Hydrogen production system and method for producing hydrogen

Patent metadata

Field	Value
Publication number	US-9957626-B2
Application number	US-201514837411-A
Country	US
Kind code	B2
Filing date	Aug 27, 2015
Priority date	Sep 2, 2014
Publication date	May 1, 2018
Grant date	May 1, 2018

Abstract

A hydrogen production system that achieves highly-efficient hydrogen production even when hydrogen is produced by using the plurality of cell stacks is provided.
A hydrogen production system includes a plurality of cell stacks provided within a reaction containment, the cell stacks generating hydrogen by high temperature steam electrolysis by supplying steam to the plurality of cell stacks, a first flow path guiding the steam to each of the cell stacks, a second flow path causing a carrier gas containing air as a main component to flow into the reaction containment, and a flow regulation device provided at an inlet of the steam in each of the cell stacks, the flow regulation device regulating a flow rate of the steam caused to flow into each of the cell stacks to be uniform.

First claim

What is claimed is:

1. A hydrogen production system comprising:
a plurality of cell stacks provided within a reaction containment, the cell stacks generating hydrogen by high temperature steam electrolysis by supplying steam to the plurality of cell stacks;
a first flow path guiding the steam to each of the cell stacks;
a second flow path causing a carrier gas containing air as a main component to flow into the reaction containment; and
a flow regulation device provided at an inlet of the steam in each of the cell stacks, the flow regulation device regulating a flow rate of the steam caused to flow into each of the cell stacks to be uniform.

2. The hydrogen production system according to claim 1 , further comprising:
a first pressure sensor measuring a pressure inside the first flow path or an outlet path of generated hydrogen;
a second pressure sensor measuring a pressure inside the reaction containment;
a first flow control valve provided in the first flow path to regulate a flow rate of the steam flowing through the first flow path;
a second flow control valve provided in the second flow path to regulate a flow rate of the carrier gas flowing through the second flow path; and
a differential pressure control device calculating a differential pressure between an inside and an outside of the cell stacks based on values of the pressures measured in the first pressure sensor and the second pressure sensor, and regulating the respective flow rates of the steam and the carrier gas by using the first flow control valve and the second flow control valve so as to make the differential pressure equal to or less than a predetermined pressure value.

3. The hydrogen production system according to claim 1 , wherein a pressure drop of the steam caused by the flow regulation device is larger than a pressure drop caused by flow resistance of the cell stacks.

4. The hydrogen production system according to claim 1 , further comprising:
an internal heater provided on an inner peripheral surface of the reaction containment to heat an inside of the reaction containment;
an external heater provided on an outer peripheral surface of the reaction containment to heat the inside of the reaction containment;
a thermometer measuring an internal temperature of the reaction containment; and
a temperature control device adjusting the internal temperature of the reaction containment to be a predetermined temperature by using the internal heater and the external heater.

5. The hydrogen production system according to claim 1 , wherein the cell stacks are connected in parallel with a power supply that applies a voltage to the cell stacks.

6. The hydrogen production system according to claim 1 , further comprising:
an ammeter measuring a value of a current flowing through each of the cell stacks connected in parallel; and
a voltage control device calculating a resistance value of the cell stacks corresponding to a minimum current value out of the measured current values, and adjusting the voltage to be applied to the cell stacks so as to obtain a predetermined current value.

7. The hydrogen production system according to claim 1 , further comprising:
an ammeter measuring a value of a current flowing through each of the cell stacks, wherein voltages from a power supply is respectively applied to each of the cell stacks; and
a voltage control device calculating a resistance value of the cell stacks out of the measured current values, and adjusting the voltages to be applied to each of the cell stacks so as to become same current flowing thorough each of the cell stacks.

8. The hydrogen production system according to claim 1 , further comprising:
a flow rate meter measuring the flow rate of the steam flowing through the first flow path;
an on off control unit selecting the cell stack to be driven according to the measured flow rate of the steam.

9. The hydrogen production system according to claim 8 , wherein a plurality of rows of the cells stacks connected in series are connected in parallel with the power supply, and the on off control unit selects each of the rows of the cell stacks to be driven from the plurality of rows.

10. The hydrogen production system according to claim 1 , wherein the cell stacks are radially arranged within the reaction containment, and the first flow path guides the steam from a center of the radially-arranged cell stacks.

11. A method for producing hydrogen by using a plurality of cell stacks that are provided within a reaction containment, and generate hydrogen by high temperature steam electrolysis by supplying steam to the plurality of cell stacks, comprising the steps of:
guiding the steam to each of the cell stacks;
causing a carrier gas containing air as a main component to flow into the reaction containment; and
regulating a flow rate of the steam caused to flow into each of the cell stacks to be uniform by using a flow regulation device that is provided at an inlet of the steam in each of the cell stacks.

Assignees

• Toshiba Kk

Inventors

• Kawajiri Yuko
• Watanabe Hisao
• Yoshimura Ryoji
• Fujiwara Seiji
• Yamauchi Hiroyuki
• Komai Masafumi
• Yamada Masahiko
• Kameda Tsuneji
• Yoshino Masato
• Asada Takatoshi
• Kasai Shigeo

Classifications

• C25B15/02 Primary

  Process control or regulation · CPC title

• C25B9/00

  Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features · CPC title

• C25B1/04

  by electrolysis of water · CPC title

• C25B15/08

  Supplying or removing reactants or electrolytes; Regeneration of electrolytes · CPC title

• Y02E60/366

  Cross-Sectional Technologies · mapped topic