Method for smoothing a perfluoro alkoxy alkane film surface

Patent metadata

Field	Value
Publication number	US-9957406-B2
Application number	US-201514638391-A
Country	US
Kind code	B2
Filing date	Mar 4, 2015
Priority date	Jul 21, 2011
Publication date	May 1, 2018
Grant date	May 1, 2018

Abstract

Method for increasing the smoothness of the free surface area of a PFA film, provided on a component by sequentially exposing it to a temperature higher than its melting temperature so as to melt at least the free surface area, lowering the temperature to solidify the melted portion, remelting the free surface area by exposing it to a temperature of at least the PFA melting temperature and again lowering the temperature. The PFA film may be provided on Al 2 O 3 , Ni or NiF 2 film.

First claim

The invention claimed is:

1. A method for smoothing a film surface, comprising the steps of:
(1) preparing a component having a film containing perfluoro alkoxy alkane (PFA) represented by formula 1

in which Rf is a perfluoro alkyl group and m and n are both positive integers, and the PFA has a melting point of 298° to 310° C.;
(2) exposing the component to an atmosphere with a temperature 30° to 70° C. higher than a melting temperature of said PFA so as to melt at least a free surface area of the film;
(3) exposing the component to the atmosphere with a temperature 5° to 60° C. lower than the melting temperature of said PFA so as to solidify at least a portion of said free surface area;
(4) remelting said portion of said free surface area by exposing the component to the atmosphere at a temperature of at least the melting temperature of said PFA to 15° C. above said melting temperature; and
(5) lowering a temperature of the atmosphere to room temperature so as to increase smoothness of the free surface area of the film, wherein
the PFA film is provided on a NiF 2 film.

2. The method according to claim 1 , wherein the component is a screw rotor for a gas exhaust screw pump.

3. The method according to claim 1 , wherein the PFA has a molecular weight of from hundreds of thousands to one million.

4. The method according to claim 1 , wherein the NiF 2 film includes P (phosphorus) or B (boron).

Assignees

• Iwaki Masamichi
• Ohmi Tadahiro
• Ohyama Kenji
• Akutsu Isao
• Univ Tohoku

Inventors

• Iwaki Masamichi
• Ohmi Tadahiro
• Ohyama Kenji
• Akutsu Isao

Classifications

• B05D3/0209

  Multistage baking · CPC title

• F04C2230/91

  Coating · CPC title

• F05C2225/04

  PTFE [PolyTetraFluorEthylene] · CPC title

• F04C18/16 Primary

  with helical teeth, e.g. chevron-shaped, screw type {(for non-parallel axes of movement F04C18/48)} · CPC title

• B05D3/0254

  After-treatment · CPC title