Process for efficiently enriching and recovering noble metals of platinum and palladium by solvent extraction

Patent metadata

Field	Value
Publication number	US-9957587-B2
Application number	US-201414903513-A
Country	US
Kind code	B2
Filing date	Jun 26, 2014
Priority date	May 31, 2014
Publication date	May 1, 2018
Grant date	May 1, 2018

Abstract

The present invention relates to a process for efficiently enriching and recovering noble metals of platinum and palladium based on solvent extraction, wherein isoamyl alcohol is used as extracting agent and 2-methoxyphenyl thiourea is used as extraction-assisted complexing agent. 2-methoxy-phenyl thiourea is added to aqueous phase to react with platinum and palladium, and isoamyl alcohol is used as extracting agent to extract the organic phase, thus realizing the purpose of separating and extracting noble metals from base metals while enriching noble metals of platinum and palladium. The present invention, which can not only realize the separation of noble metals and base metals, but also enhance the enrichment and recovery ratios of noble metals of platinum and palladium, with low cost reagents, small influence on the environment and simple technical process, thus is a new and efficient extraction and enrichment system for noble metals.

First claim

What is claimed is:

1. A process for efficiently enriching and recovering noble metals of platinum and palladium based on solvent extraction, characterized in that: using isoamyl alcohol as extracting agent and 2-methoxyphenyl thiourea as extraction-assisted complexing agent to perform enrichment and extraction of a feed liquid containing noble metals of platinum and palladium, wherein the process comprises the following operation steps of:
(1) adding 2-methoxyphenyl thiourea-hydrochloric acid solution to the feed liquid containing noble metals of platinum and palladium, adjusting the acidity of the feed liquid, so that H + concentration is in the range of 3-5 mol/L to form an original solution of aqueous phase, shaking the original solution and standing the original solution of aqueous phase; the original solution of aqueous phase containing platinum and palladium with a concentration of 0.01-5 mg/L;
(2) taking isoamyl alcohol as an organic phase;
(3) adding the organic phase and the original solution of aqueous phase in a volume ratio of 1:1 to 1:2.5 to a separatory funnel, shaking for 1-5 minutes, then standing for liquid separation, to obtain raffinate and organic phase after the liquid separation, subjecting the organic phase after the liquid separation to stripping back extraction, and performing liquid separation again to obtain a stripping solution, thereby completing the enrichment and extraction of the noble metals.

2. The process for efficiently enriching and recovering noble metals of platinum and palladium based on solvent extraction according to claim 1 , wherein the extraction-assisted complexing agent of 2-methoxyphenyl thiourea-hydrochloric acid solution has a HCl concentration of 2.5-6 mol/L, wherein 2-methoxyphenyl thiourea has a mass percent of 0.01% to 0.5%.

3. The process for efficiently enriching and recovering noble metals of platinum and palladium based on solvent extraction according to claim 1 , wherein the volume ratio of the added 2-methoxyphenyl thiourea-hydrochloric acid solution and the resulting original solution of aqueous phase is 1:2 to 1:5.

Assignees

• Univ Beijing Technology

Inventors

• Xi Xiaoli
• Nie Zuoren
• Sun Xiaokai
• Ma Liwen

Classifications

• C22B3/0031

  Chemistry & Metallurgy · mapped topic

• C22B3/0012

  Chemistry & Metallurgy · mapped topic

• C22B3/0009

  Chemistry & Metallurgy · mapped topic

• C22B3/22

  by physical processes, e.g. by filtration, by magnetic means {, or by thermal decomposition} (treatment or purification of solutions by liquid-liquid extraction C22B3/26) · CPC title

• C22B3/44

  by chemical processes (treatment or purification of solutions by liquid-liquid extraction C22B3/26, by ion-exchange extraction C22B3/42) · CPC title