Microemulsions and uses thereof in dispersing catalysts

Patent metadata

Field	Value
Publication number	US-9963368-B2
Application number	US-201113885459-A
Country	US
Kind code	B2
Filing date	Nov 15, 2011
Priority date	Nov 15, 2010
Publication date	May 8, 2018
Grant date	May 8, 2018

Abstract

Compositions for converting contaminants or dispersing compounds are described. Systems and methods of using the compositions are also disclosed.

First claim

What is claimed is:

1. A composition comprising:
a reductant; and
a microemulsion comprising lecithin;
wherein the reductant is incorporated in the microemulsion; and
wherein the reductant is selected from the group consisting of ferrous oxide, hematite, maghemite, ferrous hydroxide, ferric hydroxide, goethite, akaganeite, lepidocrocite, ferroxyhyte, ferrihydrite, schwertmannite, green rust, fougerite, troilite, greigite, pyrrhotite, mackinawite, siderite, vivianite, and combinations of any thereof;
wherein the composition is aqueous.

2. The composition of claim 1 , wherein the microemulsion comprises water, oil, a surfactant, and a co-surfactant.

3. The composition of claim 1 , wherein the reductant is an in-situ chemical reductant.

4. The composition of claim 1 , wherein the microemulsion further comprises a compound selected from the group consisting of triglycerides, diglycerides, monoglycerides, sugar alcohols, fatty acid ethoxylates, sorbitan monoester, polyoxyethylene alkyl ethers, polyoxyethylene alkyl esters, sorbitan alkyl esters, polyoxyethylene sorbitan alkyl esters, glycerol esters, short chain fatty alcohols, acids, esters, glycerols, glycols, and combinations of any thereof.

5. The composition of claim 1 , further comprising a buffer.

6. The composition of claim 1 , wherein the microemulsion further comprises a low molecular weight water soluble polymer or a biopolymer.

7. The composition of claim 1 , wherein the microemulsion further comprises a polyhydric alcohol selected from the group consisting of glycerol, ethylene glycol, propylene glycol, sugar alcohols, and combinations of any thereof.

8. The composition of claim 1 , wherein the reductant is located in a micelle formed by the microemulsion.

9. A composition comprising:
a reductant; and
a microemulsion comprising lecithin;
wherein the reductant is selected from the group consisting of ferrous oxide, hematite, maghemite, ferrous hydroxide, ferric hydroxide, goethite, akaganeite, lepidocrocite, ferroxyhyte, ferrihydrite, schwertmannite, green rust, fougerite, troilite, greigite, pyrrhotite, mackinawite, siderite, vivianite, and any combinations thereof;
wherein the microemulsion comprises a compound selected from the group consisting of triglycerides, diglycerides, monoglycerides, sugar alcohols, fatty acid ethoxylates, sorbitan monoester, polyoxyethylene alkyl esters, sorbitan alkyl esters, polyoxyethylene sorbitan alkyl esters, glycerol esters, short chain fatty alcohols, acids, esters, glycerols, glycols, and combinations of any thereof; and
wherein the reductant is incorporated in the microemulsion.

10. The composition of claim 9 , wherein the microemulsion further comprises a compound selected from the group consisting of soy soapstock, acid oil of soy soapstock, neutralized acid oil, soybean oil, ethyl lactate, ethoxylated monoglyceride, polylactate, crude glycerol, sodium stearoyl lactylate, propylene glycol, and combinations of any thereof.

11. A composition comprising:
a reductant; and
a microemulsion comprising lecithin, water, oil, a surfactant, and a co-surfactant;
wherein the reductant is incorporated in the microemulsion; and
wherein the reductant is selected from the group consisting of ferrous oxide, hematite, maghemite, ferrous hydroxide, ferric hydroxide, goethite, akaganeite, lepidocrocite, ferroxyhyte, ferrihydrite, schwertmannite, green rust, fougerite, troilite, greigite, pyrrhotite, mackinawite, siderite, vivianite, and combinations of any thereof.

12. A composition comprising:
a reductant;
a buffer; and
a microemulsion comprising lecithin;
wherein the reductant is incorporated in the microemulsion; and
wherein the reductant is selected from the group consisting of ferrous oxide, hematite, maghemite, ferrous hydroxide, ferric hydroxide, goethite, akaganeite, lepidocrocite, ferroxyhyte, ferrihydrite, schwertmannite, green rust, fougerite, troilite, greigite, pyrrhotite, mackinawite, siderite, vivianite, and combinations of any thereof.

13. A composition comprising:
a reductant; and
a microemulsion comprising lecithin and a low molecular weight water soluble polymer or a biopolymer;
wherein the reductant is incorporated in the microemulsion; and
wherein the reductant is selected from the group consisting of ferrous oxide, hematite, maghemite, ferrous hydroxide, ferric hydroxide, goethite, akaganeite, lepidocrocite, ferroxyhyte, ferrihydrite, schwertmannite, green rust, fougerite, troilite, greigite, pyrrhotite, mackinawite, siderite, vivianite, and combinations of any thereof.

14. A composition comprising:
a reductant; and
a microemulsion comprising lecithin and a polyhydric alcohol selected from the group consisting of glycerol, ethylene glycol, propylene glycol, sugar alcohols, and combinations of any thereof;
wherein the reductant is incorporated in the microemulsion; and
wherein the reductant is selected from the group consisting of ferrous oxide, hematite, maghemite, ferrous hydroxide, ferric hydroxide, goethite, akaganeite, lepidocrocite, ferroxyhyte, ferrihydrite, schwertmannite, green rust, fougerite, troilite, greigite, pyrrhotite, mackinawite, siderite, vivianite, and combinations of any thereof.

Assignees

• Baseeth Shireen
• Sebree Bruce
• Smith Donovan
• Isenhouer Gwyn
• Archer Daniels Midland Co
• JRW Bioremediation

Inventors

• Baseeth Shireen
• Sebree Bruce
• Smith Donovan
• Isenhouer Gwyn

Classifications

• C02F2305/04

  Surfactants, used as part of a formulation or alone · CPC title

• B09C1/08

  chemically · CPC title

• C02F3/348

  characterised by the way or the form in which the microorganisms are added or dosed · CPC title

• C02F2103/06

  Contaminated groundwater or leachate · CPC title

• C02F3/28

  Anaerobic digestion processes · CPC title