Formaldehyde-free smoke reduction agents for binders

Patent metadata

Field	Value
Publication number	US-9957380-B2
Application number	US-201514689102-A
Country	US
Kind code	B2
Filing date	Apr 17, 2015
Priority date	Apr 17, 2015
Publication date	May 1, 2018
Grant date	May 1, 2018

Abstract

Embodiments of the present technology may include a curable, carbohydrate binder composition. The composition may include a carbohydrate. The composition may also include a urea compound. The composition may further include a nitrogen-containing compound. The nitrogen-containing compound may not be the urea compound.

First claim

What is claimed is:

1. A curable, carbohydrate binder composition comprising:
a carbohydrate;
a first urea compound; and
a nitrogen-containing compound, wherein:
the nitrogen-containing compound is not the first urea compound,
the first urea compound is not the reaction product of a substituted or unsubstituted urea with a glyoxal, and
the nitrogen-containing compound is selected from the group consisting of an amino-amic acid, an inorganic salt of a diamine or a polyamine, an ammonium salt of a carboxylic acid, or a reaction product of a second urea compound with a glyoxal.

2. The curable, carbohydrate binder composition of claim 1 , wherein the composition is substantially free of formaldehyde.

3. The curable, carbohydrate binder composition of claim 1 , wherein the composition when cured at a temperature from 100° C. to 300° C. emits fewer volatile organic compounds than the composition without the first urea compound.

4. The curable, carbohydrate binder composition of claim 1 , wherein the composition when cured emits 50% or less of volatile organic compounds emitted when the composition without the first urea compound is cured.

5. The curable, carbohydrate binder composition of claim 1 , wherein the composition when cured emits 10% or less of volatile organic compounds emitted when the composition without the first urea compound is cured.

6. The curable, carbohydrate binder composition of claim 1 , further comprising a carboxylic acid.

7. The curable, carbohydrate binder composition of claim 1 , further comprising citric acid.

8. The curable, carbohydrate binder composition of claim 7 , wherein the citric acid is present in an amount of 0.5 mole per 1 mole of the first urea compound.

9. The curable, carbohydrate binder composition of claim 1 , wherein the molar ratio of the first urea compound to the nitrogen-containing compound is 0.5 or greater.

10. The curable, carbohydrate binder composition of claim 9 , wherein:
the carbohydrate is dextrose,
the nitrogen-containing compound is amine salt of a phosphoric acid, and
the amine of the amine salt comprises 1,6-hexanediamine or ethylene diamine.

11. The curable, carbohydrate binder composition of claim 1 , wherein the nitrogen-containing compound comprises the reaction product of the second urea compound with an equimolar amount of the glyoxal.

12. The curable, carbohydrate binder composition of claim 1 , wherein the nitrogen-containing compound is an amino-amic acid.

13. The curable, carbohydrate binder composition of claim 1 , wherein the nitrogen-containing compound is an inorganic salt of a diamine or a polyamine.

14. The curable, carbohydrate binder composition of claim 1 , wherein the mechanical strength of the cured binder composition is not less than the mechanical strength of the cured binder composition without the first urea compound.

15. The curable, carbohydrate binder composition of claim 1 , wherein the composition when cured produces smoke with 70% or less opacity when the composition without the first urea compound is cured.

16. The curable, carbohydrate binder composition of claim 1 , wherein the composition when cured produces smoke with 90% or less opacity when the composition without the first urea compound is cured.

17. The curable, carbohydrate binder composition of claim 1 , wherein the first urea compound has a formula

wherein R 1 , R 2 , R 3 , and R 4 are independently chosen from a hydrogen moiety (H), an alkyl group, an aromatic group, an alcohol group, an aldehyde group, a ketone group, a carboxylic acid group, and an alkoxy group.

18. The curable, carbohydrate binder composition of claim 1 , wherein:
the carbohydrate is dextrose,
the nitrogen-containing compound is dihydroxy ethyleneurea, and
the moles of the first urea compound to 1 mole of the nitrogen-containing compound is in a range from 0.1 mole to 1.0 mole.

19. A method of reducing volatile organic compound emission during curing of a binder composition, the method comprising:
forming an aqueous dispersion of fibers;
applying the binder composition to the aqueous dispersion of fibers to form a binder-fiber mixture; and
curing the binder-fiber mixture to form a fiber-containing composite, wherein:
the binder composition comprises a carbohydrate, a nitrogen-containing compound, and a first urea compound,
the nitrogen-containing compound is not the first urea compound,
the first urea compound is not the reaction product of a substituted or unsubstituted urea with a glyoxal, and
the nitrogen-containing compound is selected from the group consisting of an amino-amic acid, an inorganic salt of a diamine or a polyamine, an ammonium salt of a carboxylic acid, or a reaction product of a second urea compound with a glyoxal.

20. A fiber-containing composite comprising:
glass fibers;
a binder, wherein:
the binder comprises cured products from a binder composition comprising a carbohydrate, a first urea compound, and a nitrogen-containing compound that is not the first urea compound;
a reaction product of the first urea compound and an aldehyde or a ketone from a degradation product of the carbohydrate,
the first urea compound is not the reaction product of a substituted or unsubstituted urea with a glyoxal, and
the nitrogen-containing compound is selected from the group consisting of an amino-amic acid, an inorganic salt of a diamine or a polyamine, an ammonium salt of a carboxylic acid, or a reaction product of a second urea compound with a glyoxal.

Assignees

• Johns Manville

Inventors

• Alavi Kiarash

Classifications

• C08L5/00 Primary

  Compositions of polysaccharides or of their derivatives not provided for in groups C08L1/00 or C08L3/00 · CPC title

• C03C25/34 Primary

  Condensation polymers of aldehydes, e.g. with phenols, ureas, melamines, amides or amines · CPC title

• D06M13/322

  with compounds containing nitrogen · CPC title

• D06M13/148

  Polyalcohols, e.g. glycerol {or glucose} · CPC title

• D06M13/432

  Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; {Carbodiimides;} Guanidines, e.g. dicyandiamides · CPC title