Ladder compound, and organic electroluminescent element using same

Patent metadata

Field	Value
Publication number	US-9960364-B2
Application number	US-201314435126-A
Country	US
Kind code	B2
Filing date	Oct 10, 2013
Priority date	Oct 11, 2012
Publication date	May 1, 2018
Grant date	May 1, 2018

Abstract

A compound represented by the following formula (1). In the formula (1), when Ar 1 and Ar 2 are the same substituents, as for all of the following pairs: Y 1 and Y 12 , Y 2 and Y 11 , Y 3 and Y 10 , Y 4 and Y 9 , Y 5 and Y 8 , and Y 6 and Y 7 , Y 1 to Y 12 of each pair are not the same as each other.

First claim

The invention claimed is:

1. A compound represented by the following formula (1):

wherein in the formula (1),
X is O, S or a group represented by N—Ra;
Y 1 to Y 12 are independently N or a group represented by C—Ra;
Ar 1 and Ar 2 are independently a substituted or unsubstituted aryl group including 6 to 30 ring carbon atoms or a substituted or unsubstituted heteroaryl group including 5 to 30 ring atoms;
Ra is a hydrogen atom, a deuterium atom, a substituted or unsubstituted aryl group including 6 to 30 ring carbon atoms, a substituted or unsubstituted heteroaryl group including 5 to 30 ring atoms, a substituted or unsubstituted alkyl group including 1 to 30 carbon atoms, a substituted or unsubstituted fluoroalkyl group including 1 to 30 carbon atoms, a substituted or unsubstituted cycloalkyl group including 3 to 30 ring carbon atoms, a substituted or unsubstituted aralkyl group including 7 to 30 carbon atoms, a substituted phosphoryl group, a substituted silyl group, a substituted germanium group, a cyano group, a nitro group or a carboxy group;
if two or more Ras are present in the formula (1), the plural Ras may be the same or different; and
provided that, when Ar 1 and Ar 2 are the same substituents, then Y 1 and Y 12 are not the same as each other, Y 2 and Y 11 are not the same as each other, Y 3 and Y 10 are not the same as each other, Y 4 and Y 9 are not the same as each other, Y 5 and Y 8 are not the same as each other, and Y 6 and Y 7 are not the same as each other.

2. The compound according to claim 1 , wherein Ar 1 and Ar 2 in the formula (1) are independently a substituted or unsubstituted aryl group including 6 to 30 ring carbon atoms.

3. The compound according to claim 1 , wherein Ar 1 and Ar 2 in the formula (1) are independently a substituted or unsubstituted heteroaryl group including 5 to 30 ring atoms.

4. The compound according to claim 1 , wherein X in the formula (1) is a group represented by N—Ra.

5. The compound according to claim 1 , wherein X in the formula (1) is O or S.

6. The compound according to claim 1 , wherein Y 1 to Y 12 in the formula (1) are independently a group represented by C—Ra.

7. The compound according to claim 1 , wherein Ar 1 is not the same as Ar 2 in the formula (1).

8. The compound according to claim 1 , wherein Ar 1 in the formula (1) is represented by
wherein L 1 is a substituted or unsubstituted arylene group including 6 to 30 ring carbon atoms or a substituted or unsubstituted heteroarylene group including 5 to 30 ring atoms; and R 1 is a substituted or unsubstituted aryl group including 6 to 30 ring carbon atoms or a substituted or unsubstituted heteroaryl group including 5 to 30 ring atoms.

9. The compound according to claim 8 , wherein L 1 is a substituted or unsubstituted arylene group including 6 to 30 ring carbon atoms.

10. The compound according to claim 8 , wherein L 1 is a substituted or unsubstituted heteroarylene group including 5 to 30 ring atoms.

11. A material for an organic electroluminescence device that comprises the compound according to claim 1 .

12. An organic electroluminescence device comprising:
an anode and a cathode; and
one or more organic thin film layers including an emitting layer between the anode and the cathode,
wherein at least one layer of the organic thin film layers comprises the material for an organic electroluminescence device according to claim 11 .

13. The organic electroluminescence device according to claim 12 , wherein the emitting layer comprises a phosphorescent emitting material and the phosphorescent emitting material is an ortho-metalated complex of a metal atom selected from iridium (Ir), osmium (Os) and platinum (Pt).

14. The organic electroluminescence device according to claim 12 , wherein the emitting layer comprises the material for an organic electroluminescence device.

15. The organic electroluminescence device according to claim 14 , further comprising an electron-transporting zone between the cathode and the emitting layer, wherein the electron-transporting zone comprises the material for an organic electroluminescence device.

Assignees

• Idemitsu Kosan Co

Inventors

• Nakano Yuki
• Hashimoto Ryohei
• Yoshida Kei

Classifications

• C09K2211/1029

  containing one nitrogen atom as the heteroatom · CPC title

• C09K2211/1092

  containing sulfur as the only heteroatom · CPC title

• H01L51/5221

  Electricity · mapped topic

• H01L51/0085

  Electricity · mapped topic

• H01L51/0071

  Electricity · mapped topic