Combination of novel nitrification inhibitors and biopesticides as well as combination of (thio)phosphoric acid triamides and biopesticides

Patent metadata

Field	Value
Publication number	US-9968092-B2
Application number	US-201515327819-A
Country	US
Kind code	B2
Filing date	Apr 16, 2015
Priority date	Apr 17, 2014
Publication date	May 15, 2018
Grant date	May 15, 2018

Abstract

A composition including (a) at least one (thio)phosphoric acid triamide (T) according to the general formula (Ia)

R a1 R a2 N—P(X)(NH 2 ) 2   (Ia)

wherein X is oxygen or sulfur; R a1 is a C 1 to C 20 alkyl, C 3 to C 20 cycloalkyl, C 6 to C 20 aryl, or dialkylaminocarbonyl group; R a2 is H, or R a1 and R a2 together with the nitrogen atom linking them define a 5- or 6-membered saturated or unsaturated heterocyclic radical, which optionally comprises 1 or 2 further heteroatoms selected from the group consisting of nitrogen, oxygen, and sulfur; and (b) at least one biopesticide.

First claim

The invention claimed is:

1. A composition comprising:
a) at least one (thio)phosphoric acid triamide (T) according to the general formula (Ia)
Ra1Ra2N—P(X)(NH2)2  (Ia)

wherein
X is oxygen or sulfur;
Ra1 is a C1 to C20 alkyl, C3 to C20 cycloalkyl, C6 to C20 aryl, or dialkylaminocarbonyl group;
Ra2 is H, or
Ra1 and Ra2 together with the nitrogen atom linking them define a 5- or 6-membered saturated or unsaturated heterocyclic radical, which optionally comprises 1 or 2 further heteroatoms selected from the group consisting of nitrogen, oxygen, and sulfur,
and
b) at least one biopesticide.

2. The composition according to claim 1 , wherein the biopesticide (L) is selected from the group consisting of (L1), (L3), (L5), (L7) and (L8), wherein:
(L1) comprises microbial pesticides having at least one of fungicidal, bactericidal, viricidal and plant defense activator activity selected from the group consisting of:
(L11) Ampelomyces quisqualis,
(L12) Aspergillus flavus,
(L13) Aureobasidium pullulans,
(L14) Bacillus amyloliquefaciens,
(L15) Bacillus mojavensis,
(L16) Bacillus pumilus,
(L17) Bacillus simplex,
(L18) Bacillus solisalsi,
(L19) Bacillus subtilis,
(L20) Bacillus subtilis var. amyloliquefaciens,
(L21) Candida oleophila , or C. saitoana,
(L22) Clavibacter michiganensis (bacteriophages),
(L23) Coniothyrium minitans,
(L24) Cryphonectria parasitica,
(L25) Cryptococcus albidus,
(L26) Dilophosphora alopecuri,
(L27) Fusarium oxysporum,
(L28) Clonostachys rosea f. catenulate (also named Gliocladium catenulatum ),
(L29) Gliocladium roseum,
(L30) Lysobacter antibioticus, or L. enzymogenes,
(L31) Metschnikowia fructicola,
(L33) Microsphaeropsis ochracea,
(L34) Muscodor albus,
(L35) Paenibacillus polymyxa,
(L36) Pantoea vagans,
(L37) Phlebiopsis gigantea,
(L38) Pseudomonas sp ., or Pseudomonas chloraphis,
(L39) Pseudozyma flocculosa,
(L40) Pichia anomala,
(L41) Pythium oligandrum,
(L42) Sphaerodes mycoparasitica,
(L43) Streptomyces griseoviridis, S. lydicus , or S.violaceusniger,
(L44) Talaromyces flavus,
(L45) Trichoderma asperellum, T. atroviride, T. fertile, T. gamsii, T. harmatum, T. harzianum, T. stromaticum, T. virens (also named Gliocladium virens ), T. viride , or mixture of T. harzianum and T. viride , or mixture of T. polysporum and T. harzianum,
(L46) Typhula phacorrhiza,
(L47) Ulocladium oudemansii,
(L48) Verticillium dahlia , and
(L49) zucchini yellow mosaic virus (avirulent strain);

(L3) comprises microbial pesticides with at least one of insecticidal, acaricidal, molluscidal and nematicidal activity selected from the group consisting of:
(L51) Agrobacterium radiobacter,
(L52) Bacillus cereus,
(L53) Bacillus firmus,
(L54) Bacillus thuringiensis, B. t . ssp. aizawai, B. t . ssp. israelensis, B. t . ssp. galleriae, B. t . ssp. kurstaki , or B. t. ssp. tenebrionis,
(L55) Beauveria bassiana , or B. brongniartii,
(L56) Burkholderia sp.,
(L57) Chromobacterium subtsugae,
(L59) Cryptophlebia leucotreta granulovirus (CrleGV),
(L60) Isaria fumosorosea,
(L61) Heterorhabditis bacteriophora,
(L62) Lecanicillium longisporum , or L. muscarium (formerly Verticillium lecanii ),
(L63) Metarhizium anisopliae , or M. anisopliae var. acridum,
(L64) Nomuraea rileyi,
(L65) Paecilomyces fumosoroseus , or P. lilacinus,
(L66) Paenibacillus popilliae,
(L67) Pasteuria spp., P. nishizawae, P. penetrans, P. ramose, P. reneformis, P. thornea , or P. usgae,
(L68) Pseudomonas fluorescens , and
(L69) Steinernema carpocapsae, S. feltiae , or S. kraussei;

