Sandwich structure and integrally formed article using the same, and methods for production thereof

Patent metadata

Field	Value
Publication number	US-9962904-B2
Application number	US-201414912510-A
Country	US
Kind code	B2
Filing date	Jul 17, 2014
Priority date	Aug 30, 2013
Publication date	May 8, 2018
Grant date	May 8, 2018

Abstract

Provided are the following: a sandwich structure formed from a core component comprising a discontinuous reinforcing fiber, a thermoplastic resin and voids, and a skin component comprising a continuous reinforcing fiber and a matrix resin, wherein in the core component, 30% or more of the discontinuous reinforcing fiber is covered with the thermoplastic resin and monofilaments of the discontinuous reinforcing fiber intersect one another via the thermoplastic resin; an integrally formed article using the sandwich structure; and methods for the production therefor.

First claim

The invention claimed is:

1. A sandwich structure formed from a core component comprising a discontinuous reinforcing fiber, a thermoplastic resin and voids, and a skin member comprising a continuous reinforcing fiber and a matrix resin,
wherein the core component is obtained by applying the thermoplastic resin in the form of a film or nonwoven fabric to the discontinuous reinforcing fiber by:
heating the thermoplastic resin to melt or soften, and
impregnating the discontinuous reinforcing fiber with the thermoplastic resin by applying pressure; and

wherein in the core component, 30% or more of the discontinuous reinforcing fiber is covered with the thermoplastic resin, and monofilaments of the discontinuous reinforcing fiber intersect one another via the thermoplastic resin;
wherein the discontinuous reinforcing fiber and the thermoplastic resin form clusters in a size defined by an average of maximum length of 100 μm or more in the core component;
wherein a flexural modulus of the core component is 2.5 GPa to 20 GPa.

2. The sandwich structure according to claim 1 , wherein the average of maximum length of the clusters is 200 pm or more.

3. The sandwich structure according to claim 1 , wherein the volumetric specific gravity of the core component is 0.01 to 0.6.

4. The sandwich structure according to claim 1 , wherein the continuous reinforcing fiber in the skin member is a continuous carbon fiber.

5. The sandwich structure according to claim 1 , wherein the tensile modulus of the continuous reinforcing fibers in the skin member is 360 GPa to 1000 GPa.

6. The sandwich structure according to claim 1 , wherein the discontinuous reinforcing fiber in the core component is a discontinuous carbon fiber.

7. The sandwich structure according to claim 1 , wherein part of the discontinuous reinforcing fiber in the core component penetrates the skin component and the maximum penetration distance of the discontinuous reinforcing fiber into the skin component is 5 pm or more.

8. The sandwich structure according to claim 1 , wherein the thermoplastic resin in the core component is at least one selected from the group consisting of polyolefin, polyamide, polyester, polycarbonate, polystyrene, modified polyphenylene ether, polyarylene sulfide, and polyether ether ketone.

9. An integrally formed article obtained by joining a first member made of the sandwich structure according to claim 1 and a second member made of another formed article.

10. A method for producing the sandwich structure according to claim 1 comprising the following steps [1] to [3]:
step [1]: a step of forming a precursor of a core component by impregnating the discontinuous reinforcing fiber with the thermoplastic resin by applying pressure in a state where the thermoplastic resin is heated at a temperature at which the thermoplastic resin melts or softens,
step [2]: a step of forming a skin component from a continuous reinforcing fiber and a matrix resin,
step [3]: a step of forming the core component by expanding the precursor of the core component by adjusting the thickness thereof so that the precursor of the core component has a prescribed expansion ratio in a heated state.

11. The method for producing the sandwich structure according to claim 10 , wherein the expansion ratio is 1.1 to 8.

Assignees

• Toray Industries

Inventors

• Hatanaka Kazuhiro
• Matsuo Satomi
• Tsuchiya Atsuki

Classifications

• B32B5/20

  foamed in situ · CPC title

• B32B2262/106

  Carbon fibres, e.g. graphite fibres · CPC title

• B32B2266/0264

  Polyester · CPC title

• B32B2266/02

  Organic · CPC title

• B32B2260/046

  Synthetic resin · CPC title