Nanoparticle-containing polymer nanowire and method for producing the same

Patent metadata

Field	Value
Publication number	US-9957371-B2
Application number	US-201214364808-A
Country	US
Kind code	B2
Filing date	Dec 13, 2012
Priority date	Dec 14, 2011
Publication date	May 1, 2018
Grant date	May 1, 2018

Abstract

Provided is a polymer nanowire which contains nanoparticles so as to have new functionalities. A thin film is formed on a substrate and includes functional nanoparticles and polymers, and further includes a photosensitive pigment as required. The thin film is irradiated with a pulsed laser. This causes a polymer nanowire containing the functional nanoparticles to grow from a surface of the thin film.

First claim

The invention claimed is:

1. A thin film/polymer nanowire complex comprising:
a thin film that includes at least one polymer layer including a polymer and at least one nanoparticle layer including nanoparticles, wherein at least one of the polymer layer and the nanoparticle layer includes a photosensitive pigment selected from the group consisting of coumarin, pyrene, perylene, anthracene, porphyrin, and phthalocyanine; and
a polymer nanowire of the polymer containing a plurality of nanoparticles in a distributed manner along the length thereof, the nanoparticles contained in the polymer nanowire being the same type of the nanoparticles as in the thin film, and the polymer nanowire extended from the thin film;
wherein the polymer includes at least one type of polymer selected from the group consisting of a methacrylate polymer, a polyvinyl polymer, a polythiophene polymer, a polyacetylene polymer, a polyaniline polymer, and a polypyrrole polymer; and
wherein the nanoparticles are a functional material selected from the group consisting of magnetic material, material with optical properties, material with electrical properties, and radiative material.

2. The thin film/polymer nanowire complex according to claim 1 , wherein the nanowire has a diameter of less than 500 nm.

3. The thin film/polymer nanowire complex according to claim 2 , wherein the nanowire has a diameter of 0.2 nm or more.

4. The thin film/polymer nanowire complex according to claim 1 , wherein the nanowire has a length of 100 nm or more.

5. The thin film/polymer nanowire complex according to claim 4 , wherein the nanoparticle has a diameter of 0.1 nm or more and less than 300 nm.

6. The thin film/polymer nanowire complex according to claim 1 , wherein the nanoparticle is a magnetic body and is driven by applying a magnetic field thereto.

7. The thin film/polymer nanowire complex according to claim 1 , wherein the magnetic material is selected from the group consisting of Fe, Ni, Co, Mn, oxides of Fe, Ni, Co, or Mn, and metallic complex ferromagnetic bodies.

8. The thin film/polymer nanowire complex according to claim 1 , wherein the material with optical properties is selected from the group consisting of quantum dots of CdTe, ZnTe, CdS, ZnS, CdSe, and ZnSe; phthalocyanine (Pc); PcZn; PcNi; PcH 2 ; porphyrin; a compound comprising porphyrin; tetraphenylporphyrin; a compound comprising tetraphenylporphyrin; anthracene; a compound comprising anthracene; pyrene; a compound comprising pyrene; rubrene; coumarin; a compound comprising coumarin; fluorescein; rhodamine; and a compound comprising rhodamine.

9. The thin film/polymer nanowire complex according to claim 1 , wherein the material with electrical properties is a metal.

10. The thin film/polymer nanowire complex according to claim 1 , wherein the radiative material is selected from the group consisting of uranium, potassium, radium, radon, plutonium, cesium, cobalt, iodine, thorium, and carbon.

11. The thin film/polymer nanowire complex according to claim 1 , wherein the nanowire is formed by laser irradiation.

Assignees

• Nat Inst Materials Science

Inventors

• Sasaki Michiko
• Goto Masahiro
• Kasahara Akira
• Chikyo Toyohiro
• Tosa Masahiro

Classifications

• C08K5/0025

  Crosslinking or vulcanising agents; including accelerators · CPC title

• Y10T428/31938

  Polymer of monoethylenically unsaturated hydrocarbon · CPC title

• Y10T428/298

  Physical dimension · CPC title

• C08K2003/2265

  of iron · CPC title

• C08K2201/01

  Magnetic additives · CPC title