Electrode unit

Patent metadata

Field	Value
Publication number	US-9957625-B2
Application number	US-201313915097-A
Country	US
Kind code	B2
Filing date	Jun 11, 2013
Priority date	Jun 11, 2012
Publication date	May 1, 2018
Grant date	May 1, 2018

Abstract

The invention relates to an electrode unit for an electrochemical device, comprising a solid electrolyte ( 3 ) and a porous electrode ( 7 ), the solid electrolyte ( 3 ) dividing a compartment for cathode material and a compartment for anode material and the porous electrode ( 7 ) being extensively connected to the solid electrolyte ( 3 ), with a displacer ( 23 ) being accommodated in the anode material compartment, where the displacer ( 23 ) is manufactured from a stainless steel or from graphite foil and bears resiliently against the internal geometry of the solid electrolyte ( 3 ) in such a way that the displacer ( 23 ) does not contact the solid electrolyte over its full area, or with the displacer comprising an outer shell ( 62 ) of stainless steel or graphite, and a core ( 64 ) of a nonferrous metal, the nonferrous metal being thermoplastically deformable at a temperature which is lower than the temperature at which the stainless steel is thermoplastically deformable, and where for production the shell ( 62 ) of stainless steel or graphite is pressed onto the solid electrolyte ( 3 ) by introduction and heating of the nonferrous metal, and on cooling forms a gap between solid electrolyte ( 3 ) and shell ( 62 ) of stainless steel.

First claim

The invention claimed is:

1. An electrode unit for an electrochemical device comprising;
a solid electrolyte dividing a compartment for a cathode material and a compartment for an anode material,
a porous electrode being extensively connected to the solid electrolyte, and
a displacer closed at the bottom, and accommodated in the anode material compartment, wherein the displacer comprises an outer shell of stainless steel or graphite, and a core of a nonferrous metal, the nonferrous metal being thermoplastically deformable at a temperature which is lower than the temperature at which the outer shell is thermoplastically deformable, and where for production the outer shell is pressed onto the solid electrolyte by heating of the nonferrous metal, and on cooling of the nonferrous metal a gap is formed between the solid electrolyte and the outer shell.

2. The electrode unit according to claim 1 , wherein the displacer comprises an outer contour with projections and recesses.

3. The electrode unit according to claim 2 , wherein the projections and recesses are realized by means of a waveform or zig zag form on the displacer.

4. The electrode unit according to claim 1 , wherein the outer shell of stainless steel or graphite is a flexible sheet.

5. The electrode unit according to claim 1 , wherein the outer shell comprises a cylindrically bent metal sheet whose edges overlap in axial direction.

6. The electrode unit according to claim 5 , wherein the outer shell comprises a base which, with an upwardly bent edge, surrounds the cylindrically bent metal sheet or is surrounded by cylindrically bent metal sheet, so that the base is movable relative to the outer shell for the production of the displacer.

7. The electrode unit according to claim 1 , wherein the displacer having the outer shell of stainless steel further comprises an inner shell of stainless steel and the core of the nonferrous metal is disposed between the inner and the outer shells.

8. The electrode unit according to claim 7 , wherein the nonferrous metal is zinc, aluminum or an alloy comprising at least one of these metals.

9. The electrode unit according to claim 1 , wherein the displacer comprises a conductor to conduct current.

10. The electrode unit according to claim 9 , wherein the conductor comprises a special steel tube closed at both ends and with a core of an electrically highly conductive material and are arranged in recesses of the displacer, or wherein the conductor comprises a coating of an electrically highly conductive material on the inside of the displacer.

11. The electrode unit according to claim 9 , wherein the conductor comprises a special steel tube closed at both ends and with a core of an electrically highly conductive material are clamped in the recesses.

12. The electrode unit according to claim 10 , wherein the electrically highly conductive material is selected from the group consisting of copper, aluminum, silver, gold, sodium, and also mixtures and alloys comprising at least one of these metals.

13. The electrode unit according to claim 1 , wherein the solid electrolyte is of cylindrical design and closed at one end, and the porous electrode surrounds the solid electrolyte, the compartment for the anode material being surrounded by the solid electrolyte.

14. The electrode unit according to claim 1 , wherein the displacer allows an anode material to flow through the annular gap.

15. The electrode unit according to claim 1 , wherein the solid electrolyte ( 3 ) is made from β″-alumina.

16. The electrode unit according to claim 1 , wherein the anode material is an alkali metal.

17. The electrode unit according to claim 1 , wherein the cathode material is sulfur or polysulfide.

18. An electrolysis cell comprising an electrode according to claim 1 .

19. The electrolysis cell according to claim 18 further comprising a liquid alkali metal as anode material and sulfur or polysulfide as cathode material.

20. An electrode for an electrochemical cell, the electrode prepared by a process comprising:
providing a cylindrical foil with an inner and outer surface, and which is closed at one end, the foil being a stainless steel or graphite;
providing a solid electrolyte with an inner and outer surface of corresponding cylindrical shape, which is closed at one end;
inserting the foil into the solid electrolyte such that the outer surface of the foil contacts the inner surface of the solid electrolyte;
introducing a nonferrous metal into the cylindrical foil, the nonferrous metal in contact with the inner surface of the foil;
heating the nonferrous metal such that the expansion of the nonferrous metal upon heating presses against the foil into the solid electrolyte;
cooling the nonferrous metal such that the contraction of the nonferrous metal upon cooling forms a gap between the outer surface of the foil and the solid electrolyte;
positioning an alkali metal in molten form within the gap to provide an anode material; and
positioning a cathode material on the outer surface of the solid electrolyte.

21. The electrode according to claim 20 , wherein the cathode material is sulfur or a polysulfide, the solid electrolyte is β-alumina or β″-alumina, and the nonferrous metal is selected from zinc, aluminum, copper, or an alloy comprising zinc or aluminum.

Assignees

• Basf Se

Inventors

• HUBER GüNTHER
• Zerpa Unda Jesus Enrique
• Lutz Michael
• Heidebrecht Peter
• Bayer Domnik
• Jabczynski Wolfgang
• Dürr Anna Katharina
• Freitag Katrin

Classifications

• H01M50/469

  tubular or cylindrical · CPC title

• C25B13/07

  based on ceramics · CPC title

• H01M4/58

  of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates · CPC title

• H01M2004/025

  with shapes other than plane or cylindrical · CPC title

• H01M10/3945

  containing additives or special arrangements in the sodium compartment · CPC title