Process for refining a heavy hydrocarbon feed using a selective deasphalting step

Patent metadata

Field	Value
Publication number	US-9963643-B2
Application number	US-201314652813-A
Country	US
Kind code	B2
Filing date	Dec 3, 2013
Priority date	Dec 18, 2012
Publication date	May 8, 2018
Grant date	May 8, 2018

Abstract

The invention concerns a process for refining a heavy hydrocarbon feed, comprising the following steps:
a) a step for selective deasphalting of the heavy hydrocarbon feed by single-step liquid/liquid extraction in an extraction medium, said extraction being carried out using a mixture of at least one polar solvent and at least one apolar solvent, in order to obtain an asphalt phase and a deasphalted oil phase DAO, the proportions of said polar solvent and said apolar solvent in the solvent mixture being adjusted as a function of the properties of the feed and the desired asphalt yield, said deasphalting step being carried out under subcritical conditions for the solvent mixture;

b) a step for hydrotreatment of at least a portion of the deasphalted oil phase DAO obtained from step a);

c) optionally, a step for catalytic cracking of at least a portion of the effluent obtained from step b).

First claim

The invention claimed is:

1. A process for refining a heavy hydrocarbon feed, comprising:
a) selectively deasphalting the heavy hydrocarbon feed by single-step liquid/liquid extraction in an extraction medium, said extraction being carried out using a solvent mixture of at least one polar solvent and at least one apolar solvent, in order to obtain an asphalt phase and a deasphalted oil phase, the proportions of said polar solvent and said apolar solvent in the solvent mixture being adjusted as a function of the properties of the feed and the desired asphalt yield, and said deasphalting is carried out under subcritical conditions for the solvent mixture;
b) hydrotreating at least a portion of the deasphalted oil phase obtained from a) in the presence of hydrogen in at least one fixed bed reactor containing at least one hydrodemetallization catalyst and under conditions which can be used to obtain an effluent with a reduced metals content and Conradson Carbon Residue; and
c) optionally, catalytic cracking at least a portion of the effluent obtained from b) in at least one fluidized bed reactor under conditions for producing a gaseous fraction, a gasoline fraction, a LCO fraction, a HCO fraction and a slurry,
wherein the extraction in a) is carried out at a temperature in the range of 150° C. to 310° C., and at a pressure in the range of 0.1 to 6 MPa,
wherein the volume ratio of the mixture of polar and apolar solvents to the mass of feed is in the range 2/1 to 8/1, expressed in liters per kilogram,
wherein said polar solvent is selected from monoaromatic hydrocarbons and mixtures thereof and said apolar solvent is selected from saturated hydrocarbons containing 2 to 9 carbon atoms, and the boiling point of said polar solvent is higher than said boiling point of the apolar solvent, and
wherein the proportion of polar solvent in said solvent mixture is in the range of 1% to 80%.

2. A process according to claim 1 , in which the feed is a heavy feed obtained from atmospheric distillation or from vacuum distillation of crude oil, a residual fraction obtained from direct liquefaction of coal, or a residual fraction obtained from the direct liquefaction of lignocellulosic biomass, alone or as a mixture with coal and/or a residual oil fraction.

3. A process according to claim 1 , in which b) is carried out with at least one catalyst carrying out principally hydrodesulphurization under conditions that can produce a liquid effluent with a reduced metals content, reduced Conradson Carbon Residue content, and reduced sulfur content.

4. A process according to claim 1 , in which b) is carried out at a pressure in the range of 2 to 35 MPa, a temperature in the range of 300° C. to 500° C., and an hourly space velocity in the range of 0.1 to 5 h −1 .

5. A process according to claim 1 , in which the effluent obtained from b) undergoes a separation in order to separate at least:
a gaseous cut;
a gasoline cut;
a gas oil cut;
a vacuum distillate cut; or
a vacuum residue cut.

6. A process according to claim 5 , in which said separation is carried out on at least one mixture comprising at least one vacuum distillate cut and/or a vacuum residue cut.

7. A process according to claim 1 , wherein catalytic cracking at least a portion of the effluent obtained from b) is performed in at least one fluidized bed reactor under conditions for producing a gaseous fraction, a gasoline fraction, a LCO fraction, a HCO fraction and a slurry.

8. A process according to claim 2 , wherein the feed is a heavy feed, obtained from atmospheric distillation or from vacuum distillation of crude oil, having a boiling point of at least 300° C. and containing sulfur, nitrogen and metals impurities.

9. A process according to claim 4 , wherein b) is carried out at a pressure in the range of 10 to 20 MPa, a temperature in the range of 340° C. to 420° C., and an hourly space velocity in the range of 0.1 to 2 h −1 .

10. A process according to claim 5 , wherein the following are recovered from said separation:
a gaseous cut;
a gasoline cut with a boiling point in the range 20° C. to 150° C.;
a gas oil cut with a boiling point in the range 150° C. to 375° C.;
a vacuum distillate; and
a vacuum residue.

11. A process according to claim 1 , wherein said polar solvent is selected from benzene, toluene, xylenes, and mixtures thereof.

12. A process according to claim 1 , wherein said solvent mixture is a mixture of heptane and toluene.

Assignees

• Ifp Energies Now

Inventors

• Merdrignac Isabelle
• Majcher Jerome
• Digne Mathieu

Classifications

• C10G67/14

  including at least two different refining steps in the absence of hydrogen · CPC title

• C10G69/04

  including at least one step of catalytic cracking in the absence of hydrogen · CPC title

• C10G21/003

  Solvent de-asphalting · CPC title

• C10G67/0463

  The hydrotreatment being a hydrorefining · CPC title

• C10G21/14 Primary

  Hydrocarbons · CPC title