Manufacturing method of sintered body for electrolyte and electrolyte for fuel cell using the same

Patent metadata

Field	Value
Publication number	US-9966624-B2
Application number	US-201615346105-A
Country	US
Kind code	B2
Filing date	Nov 8, 2016
Priority date	Jul 20, 2016
Publication date	May 8, 2018
Grant date	May 8, 2018

Abstract

Provided is a method for manufacturing a sintered body for an electrolyte and an electrolyte for a fuel cell using the same. More particularly, the following disclosure relates to a method for preparing an electrolyte having a firm thin film layer by using a sintered body having controlled sintering characteristics, and application of the electrolyte to a solid oxide fuel cell. It is possible to control the sintering characteristics of a sintered body through a simple method, such as controlling the amounts of crude particles and nanoparticles. In addition, an electrode using the obtained sintered body having controlled sintering characteristics is effective for forming a firm thin film layer. Further, such an electrolyte having a firm thin film layer formed thereon inhibits combustion of fuel with oxygen when it is applied to a fuel cell, and thus shows significantly effective for improving the quality of a cell.

First claim

What is claimed is:

1. A method for manufacturing a sintered body for an electrolyte, which comprises:
(i) mixing a solution containing preliminarily formed crude particles dispersed therein with a nanoparticle precursor solution for preparing nanoparticles;
(ii) a combustion step wherein nanoparticles are prepared on the surface of the crude particles from the resultant mixture; and
(iii) a calcination step wherein impurities are removed from the combustion product,
wherein the crude particle is at least one selected from cerium oxides and zirconium oxides, the cerium oxides including at least one selected from the group consisting of gadolinium (Gd), samarium (Sm) and lanthanum (La), and the zirconium oxides including at least one selected from the group consisting of yttrium (Y), scandium (Sc) and calcium (Ca); and
the nanoparticles are prepared in the form of nanoparticles attached to the surface of the crude particles through a combustion process using at least one selected from cerium nitrate, gadolinium nitrate, samarium nitrate, lanthanum nitrate, zirconium nitrate, yttrium nitrate, scandium nitrate and calcium nitrate as a precursor.

2. The method for manufacturing a sintered body for an electrolyte according to claim 1 , wherein the crude particles have a diameter of 0.1-3 μm, and the nanoparticles have a diameter of 10-100 nm.

3. The method for manufacturing a sintered body for an electrolyte according to claim 1 , wherein the crude particles and nanoparticles are mixed at a molar (M) ratio of 7:3-3:7.

4. The method for manufacturing a sintered body for an electrolyte according to claim 1 , wherein cerium oxide is gadolinia-doped ceria (GDC), samaria-doped ceria (SDC), lanthanum-doped ceria (LDC) or a mixture thereof.

5. The method for manufacturing a sintered body for an electrolyte according to claim 1 , wherein zirconium oxide is yttria-stabilized zirconia (YSZ), scandia-stabilized zirconia (ScSZ), calcium-stabilized zirconia (CSZ) or a mixture thereof.

6. The method for manufacturing a sintered body for an electrolyte according to claim 1 , wherein the nanoparticle precursor solution comprises a nanoparticle precursor, solvent, additive and a sintering aid.

7. The method for manufacturing a sintered body for an electrolyte according to claim 6 , wherein the additive is at least one selected from glycine, citric acid and urea.

8. The method for manufacturing a sintered body for an electrolyte according to claim 6 , wherein the nanoparticle precursor and additive are added at a molar (M) ratio of 0.5-0.8:1.

9. The method for manufacturing a sintered body for an electrolyte according to claim 6 , wherein the sintering aid is at least one selected from the group consisting of cobalt, copper, zinc, nickel, iron, manganese and lithium.

10. The method for manufacturing a sintered body for an electrolyte according to claim 6 , wherein the solvent is distilled water.

11. The method for manufacturing a sintered body for an electrolyte according to claim 1 , wherein step (ii) is carried out at a temperature of 100-500° C.

12. The method for manufacturing a sintered body for an electrolyte according to claim 1 , wherein step (iii) is carried out by performing calcination at a temperature of 400-1000° C., and then performing a ball milling process.

Assignees

• Korea Inst Sci & Tech

Inventors

• Yoon Kyung Joong
• Lee Seung-Hwan
• Park Mansoo
• Hong Jongsup
• Kim Hyoungchul
• Son Ji-Won
• Lee Jong Ho
• Kim Byung Kook
• Lee Hae-Weon

Classifications

• C01F17/32

  oxide or hydroxide being the only anion, e.g. NaCeO2 or MgxCayEuO · CPC title

• C04B2235/3272

  Iron oxides or oxide forming salts thereof, e.g. hematite, magnetite · CPC title

• C04B2235/3208

  Calcium oxide or oxide-forming salts thereof, e.g. lime · CPC title

• H01M8/1253 Primary

  the electrolyte containing zirconium oxide · CPC title

• H01M2008/1293

  Fuel cells with solid oxide electrolytes · CPC title