Process for continuously recovering (meth)acrylic acid and apparatus for the process

Patent metadata

Field	Value
Publication number	US-9962625-B2
Application number	US-201414903206-A
Country	US
Kind code	B2
Filing date	Jul 21, 2014
Priority date	Jul 22, 2013
Publication date	May 8, 2018
Grant date	May 8, 2018

Abstract

This disclosure relates to a method for continuous recovery of (meth)acrylic acid and an apparatus used for the recovery method. The method of continuous recovery of (meth)acrylic acid according to the present invention may remarkably reduce the amount of extraction solvent used and energy consumption of the total process, and minimize polymerization of (meth)acrylic acid in the recovery process, thus enabling stable recovery of (meth)acrylic acid and operation of a continuous process.

First claim

The invention claimed is:

1. A method for continuous recovery of (meth)acrylic acid, comprising:
an absorption process wherein a mixed gas including (meth)acrylic acid, organic by-products, and vapor, which is produced by a synthesis reaction of (meth)acrylic acid, is contacted with water to obtain a (meth)acrylic acid aqueous solution;
an extraction process wherein the (meth)acrylic acid aqueous solution obtained through the absorption process is contacted with an extraction solvent in an extraction column to obtain a (meth)acrylic acid extract solution and a raffinate solution; and
a distillation process wherein a feed including the (meth)acrylic acid extract solution obtained through the extraction process is distilled to obtain (meth)acrylic acid,
wherein the absorption process is conducted in a packed column type of (meth)acrylic acid absorption tower,
a weight ratio of the extraction solvent to the (meth)acrylic acid aqueous solution fed to the extraction column is greater than 0.3 and less than 1.0, and
the raffinate solution obtained through the extraction process is fed to at least one point corresponding to 10 to 30% below the uppermost part based on the total height of the column packing within the (meth)acrylic acid absorption tower.

2. A method for continuous recovery of (meth)acrylic acid, comprising:
an absorption process wherein a mixed gas including (meth)acrylic acid, organic by-products, and vapor, which is produced by a synthesis reaction of (meth)acrylic acid, is contacted with water to obtain a (meth)acrylic acid aqueous solution;
an extraction process wherein the (meth)acrylic acid aqueous solution obtained through the absorption process is contacted with an extraction solvent in an extraction column to obtain a (meth)acrylic acid extract solution and a raffinate solution; and
a distillation process wherein a feed including the (meth)acrylic acid extract solution obtained through the extraction process is distilled to obtain (meth)acrylic acid,
wherein the absorption process is conducted in a multistage tray type of (meth)acrylic acid absorption tower,
a weight ratio of the extraction solvent to the (meth)acrylic acid aqueous solution fed to the extraction column is greater than 0.3 and less than 1.0, and
the raffinate solution obtained through the extraction process is fed to at least one point corresponding to 10 to 30% below the uppermost stage of the multistage trays present within the (meth)acrylic acid absorption tower based on the total number of stages within the multistage tray type of (meth)acrylic acid absorption tower.

3. The method for continuous recovery of (meth)acrylic acid according to claim 1 , wherein the extraction solvent is a hydrophobic solvent having a boiling point of 10 to 120° C.

4. The method for continuous recovery of (meth)acrylic acid according to claim 1 , wherein the extraction solvent is at least one selected from the group consisting of benzene, toluene, xylene, n-heptane, cycloheptane, cycloheptene, 1-heptene, ethyl-benzene, methyl-cyclohexane, n-butyl acetate, isobutyl acetate, isobutyl acrylate, n-propyl acetate, isopropyl acetate, methyl isobutyl ketone, 2-methyl-1-heptene, 6-methyl-1-heptene, 4-methyl-1-heptene, 2-ethyl-1-hexene, ethylcyclopentane, 2-methyl-1-hexene, 2,3-dimethylpentane, 5-methyl-1-hexene, and isopropyl-butyl-ether.

5. The method for continuous recovery of (meth)acrylic acid according to claim 1 , wherein the extract solution obtained through the extraction process includes 30 to 60 wt % of (meth)acrylic acid, 30 to 60 wt % of an extraction solvent, 3 to 10 wt % of water, and a remaining amount of organic by-products.

6. The method for continuous recovery of (meth)acrylic acid according to claim 1 , wherein the raffinate solution obtained through the extraction process includes (meth)acrylic acid in a content of 15 wt % or less.

7. The method for continuous recovery of (meth)acrylic acid according to claim 1 , wherein the synthesis reaction of (meth)acrylic acid is an oxidation reaction of at least one compound selected from the group consisting of propane, propylene, butane, isobutylene, and (meth)acrolein in the presence of a gas phase catalyst.

Assignees

• Lg Chemical Ltd

Inventors

• Baek Se Won
• Song Jong Hun
• Yoo Sul Hee

Classifications

• B01D3/143 Primary

  by two or more of a fractionation, separation or rectification step · CPC title

• C07C57/04

  Acrylic acid; Methacrylic acid · CPC title

• C07C51/48

  by liquid-liquid treatment · CPC title

• C07C51/43

  by change of the physical state, e.g. crystallisation · CPC title

• C07C51/44 Primary

  by distillation · CPC title