Solid state electrolyte composites based on complex hydrides and metal doped fullerenes/fulleranes for batteries and electrochemical applications

Patent metadata

Field	Value
Publication number	US-9959949-B2
Application number	US-201414295987-A
Country	US
Kind code	B2
Filing date	Jun 4, 2014
Priority date	Jun 4, 2013
Publication date	May 1, 2018
Grant date	May 1, 2018

Abstract

A LiBH 4 —C 60 nanocomposite that displays fast lithium ionic conduction in the solid state is provided. The material is a homogenous nanocomposite that contains both LiBH 4 and a hydrogenated fullerene species. In the presence of C 60 , the lithium ion mobility of LiBH 4 is significantly enhanced in the as prepared state when compared to pure LiBH 4 . After the material is annealed the lithium ion mobility is further enhanced. Constant current cycling demonstrated that the material is stable in the presence of metallic lithium electrodes. The material can serve as a solid state electrolyte in a solid-state lithium ion battery.

First claim

What is claimed is:

1. A process for manufacturing a complex hydride-C 60 nanocomposite for use as an electrolyte in a battery comprising the steps of:
dissolving a complex metal hydride and a C 60 in the presence of a solvent;
removing the solvent, thereby providing a solid-state complex metal hydride-C 60 material;
annealing the solid-state complex metal hydride C 60 material at about 300° C. and in the presence of an inert gas, thereby providing a solid-state complex metal hydride-metal doped C 60 nanocomposite;
placing the solid-state complex metal hydride-metal doped C 60 nanocomposite in a battery as a solid-state electrolyte to enhance a mobility of metal ions and hydrogen containing ions from the complex metal hydride within the solid-state electrolyte with the metal doped C 60 .

2. The process according to claim 1 , wherein the complex metal hydride is a boron hydride selected from the group consisting of LiBH 4 , NaBH 4 , Mg(BH 4 ) 2 , Al(BH 4 ) 3 and combinations thereof.

3. The process according to claim 1 , wherein the complex metal hydride is an aluminum based complex hydride selected from the group consisting of LiAlH 4 , NaAlH 4 , Mg(AlH 4 ) 2 and combinations thereof.

4. The process according to claim 1 , wherein the complex metal hydride is an amide hydride selected from the group consisting of LiNH 2 , NaNH 2 , Mg(NH 2 ) 2 , Ca(NH 2 ) 2 , CaNH, magnesium amides, and combination thereof.

5. The process according to claim 1 , wherein the metal doped C 60 is hydrogenated.

Assignees

• Savannah River Nuclear Solutions Llc

Inventors

• Zidan Ragaiy
• Teprovich Jr Joseph A
• Colon-Mercado Hector R
• Greenway Scott D

Classifications

• H01M10/0562

  Solid materials · CPC title

• H01M10/054

  Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium · CPC title

• H01B1/06 Primary

  mainly consisting of other non-metallic substances · CPC title

• C01B32/156

  After-treatment · CPC title

• H01M6/188

  Processes of manufacture · CPC title