ( 10 ) and a cracking gas ( 5 ) freed of particles of carbonaceous material, heavy oils, and a petroleum spirit fraction is discharged from the top of said scrubbing column ( 10 ).

5. The process as claimed in claim 4 , wherein said liquid phase ( 4 ) taken off from the bottom of the scrubbing column ( 10 ) is separated into a first liquid phase ( 63 ) containing the particles of carbonaceous material and a second liquid phase ( 62 ) containing a heavy oil fraction.

6. The process as claimed in claim 5 , wherein light hydrocarbons ( 45 ) present in the second liquid phase ( 62 ) are stripped out of said second liquid phase ( 62 ) and are recirculated to the scrubbing column ( 10 ).

7. The process as claimed in claim 1 , wherein said lower section ( 11 ) of the scrubbing column ( 10 ) contains cascade trays and said upper section ( 12 ) of the scrubbing column ( 10 ) contains sieve trays, valve trays, mesh packing, structured packing and/or beds of random packing elements.

8. The process as claimed in claim 1 , wherein part of said fraction ( 43 ) rich in petroleum spirit used as the scrubbing medium in the lower section ( 11 ) of the scrubbing column ( 10 ) is obtained from the hydrocarbon-containing feed.

9. The process as claimed claim 1 , wherein said cracking gas ( 1 ), directly at the output of the cracking furnace, has a temperature in the range from 720° C. to 800° C. and/or a pressure in the range from 2.5 barg to 4 barg.

10. The process as claimed in claim 1 , wherein said tray ( 14 ) is a chimney neck tray.

11. The process as claimed in claim 1 , wherein said cracking furnace is operated under conditions such that the cracking gas ( 1 ) contains propylene and ethylene in a propylene to ethylene ratio of from 0.7 kg/kg to 1.6 kg/kg.

12. The process as claimed in claim 1 , wherein steam is added to the hydrocarbon-containing feed upstream of the cracking furnace so that the mass ratio of steam to hydrocarbons in the hydrocarbon-containing feed is in the range from 0.15 kg/kg to 0.45 kg/kg.

13. The process as claimed in claim 5 , wherein said liquid phase ( 4 ) taken off from the bottom of the scrubbing column ( 10 ) is separated in a centrifugal separator into said first liquid phase ( 63 ) containing the particles of carbonaceous material and said second liquid phase ( 62 ) containing the heavy oil fraction.

14. The process as claimed in claim 13 , wherein said first liquid phase ( 63 ) containing the particles of carbonaceous material is sent to a filter ( 72 ) wherein a stream containing the particles of carbonaceous material ( 64 ) is separated from a liquid phase ( 65 ) and wherein the liquid phase ( 65 ) is recirculated to the cracking gas ( 1 ).

15. The process as claimed in claim 5 , wherein light hydrocarbons ( 45 ) present in the second liquid phase ( 62 ) are stripped out of said second liquid phase ( 62 ) and are recirculated to the lower section ( 11 ) of said scrubbing column ( 10 ).

Assignees

• Linde Ag

Inventors

• Pham Duc Tuat
• Schmigalle Holger

Classifications

• C10G9/00 Primary

  Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils · CPC title

• C10G9/36

  with heated gases or vapours · CPC title

• C07C4/04

  Thermal processes {(C07C4/025 takes precedence)} · CPC title

• C07C11/04

  Ethene · CPC title

• C07C7/11 Primary

  by absorption, i.e. purification or separation of gaseous hydrocarbons with the aid of liquids · CPC title