Expandable particulates and methods of use and preparation

Patent metadata

Field	Value
Publication number	US-9957440-B2
Application number	US-201314915080-A
Country	US
Kind code	B2
Filing date	Sep 27, 2013
Priority date	Sep 27, 2013
Publication date	May 1, 2018
Grant date	May 1, 2018

Abstract

Embodiments relate to preparation of expandable particulates and their use in fracturing operations. An embodiment provides a method for treating a subterranean formation comprising: introducing a treatment fluid comprising expandable particulates into the subterranean formation, wherein the expandable particulates each comprise a particulate substrate, a swellable material coating the particulate substrate, and an exterior coating comprising a resin; and depositing at least a portion of the expandable particulates in the subterranean formation.

First claim

What is claimed is:

1. A method of treating a subterranean formation comprising:
introducing a treatment fluid comprising expandable particulates into a wellbore penetrating a subterranean formation, wherein the expandable particulates each comprise a particulate substrate, a swellable material coating the particulate substrate, and an exterior coating comprising a cured resin, wherein the exterior coating comprises one or more access paths to allow fluid entry to the swellable material beneath the resin;
depositing at least a portion of the expandable particulates in the subterranean formation such that a proppant pack comprising the portion of the expandable particulates is formed in one or more fractures in the subterranean formation, wherein the one or more access paths being formed after the expandable particulates are deposited in the subterranean formation; and
allowing a fluid to enter the one or more access parts and contact the swellable material.

2. The method of claim 1 , wherein the portion of the expandable particulates is deposited in one or more micro-fractures in a complex fracture network formed in the subterranean formation.

3. The method of claim 1 , further comprising contacting the exterior coating of at least one of the expandable particulates with water to form the one or more access paths through the exterior coating.

4. The method of claim 1 , further comprising applying pressure to the exterior coating of at least one of the expandable particulates to form the one or more access paths through the exterior coating.

5. The method of claim 1 , wherein the expandable particulates are present in the treatment fluid in an amount in the range of about 0.1 pounds to about 30 pounds per gallon of the treatment fluid, and wherein the particulate substrate comprises at least one material selected from the group consisting of sand, bauxite, a ceramic material, a glass material, a polymer material, a tetrafluoroethylene material, a nut shell, a ground or crushed nut shell, a seed shell, a ground or crushed seed shell, a fruit pit piece, a ground or crushed fruit pit, processed wood, a composite particulate, and any combination thereof.

6. The method of claim 1 , wherein the particulate substrate has a d50 of less than about 150 microns.

7. The method of claim 1 , wherein the swellable material comprises at least one water swellable material selected from the group consisting of a cross-linked polyacrylamide, a cross-linked polyacrylate, a cross-linked polymer of acrylamide and acrylate monomers, a starch grafted with acrylonitrile and acrylate, a cross-linked polymer of two or more monomers selected from the group consisting of allylsulfonate, 2-acrylamido-2-methyl-1-propanesulfonic acid, 3-allyloxy-2-hydroxy-1-propanesulfonic acid, acrylamide, and acrylic acid monomer, a salt of carboxyl starch, a salt of carboxylmethyl starch, a salt of carboxymethyl cellulose, a salt of cross-linked carboxyalkyl polysaccharide, a starch grafted with acrylonitrile and acrylate monomers, a swellable clay, and any combination thereof.

8. The method of claim 1 , wherein the swellable material comprises at least one oil-swellable material selected from the group consisting of a polyacrylate rubber, an isoprene rubber, a chloroprene rubber, a butyl rubber, a brominated butyl rubber, a chlorinated butyl rubber, a neoprene rubber, a styrene-butadiene copolymer rubber, a sulphonated polyethylene rubber, an ethylene-acrylate rubber, an epichlorohydrin ethylene oxide copolymer rubber, an ethylene-propylene rubber, an ethylene-propylene-diene terpolymer rubber, an ethylene vinyl acetate copolymer rubber, a fluoro rubber, a fluoro silicone rubber, a silicone rubber, a poly 2,2,1-bicyclo heptene rubber, an alkylstyrene rubber, a crosslinked substituted vinyl acrylate copolymer rubber, diatomaceous earth, and any combination thereof.

9. The method of claim 1 , wherein the resin comprises at least one UV-curable resin selected from the group consisting of an epoxy resin, a urethane acrylate resin, an epoxy methacrylate resin, an epoxy-modified novolak resin, a resole resin, a modified resole resin, a terpolymer of phenol furfuryl alcohol and formaldehyde, a furan resin, a urethane resin, a melamine resin, and blends and copolymers thereof.

10. The method of claim 1 , wherein the resin comprises a mixture of a water-soluble material and a water-insoluble material.

11. The method of claim 1 , wherein the resin comprises a water-curable resin.

12. The method of claim 1 , wherein the treatment fluid is introduced through a tubular and into the subterranean formation at a pressure of 1000 psi or greater using at least a high pressure pump.

13. The method of claim 1 , wherein the treatment fluid further comprises a micron-sized, non-swellable proppant having mean particle size of about 0.5 μm to about 150 μm.

Assignees

• Halliburton Energy Services Inc

Inventors

• Nguyen Philip D
• Ogle James William
• Alwattari Ali
• Vo Loan Kim

Classifications

• C09K8/805 Primary

  Coated proppants · CPC title

• C09K2208/04

  Hulls, shells or bark containing well drilling or treatment fluids · CPC title

• C04B26/10

  obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds · CPC title

• C04B20/1051

  Organo-metallic compounds; Organo-silicon compounds, e.g. bentone · CPC title

• C04B20/1037

  obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds · CPC title