Ductile metal alloys, method for making ductile metal alloys

Patent metadata

Field	Value
Publication number	US-9957593-B2
Application number	US-201414191691-A
Country	US
Kind code	B2
Filing date	Feb 27, 2014
Priority date	Feb 28, 2013
Publication date	May 1, 2018
Grant date	May 1, 2018

Abstract

A ductile alloy is provided comprising molybdenum, chromium and aluminum, wherein the alloy has a ductile to brittle transition temperature of about 300 C after radiation exposure. The invention also provides a method for producing a ductile alloy, the method comprising purifying a base metal defining a lattice; and combining the base metal with chromium and aluminum, whereas the weight percent of chromium is sufficient to provide solute sites within the lattice for point defect annihilation.

First claim

The embodiment of the invention in which an exclusive property or privilege is claimed is defined as follows:

1. An alloy, consisting of:
purified molybdenum in solid solution with chromium, the purified molybdenum having less than 20 ppm carbon and 10 ppm oxygen, and further consisting of
11 ppm to 500 ppm aluminum,
less than 15 ppm nitrogen, and
0.1 wt. % to 0.9 wt. % chromium, wherein
the purified molybdenum is the solvent,
the chromium is the solute, and
the alloy has a ductile to brittle transition temperature of −194° C. to −150° C.

2. The alloy of claim 1 consisting of 0.4 wt. % to 0.9 wt. % chromium.

3. The alloy of claim 2 wherein at least a portion of the 11 ppm to 500 ppm aluminum and the less than 10 ppm oxygen are present as aluminum oxide.

4. The alloy of claim 3 consisting of less than 10 ppm nitrogen.

5. The alloy of claim 2 wherein:
at least a portion of the less than 10 ppm oxygen is present in the solid solution as a first interstitial element, and
at least a portion of the less than 20 ppm carbon is present in the solid solution as a second interstitial element.

6. The alloy of claim 5 further consisting of:
less than 10 ppm nitrogen, wherein
at least a portion of the less than 10 ppm nitrogen is present in the solid solution as a third interstitial element.

7. The alloy of claim 1 , wherein:
the solid solution has a body-centered cubic (BCC) structure,
the BCC structure comprises lattice points,
a plurality of solvent molybdenum atoms are present at a first group of lattice points, and
a plurality of solute chromium atoms are present at a second group of lattice points.

8. The Mo—Cr alloy of claim 7 , wherein:
at least a portion of the less than about 10 ppm oxygen is present in the solid solution as a first interstitial element,
at least a portion of the less than about 20 ppm carbon is present in the solid solution as a second interstitial element, and
at least a portion of the less than about 10 ppm nitrogen is present in the solid solution as a third interstitial element.

9. A method of forming an alloy, comprising:
purifying molybdenum by heat treating the molybdenum in a reducing atmosphere until the purified molybdenum consists of less than 20 ppm carbon, less than 10 ppm oxygen, and less than 15 ppm nitrogen;
adding between 11 ppm and 500 ppm aluminum to the purified molybdenum; and
forming an alloy of the purified molybdenum, the aluminum, and between 0.1% wt and 0.9% wt chromium, wherein:
the purified molybdenum is in solid solution with the chromium,
the purified molybdenum is the solvent,
the chromium is the solute, and
the alloy has a ductile to brittle transition temperature of −194° C. to −150° C.

10. The method of claim 9 , further comprising heat treating the molybdenum in a hydrogen atmosphere at a temperature of at least 1000° C. for at least 48 hours.

11. The method of claim 10 further comprising exposing the molybdenum to a second reducing atmosphere.

12. The method of claim 11 , further comprising heat treating the molybdenum at a temperature of at least 1000° C. for at least 48 hours.

Assignees

• Us Energy
• Us Dept Energy

Inventors

• Cockeram Brian V

Classifications

• C22F1/18

  High-melting or refractory metals or alloys based thereon · CPC title

• C22C1/03

  using master alloys · CPC title

• C22C27/04 Primary

  Alloys based on tungsten or molybdenum · CPC title

• C22C27/02

  Alloys based on vanadium, niobium, or tantalum · CPC title

• C22C1/02

  by melting {(C22C1/1036 takes precedence)} · CPC title