Ultraviolet curable white ink composition for inkjet printing, method for preparing white bezel pattern using same, and electronic device comprising white bezel pattern prepared by same

Patent metadata

Field	Value
Publication number	US-9963602-B2
Application number	US-201515515847-A
Country	US
Kind code	B2
Filing date	Nov 13, 2015
Priority date	Nov 13, 2014
Publication date	May 8, 2018
Grant date	May 8, 2018

Abstract

The present invention relates to an ultraviolet curable white ink composition for inkjet printing comprising a pigment dispersion, a binder solution, a monofunctional monomer and a photoinitiator and, more particularly, to an ultraviolet curable white ink composition for inkjet printing which, at the time of forming a pattern, has a thickness of 30 μm or less and a contrast ratio of 98% or more, a method for preparing a white bezel pattern using the same, and an electronic device comprising the white bezel pattern prepared by the method.

First claim

The invention claimed is:

1. An ultraviolet curable white ink composition for inkjet printing comprising a pigment dispersion, a binder solution, a monofunctional monomer, and a photoinitiator, wherein the ultraviolet curable white ink composition for inkjet printing has, at the time of forming a pattern, a thickness of 30 μm or less and a contrast ratio of 98% or more,
wherein the ultraviolet curable white ink composition is for forming a bezel.

2. The ultraviolet curable white ink composition of claim 1 , wherein the ultraviolet curable white ink composition further comprises any one or more selected from the group consisting of an oligomer, a polyfunctional monomer, a polymerization inhibitor, and a surfactant.

3. The ultraviolet curable white ink composition of claim 2 , wherein the polyfunctional monomer is dipentaerythritol hexaacrylate (DPHA).

4. The ultraviolet curable white ink composition of claim 2 , wherein the monofunctional monomer is comprised in an amount of 1 to 15 wt % based on the total weight of the ink composition.

5. The ultraviolet curable white ink composition of claim 1 , wherein the monofunctional monomer has a hydroxy functional group.

6. The ultraviolet curable white ink composition of claim 5 , wherein the monofunctional monomer is one or more monomers selected from the group consisting of 2-hydroxyethyl acrylate (2-HEA), hydroxypropyl acrylate (HPMA), 2-hydroxyethyl methacrylate (2-HEMA), and hydroxypropyl methacrylate (HPMA).

7. The ultraviolet curable white ink composition of claim 1 , wherein the monofunctional monomer is comprised in an amount of 5 to 25 wt % based on a total weight of the ink composition.

8. The ultraviolet curable white ink composition of claim 1 , wherein the pigment dispersion comprises a white pigment, a first reactive monomer, and a dispersing agent.

9. The ultraviolet curable white ink composition of claim 8 , wherein the white pigment is titanium dioxide (TiO 2 ).

10. The ultraviolet curable white ink composition of claim 8 , wherein the white pigment is comprised in an amount of 55 to 70 wt % based on a total weight of the pigment dispersion.

11. The ultraviolet curable white ink composition of claim 8 , wherein the first reactive monomer is a bifunctional acrylate-based monomer.

12. The ultraviolet curable white ink composition of claim 1 , wherein the binder solution is composed of an epoxy-based resin and a second reactive monomer.

13. The ultraviolet curable white ink composition of claim 12 , wherein the second reactive monomer is a monofunctional acrylate-based monomer.

14. The ultraviolet curable white ink composition of claim 12 , wherein the second reactive monomer is comprised in an amount of 60 to 80 wt % based on a total weight of the binder solution.

15. The ultraviolet curable white ink composition of claim 1 , wherein the binder solution is comprised in an amount of 1 to 15 wt % based on the total weight of the ink composition.

16. The ultraviolet curable white ink composition of claim 1 , wherein the photoinitiator comprises ethyl-2, 4, 6 trimethylbenzoylphenyl phosphinate.

17. The ultraviolet curable white ink composition of claim 1 , wherein the photoinitiator is comprised in an amount of 1 to 10 wt % based on the total weight of the ink composition.

18. The ultraviolet curable white ink composition of claim 1 , wherein the ultraviolet curable white ink composition has a viscosity of 10 to 50 cP at normal temperature, and has a viscosity of 5 to 20 cP at 60° C.

19. A method for preparing a white bezel pattern using an ultraviolet curable white ink composition for inkjet printing, the method comprising the steps of:
a) preparing a substrate on which a white bezel is formed by inkjet printing the ultraviolet curable white ink composition of claim 1 to have a thickness of 30 μm or less on a substrate;
b) forming a cured white bezel pattern by irradiating an ultraviolet of 1,000 mJ/cm 2 or more on the substrate; and
c) heat-treating the substrate.

20. The method of claim 19 , wherein Step c) is a step of heat-treating the substrate on which the bezel is formed under conditions of 150 to 180° C. and 10 to 30 minutes after the ultraviolet curing.

Assignees

• Lg Chemical Ltd

Inventors

• Yoo Jae-Hyun
• Choi Kook-Hyun
• Kim Joon-Hyung
• Kim Mi-Kyoung

Classifications

• C09D11/322

  Pigment inks · CPC title

• B41J3/407

  for marking on special material · CPC title

• B41J11/002

  Curing or drying the ink on the copy materials, e.g. by heating or irradiating · CPC title

• B41M3/00

  Printing processes to produce particular kinds of printed work, e.g. patterns ({printing apparatus or machines of special type or for particular purposes B41F17/00;} special designs or pictures per se B44F; manufacturing printed circuits using printing techniques H05K3/12 {; manufacturing organic semiconductor devices using printing techniques H10K71/13}) · CPC title

• C09D11/102

  containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds · CPC title