Use of a polyalkylene glycol to reduce fuel consumption

Patent metadata

Field	Value
Publication number	US-9957455-B2
Application number	US-201415031474-A
Country	US
Kind code	B2
Filing date	Oct 14, 2014
Priority date	Oct 24, 2013
Publication date	May 1, 2018
Grant date	May 1, 2018

Abstract

The use of a polyalkylene glycol of formula HO-(A-O) p —(CH 2 CH 2 —O) m -(A-O) q —H wherein A is a C 3 - to C 20 -alkylene group or a mixture of such alkylene groups, m is a number of from 2 to 100 and p and q are each numbers of from 1 to 100, as an additive in a fuel.

First claim

The invention claimed is:

1. A process of reducing fuel consumption, the process comprising:
operating an internal combustion engine with fuel, said fuel comprising
a polyalkylene glycol of formula I
HO-(A-O) p —(CH 2 CH 2 —O) m -(A-O) q —H  (I)

wherein
A is a mixture of two different types of alkylene groups A 1 and A 2 with A 1 designating one or more C 3 - to C 4 -alkylene groups and A 2 designating one or more C 8 - to C 12 -alkylene groups, A 1 and A 2 being arranged randomly or blockwise,
m is a number of from 2 to 100 and p and q are each numbers of from 1 to 100.

2. A process for minimization of power loss in an internal combustion engine and for improving acceleration of an internal combustion engine, the process comprising:
operating an internal combustion engine with fuel, said fuel comprising
a polyalkylene glycol of formula I
HO-(A-O) p —(CH 2 CH 2 —O) m -(A-O) q —H  (I)

A is a mixture of two different types of alkylene groups A 1 and A 2 with A 1 designating one or more C 3 - to C 4 -alkylene groups and A 2 designating one or more C 8 - to C 12 -allylene groups, A 1 and A 2 being arranged randomly or blockwise,
m is a number of from 2 to 100 and p and q are each numbers of from 1 to 100.

3. A process for improving the lubricity of a lubricant oil contained in an internal combustion engine for lubricating purposes, the process comprising:
operating an internal combustion engine with fuel, said fuel comprising
a polyalkylene glycol of formula I
HO-(A-O) p —(CH 2 CH 2 —O) m -(A-O) q —H  (I)

A is a mixture of two different types of alkylene groups A 1 and A 2 with A 1 designating one or more C 3 - to C 4 -alkylene groups and A 2 designating one or more C 8 - to C 12 -alkylene groups, A 1 and A 2 being arranged randomly or blockwise,
m is a number of from 2 to 100 and p and q are each numbers of from 1 to 100;
wherein said polyalkylene glycol of general formula I is present in the fuel in an amount effective for improving the lubricity of said lubricant oil.

4. The process of claim 1 , wherein A is arranged randomly.

5. The process of claim 1 , wherein the polyalkylene glycol of formula I is obtained by alkoxylation of a polyethylene glycol of formula II
HO—(CH 2 CH 2 —O) m —H  (II)

wherein m is a number of from 2 to 100,
with 2 to 200 moles of a mixture of two different types of alkylene groups A 1 and A 2 wherein A 1 is one or more C 3 - to C 4 -alkylene groups and A 2 is one or more C 8 - to C 12 -alkylene groups, A 1 and A 2 being arranged randomly or blockwise,
per mole of polyethylene glycol II.

6. A fuel composition, comprising:
in a major amount, a gasoline fuel, and,
in a minor amount, a polyalkylene glycol, and
at least one fuel additive which is different from the said polyalkylene glycol and has detergent action,
wherein the polyalkylene glycol is of formula I
HO-(A-O) p —(CH 2 CH 2 —O) m -(A-O) q —H  (I)

A is a mixture of two different types of alkylene groups A 1 and A 2 with A 1 designating one or more C 3 - to C 4 -alkylene groups and A 2 designating one or more C 8 - to C 12 -alkylene groups, A 1 and A 2 being arranged randomly or blockwise,
m is a number of from 2 to 100 and p and q are each numbers of from 1 to 100.

7. The fuel composition according to claim 6 , wherein the fuel additive which is different from the polyalkylene glycol and has detergent action, is at least one selected from the group consisting of:
(Da) mono- or polyamino groups having up to 6 nitrogen atoms, at least one nitrogen atom having basic properties;
(Db) nitro groups, optionally in combination with hydroxyl groups;
(Dc) hydroxyl groups in combination with mono- or polyamino groups, at least one nitrogen atom having basic properties;
(Dd) carboxyl groups or their alkali metal or alkaline earth metal salts;
(De) sulfonic acid groups or their alkali metal or alkaline earth metal salts;
(Df) polyoxy-C 2 -C 4 -alkylene moieties terminated by hydroxyl groups, mono- or polyamino groups, at least one nitrogen atom having basic properties, or by carbamate groups;
(Dg) carboxylic ester groups;
(Dh) moieties derived from succinic anhydride and having hydroxyl and/or amino and/or amido and/or imido groups; and
(Di) moieties obtained by Mannich reaction of substituted phenols with aldehydes and mono- or polyamines.

8. The fuel composition according to claim 6 , further comprising at least one carrier oil.

9. The fuel composition according to claim 8 , further comprising at least one tertiary hydrocarbyl amine of formula NR 1 R 2 R 3 wherein R 1 , R 2 and R 3 are the same or different C 1 - to C 20 -hydro-carbyl residues with the proviso that the overall number of carbon atoms in formula NR 1 R 2 R 3 does not exceed 30.

10. The fuel composition according to claim 6 , which comprises (Da) a polyisobutene a monoamine or a polyisobutene polyamine having M n =300 to 5000, having at least 50 mol-% of vinylidene double bonds and having been prepared by hydroformylation of the respective polyisobutene and subsequent reductive amination with ammonia, a monoamine or a polyamine, in combination with at least one mineral or synthetic carrier oil.

11. An additive concentrate, comprising:
at least one polyalkylene glycol, and
at least one fuel additive which is different from the polyalkylene glycol and has detergent action,
wherein each of the at least one polyalkylene glycol is a polyalkylene glycol of formula I
HO-(A-O) p —(CH 2 CH 2 —O) m -(A-O) q —H  (I)

A is a mixture of two different types of alkylene groups A 1 and A 2 with A 1 designating one or more C 3 - to C 4 -alkylene groups and A 2 designating one or more C 8 - to C 12 -alkylene groups, A 1 and A 2 being arranged randomly or blockwise,
m is a number of from 2 to 100 and p and q are each numbers of from 1 to 100.

12. An additive concentrate according to claim 11 , wherein the at least one fuel additive comprises (Da) a polyisobutene monoamine or a polyisobutene polyamine having M n =300 to 5000, having at least 50 mol-% of vinylidene double bonds and having been prepared by hydroformylation of the respective polyisobutene and subsequent reductive amination with ammonia, a monoamine or a polyamine, and further comprising at least one mineral or synthetic carrier oil.

Assignees

• Basf Se

Inventors

• Voelkel Ludwig
• Hansch Markus
• Hayden Thomas
• Walter Marc
• Kashani-Shirazi Nawid
• Weiss Thomas

Classifications

• C08G65/00

  Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule · CPC title

• C10L1/2383

  Polyamines or polyimines, or derivatives thereof {(poly)amines and imines; derivatives thereof (substituted by a macromolecular group containing 30C) (C10L1/221 takes precedence)} · CPC title

• C10L2270/023

  for gasoline engines · CPC title

• C10L1/18

  containing oxygen · CPC title

• C10L2230/22

  for improving fuel economy or fuel efficiency · CPC title