Method for producing organic solvent dispersion of titanium oxide particles

Patent metadata

Field	Value
Publication number	US-9963355-B2
Application number	US-201615552525-A
Country	US
Kind code	B2
Filing date	Feb 23, 2016
Priority date	Feb 27, 2015
Publication date	May 8, 2018
Grant date	May 8, 2018

Abstract

The invention provides a method for producing an organic solvent dispersion of titanium oxide particles in an organic solvent except methanol and ethanol, comprising:
(a) a surface treating process for surface treating an alcohol dispersion of titanium oxide particles in at least one alcohol solvent selected from the group consisting of methanol and ethanol with a surface treating agent comprising a silane coupling agent and 12-hydroxystearic acid thereby surface treating the titanium oxide particles; and (b) a solvent replacing process for replacing the alcohol solvent that is a dispersion medium of the alcohol dispersion of titanium oxide particles by the organic solvent except methanol and ethanol, wherein the silane coupling agent has the general formula (I)

(RO) n —Si—X 4-n   (I)

wherein R is an alkyl group having carbon atoms of 1-4, n is 2 or 3, X is an alkyl, a fluoroalkyl, a vinyl or a (meth)acryloyloxyalkyl group.

First claim

The invention claimed is:

1. A method for producing an organic solvent dispersion of titanium oxide particles in an organic solvent except methanol and ethanol, comprising:
(a) a surface treating process for surface treating an alcohol dispersion of titanium oxide particles in at least one alcohol solvent selected from the group consisting of methanol and ethanol with a surface treating agent comprising a silane coupling agent and 12-hydroxystearic acid thereby surface treating the titanium oxide particles; and
(b) a solvent replacing process for replacing the alcohol solvent that is a dispersion medium of the alcohol dispersion of titanium oxide particles by the organic solvent except methanol and ethanol,
wherein the silane coupling agent has the general formula (I)
(RO) n —Si—X 4-n (I)

wherein R is an alkyl group having carbon atoms of 1-4, n is 2 or 3, X is an alkyl, a fluoroalkyl, a vinyl or a (meth)acryloyloxyalkyl group.

2. The method for producing an organic solvent dispersion of titanium oxide particles according to claim 1 , wherein the titanium oxide particles are surface-treated with 1-40 parts by weight of the silane coupling agent and 1-80 parts by weight of 12-hydroxystearic acid each in relation to 100 parts by weight of the titanium oxide particles.

3. The method for producing an organic solvent dispersion of titanium oxide particles according to claim 1 , wherein the organic solvent is at least one selected from the group consisting of methyl isobutyl ketone, methyl ethyl ketone, butanol, propanol, diacetone alcohol, propylene glycol monomethyl ether, toluene, dimethylsulfoxide, N,N-dimethylacetamide, N,N,2-trimethylpropionamide, γ-butyrolactone, and butyl acetate.

4. The method for producing an organic solvent dispersion of titanium oxide particles according to claim 1 , wherein the alcohol dispersion of titanium oxide particles has a content of 10% by weight or more, a transmittance of 40% or more at a wavelength of 500 nm, and a transmittance of 80% or more at a wavelength of 800 nm, wherein the titanium oxide particles have a D50 in a range of 1 to 20 nm.

5. The method for producing an organic solvent dispersion of titanium oxide particles according to claim 1 , wherein the alcohol dispersion of titanium oxide particles is surface-treated with the surface treating agent in the presence of an organic solvent other than the alcohol solvent.

6. The method for producing an organic solvent dispersion of titanium oxide particles according to claim 1 , wherein the alcohol dispersion of titanium oxide particles used in the surface treating process is such that it is obtained by the following steps (a) to (c):
(a) a step of wet dispersing treatment of an aqueous slurry of titanium oxide particles in the presence of acetic acid and nitric acid with a medium agitating mill or a high pressure dispersing machine to obtain an aqueous dispersion of titanium oxide particles;
(b) a step of washing the aqueous dispersion of titanium oxide particles obtained in the step (a); and
(c) a step of replacing water that is a dispersion medium of the aqueous dispersion of titanium oxide particle obtained in the step (b) by at least one alcohol solvent selected from the group consisting of methanol and ethanol.

Assignees

• Sakai Chemical Industry Co

Inventors

• Morita Takanori
• Miyata Atsushi
• ONISHI Kasumi

Classifications

• C09C3/08

  Treatment with low-molecular-weight {non-polymer} organic compounds {(C09C3/006, C09C3/048 take precedence)} · CPC title

• C09C3/12

  Treatment with organosilicon compounds {(C09C3/006 takes precedence)} · CPC title

• C09D17/008 Primary

  Titanium dioxide · CPC title

• C09D17/00

  Pigment pastes, e.g. for mixing in paints (artists' paints C09D5/06) · CPC title

• C01G23/08

  Drying; Calcining {; After treatment of titanium oxide} · CPC title