Low-gloss, flexible clear coats, articles of manufacture having low-gloss, two coat paint systems, and methods for applying the same

Patent metadata

Field	Value
Publication number	US-9962736-B2
Application number	US-87733110-A
Country	US
Kind code	B2
Filing date	Sep 8, 2010
Priority date	Sep 8, 2010
Publication date	May 8, 2018
Grant date	May 8, 2018

Abstract

Low-gloss flexible clear coast can include a base formula that includes a base resin and a cross-linker, a silica-based flattener, wherein the silica-based flattener comprises from 5 parts by weight per 100 parts by weight of the base formula to 20 parts by weight per 100 parts by weight of the base formula, one or more flattener enhancing agents, wherein the one or more flattener enhancing agents comprise 0.25 parts by weight per 100 parts by weight of the base formula to 5 parts by weight per 100 parts by weight of the base formula, and possess 90° flexibility and a 60° gloss finish from 22 gloss units to 34 gloss units.

First claim

What is claimed is:

1. A low-gloss, flexible clear coat comprising:
a base formula comprising a base resin and a cross-linker, wherein the base resin comprises an acrylic polymer resin in an amount of from 50 weight percent to 90 weight percent of the base formula;
a silica-based flattener, wherein the silica-based flattener comprises from 5 parts by weight per 100 parts by weight of the base formula to 20 parts by weight per 100 parts by weight of the base formula; and
one or more flattener enhancing agents, wherein the one or more flattener enhancing agents comprise 0.25 parts by weight per 100 parts by weight of the base formula to 5 parts by weight per 100 parts by weight of the base formula, wherein the low-gloss, flexible clear coat has a 90° flexibility and a 60° gloss finish from 22 gloss units to 34 gloss units when cured, and wherein the one or more flattener enhancing agents comprises an anti-settling agent.

2. The low-gloss, flexible clear coat of claim 1 , wherein the silica-based flattener is selected from the group consisting of thermally derived silicas, precipitated silicas, surface treated silicas, wax treated amorphous silicas, organically treated amorphous silicas, pyrogenic surface modified silicas, hydrophobic silicas and combinations thereof.

3. The low-gloss, flexible clear coat of claim 2 , wherein the silica-based flattener comprises about 5.5 parts by weight pyrogenic surface modified silica per 100 parts by weight of the base formula.

4. The low-gloss, flexible clear coat of claim 1 , wherein the acrylic polymer resin comprises acrylate and methacrylate monomers.

5. The low-gloss, flexible clear coat of claim 1 , wherein the cross-linker is selected from the group consisting of melamines, isocyanates, carbodiimides, blocked isocyanates, and combinations thereof.

6. The low-gloss, flexible clear coat of claim 1 , wherein the cross-linker is an isocyanurate trimer based on hexamethylene diisocyanate.

7. The low-gloss, flexible clear coat of claim 1 , wherein the anti-settling agent is selected from the group consisting of silicas, silicates, organoclays, bentonites, cellulosics, polycarbonates, polyamides, polyesters, polyacrylates, polyacrylamides, polystyrenes and combinations thereof.

8. The low-gloss, flexible clear coat of claim 1 , wherein the anti-settling agent is styrene.

9. The low-gloss, flexible clear coat of claim 1 , wherein the one or more flattener enhancing agents further comprises a dispersant selected from the group consisting of siloxanes, acrylics, waxes and combinations thereof.

10. An article of manufacture having a low-gloss, two coat paint system, the article of manufacture comprising:
an article of manufacture surface;
a basecoat applied to the article of manufacture surface; and
a low-gloss, flexible clear coat applied to a basecoat surface of the basecoat, wherein the low-gloss, flexible clear coat comprises:
a base formula comprising a base resin and a cross-linker, wherein the base resin comprises an acrylic polymer resin in an amount of from 50 weight percent to 90 weight percent of the base formula;
a silica-based flattener comprising from 5 parts by weight per 100 parts by weight of the base formula to 20 parts by weight per 100 parts by weight of the base formula; and
one or more flattener enhancing agents comprising from 0.25 parts by weight per 100 parts by weight of the base formula to 5 parts by weight per 100 parts by weight of the base formula, wherein the low-gloss, flexible clear coat comprises 90° flexibility and a 60° gloss finish from 22 gloss units to 34 gloss units when cured, and wherein the one or more flattener enhancing agents comprises an anti-settling agent.

11. The article of manufacture of claim 10 , wherein the cross-linker is selected from the group consisting of melamines, isocyanates, carbodiimides, blocked isocyanates, and combinations thereof.

12. A method for applying a low-gloss, two coat paint system, the method comprising:
applying a basecoat to a vehicle part;
curing the basecoat on the vehicle part;
applying a low-gloss, flexible clear coat to a basecoat surface of the basecoat, wherein the low-gloss, flexible clear coat comprises:
a base formula comprising a base resin and a cross-linker, wherein the base resin comprises an acrylic polymer resin in an amount of from 50 weight percent to 90 weight percent of the base formula;
a silica-based flattener comprising from 5 parts by weight per 100 parts by weight of the base formula to 20 parts by weight per 100 parts by weight of the base formula; and
one or more flattener enhancing agents comprising from 0.25 parts by weight per 100 parts by weight of the base formula to 5 parts by weight per 100 parts by weight of the base formula, and wherein the one or more flattener enhancing agents comprises an anti-settling agent; and

curing the low-gloss, flexible clear coat to the basecoat surface of the basecoat, wherein the low-gloss, flexible clear coat comprises 90° flexibility and a 60° gloss finish of 22 units to 34 units after curing.

13. The method of claim 12 , wherein the cross-linker is selected from the group consisting a melamines, isocyanates, carbodiimides, blocked isocyanates and combinations thereof.

14. The low-gloss, flexible clear coat of claim 2 , wherein the silica-based flattener is a pyrogenic surface modified silica.

15. The article of manufacture of claim 10 , wherein the silica-based flattener is selected from the group consisting of thermally derived silicas, precipitated silicas, surface treated silicas, wax treated amorphous silicas, organically treated amorphous silicas, pyrogenic surface modified silicas, hydrophobic silicas and combinations thereof.

16. The method of claim 12 , wherein the silica-based flattener is selected from the group consisting of thermally derived silicas, precipitated silicas, surface treated silicas, wax treated amorphous silicas, organically treated amorphous silicas, pyrogenic surface modified silicas and/or hydrophobic silicas, and combinations thereof.

17. The low-gloss, flexible clear coat of claim 1 , wherein the silica-based flattener is selected from the group consisting of organically treated amorphous silicas, hydrophobic silicas and combinations thereof.

18. The article of manufacture of claim 10 , wherein the silica-based flattener is selected from the group consisting of organically treated amorphous silicas, hydrophobic silicas and combinations thereof.

19. The method of claim 12 , wherein the silica-based flattener is selected from the group consisting of organically treated amorphous silicas, hydrophobic silicas and combinations thereof.

Assignees

• Gidcumb Yuko Nagata
• Kubish Scott Dale
• Mecozzi Joe
• Imai Makoto
• Toyota Eng & Mfg North America
• Nb Coatings Inc

Inventors

• Gidcumb Yuko Nagata
• Kubish Scott Dale
• Mecozzi Joe
• Imai Makoto

Classifications

• C09D7/42

  Gloss-reducing agents · CPC title

• B05D7/536 Primary

  each layer being cured, at least partially, separately · CPC title

• Y10T428/31551

  Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.] · CPC title

• Y10T428/31507

  Of polycarbonate · CPC title