(L5) comprises microbial pesticides with at least one of plant stress reducing, plant growth regulator, plant growth promoting and yield enhancing activity selected from the group consisting of:
(L81) Azospirillum amazonense, A. brasilense, A. lipoferum, A. irakense , or A. halopraeferens,
(L82) Bradyrhizobium sp., B. elkanii, B. japonicum, B. liaoningense , or B. lupini,
(L83) Delftia acidovorans,
(L84) VA mycorrhiza selected from the genera Glomus, Acaulospora, Entrophosphora, Gigaspora, Scutellospora and Sclerocytis,
(L85) VA mycorrhiza selected from the group consisting of Glomus fasciculatum, G. caledonium, G. mosseae, G. versiforme, G. intraradices and G. etunicatum,
(L86) Mesorhizobium sp.,
(L87) Paenibacillus alvei,
(L88) Penicillium bilaiae,
(L89) Rhizobium leguminosarum bv. phaseoli, R. l. trifolii, R. l . bv. viciae , or R. tropici,
(L90) Sinorhizobium meliloti,
(L91) Enterobacter spp., E. ludwigii, E. aerogenes, E. amnigenus, E. agglomerans, E. arachidis, E. asburiae, E. cancerogenous, E. cloacae, E. cowanii, E. dissolvens, E. gergoviae, E. helveticus, E. hormaechei, E. intermedius, E. kobei, E. mori, E. nimipressuralis, E. oryzae, E. pulveris, E. pyrinus, E. radicincitans, E. taylorae, E. turicensis , or E. sakazakii , and
(L92) Oxalobacteraceae spp., Herbaspirillum seropedicae (DSM No.: 6445) (free-living nitrogen fixing bacterium), Janthinobacterium lividum (DSM No.: 1522) (violacein-producing bacterium), or Pseudoduganella violaceinigra (DSM No.: 15887) (violacein-producing bacterium);

(L7) comprises metabolites produced by the microbial pesticides selected from the group consisting of:
(L93) siderophores, bacillibactin
(L94) antibiotics selected from the group consisting of zwittermicin-A, kanosamine, polyoxine, bacilysin, violacein
(L95) enzymes selected from the group consisting of alpha-amylase, chitinases, pektinases, phosphatase (acid and alkaline) and phytase
(L96) phytohormones and precursors thereof and volatile compounds, selected from the group consisting of auxines, gibberellin-like substances, cytokinin-like compounds, acetoin, 2,3-butanediol, ethylene, indole acetic acid,
(L97) lipopeptides selected from the group consisting of iturins, plipastatins, surfactins, agrastatin, agrastatin A, bacillomycin, bacillomycin D, fengycin,
(L98) antibacterial polyketides selected from the group consisting of difficidin, macrolactin and bacilaene, and
(L99) antifungal metabolites selected from the group consisting of pyrones, cytosporone, 6-pentyl-2H-pyran-2-one (also termed 6-pentyl-a-pyrone), koninginins (complex pyranes), and

(L8) comprises biochemical pesticides with at least one of insecticidal, acaricidal, molluscidal, pheromone and nematicidal activity selected from the group consisting of:
L-carvone, citral, (E,Z)-7,9-dodecadien-1-yl acetate, ethyl formate, (E,Z)-2,4-ethyl decadienoate (pear ester), (Z,Z,E)-7,11,13-hexadecatrienal, heptyl butyrate, isopropyl myristate, lavanulyl senecioate, cis-jasmone (B.27), 2-methyl 1-butanol, methyl eugenol, methyl jasmonate (B.28), (E,Z)-2,13-octadecadien-1-ol, (E,Z)-2,13-octadecadien-1-ol acetate, (E,Z)-3,13-octadecadien-1-ol, R-1-octen-3-ol, pentatermanone, potassium silicate, sorbitol actanoate, (E,Z,Z)-3,8,11-tetradecatrienyl acetate, (Z,E)-9,12-tetradecadien-1-yl acetate, Z-7-tetradecen-2-one, Z-9-tetradecen-1-yl acetate, Z-11-tetradecenal, Z-11-tetradecen-1-ol, Acacia negra extract, extract of grapefruit seeds and pulp, extract of Chenopodium ambrosiodes , Catnip oil, Neem oil (B.29), Quillay extract (B.30), and Tagetes oil.

3. The composition according to claim 1 , wherein in the general formula (Ia) of (T) X is sulfur and/or wherein in the general formula (Ia) of (T) R a1 is C 1 -C 20 alkyl and R a2 is H.

4. The composition according to claim 1 , wherein the (thio)phosphoric acid triamide (T) is one of N-n-butylthiophosphoric acid triamide (NBPT) and N-n-propylthiophosphoric acid triamide (NPPT).

Assignees

• Basf Se

Inventors

• Nave Barbara
• Dickhaut Joachim
• Sisay Mihiret Tekeste
• Wissemeier Alexander
• Zerulla Wolfram
• Pasda Gregor
• Schmid Markus

Classifications

• A01N31/14

  Ethers · CPC title

• A01N57/28 Primary

  containing acyclic or cycloaliphatic radicals · CPC title

• Y02P60/21

  Dinitrogen oxide [N2O], e.g. using aquaponics, hydroponics or efficiency measures · CPC title