Fracturing fluid for prevention of shale fracture hydration during well stimulation by hydraulic fracturing

Patent metadata

Field	Value
Publication number	US-9957439-B2
Application number	US-201514960085-A
Country	US
Kind code	B2
Filing date	Dec 4, 2015
Priority date	Dec 5, 2014
Publication date	May 1, 2018
Grant date	May 1, 2018

Abstract

Friction reducers for hydraulic fracturing fluids, hydraulic fracturing fluids containing the friction reducers, and methods of making and using same are disclosed. The friction reducers comprise ethylene oxide polymers, propylene oxide polymers, ethylene oxide-propylene oxide co-polymers, and combinations thereof, and can further comprise a dispersant, such as polypropylene glycol. The friction reducer formulations can be active across a wide range of brine salinities, and tolerant of high levels of divalent cations in solution. The friction reducers can have a cloud point temperature, above which temperature they can precipitate out of solution and deposit on a surface of a hydrocarbon-bearing formation to inhibit hydration of the shale formations lining the fractures.

First claim

The invention claimed is:

1. A fracturing fluid comprising:
an aqueous base fluid;
a drag friction reducer, wherein the friction reducer is a linear polyalkylene polymer having a molecular weight between 10,000 and 10,000,000; and
a dispersant.

2. The fracturing fluid of claim 1 , wherein the concentration of the friction reducer is about 0.1% or less by weight of the fracturing fluid.

3. The fracturing fluid of claim 1 , wherein the friction reducer is polyethylene oxide.

4. The fracturing fluid of claim 3 , wherein the polyethylene oxide has a molecular weight between 1,000,000 and 7,000,000.

5. The fracturing fluid of claim 1 , wherein the dispersant is provided in a ratio of about 1:1 to about 10:1 by weight relative to the friction reducer.

6. The fracturing fluid of claim 5 , wherein the dispersant is polypropylene glycol.

7. The fracturing fluid of claim 1 , wherein the aqueous base fluid is a brine comprising one or more dissolved inorganic salts in a total concentration between 0.1 and 20 weight percent of the total weight of the aqueous base fluid.

8. The fracturing fluid of claim 7 , wherein inorganic salt is comprises one or more monovalent or divalent cations.

9. The fracturing fluid of claim 1 , wherein at least a portion of the aqueous base fluid is flowback water.

10. The fracturing fluid of claim 1 , wherein the friction reducer has a cloud point temperature between 60° C. and 90° C.

11. The fracturing fluid of claim 1 , wherein the aqueous base fluid comprises fresh fracturing fluid recycled fracturing fluid, flowback fracturing fluid or backproduced fracturing fluid, or combinations thereof.

12. The fracturing fluid of claim 1 , wherein the friction reducer comprises an ethylene oxide polymer.

13. The fracturing fluid of claim 1 , wherein the friction reducer comprises a propylene oxide polymer.

14. The fracturing fluid of claim 1 , wherein the friction reducer comprises an ethylene oxide-propylene oxide copolymer.

15. The fracturing fluid of claim 1 , wherein the friction reducer comprises a combination of ethylene oxide polymers, propylene oxide polymers, or ethylene oxide-propylene oxide co-polymers.

16. The fracturing fluid of claim 5 , wherein the dispersant is a solvent or co-solvent for the friction reducer.

17. The fracturing fluid of claim 5 , wherein the dispersant is a liquid comprising at least one C 1 -C 6 alcohol or diol.

18. The fracturing fluid of claim 5 , wherein the dispersant has a molecular weight of between 20 and 10,000 Daltons.

19. The fracturing fluid of claim 8 , where the divalent cations comprise calcium cations.

20. The fracturing fluid of claim 8 , wherein the divalent cations comprise magnesium cations.

21. The fracturing fluid of claim 8 , wherein the divalent cations comprise both calcium cations and magnesium cations.

22. The fracturing fluid of claim 8 , wherein the monovalent cations comprise sodium cations.

23. The fracturing fluid of claim 8 , wherein the monovalent cations comprise potassium cations.

24. The fracturing fluid of claim 8 , wherein the monovalent cations comprise both sodium cations and potassium cations.

Assignees

• Van Oort Eric
• Downs John David
• Univ Texas

Inventors

• Van Oort Eric
• Downs John David

Classifications

• C09K8/885

  obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds · CPC title

• C09K2208/28

  Friction or drag reducing additives · CPC title

• C09K8/68 Primary

  containing organic compounds · CPC title