Hydrocarbon conversion process

Patent metadata

Field	Value
Publication number	US-9957204-B2
Application number	US-201615333548-A
Country	US
Kind code	B2
Filing date	Oct 25, 2016
Priority date	Jul 7, 2011
Publication date	May 1, 2018
Grant date	May 1, 2018

Abstract

The invention relates to processes for converting a mixture of hydrocarbon and sulfur-containing molecules such as mercaptan into products comprising acetylene, ethylene, and hydrogen sulfide, to processes utilizing the acetylene and ethylene resulting from the conversion, and to equipment useful for such processes.

First claim

The invention claimed is:

1. A hydrocarbon conversion process, comprising:
(a) providing a first mixture comprising ≥90 wt. % of hydrocarbon having a hydrogen content in the range of from 6 wt. % to 25 wt. % and ≥4.0 ppmw mercaptan based on the weight of the first mixture; and
(b) adding carbon monoxide to the first mixture and then pyrolysing the first mixture in a first region under pyrolysis conditions which include exposing the first mixture to a temperature≥1.20×10 3 ° C., to convert at least a portion of the first mixture's hydrocarbon and ≥90.0 wt. % of the first mixture's mercaptan based on the weight of mercaptan in the first mixture to produce a second mixture, the second mixture comprising ≥1.0 wt. % C 2 unsaturates comprising acetylene, ≤20.0 wt. % CO and CO 2 combined, ≤1.0 ppmw mercaptan, ≤1.0 ppmw thiophene based on the weight of the second mixture, wherein a molar ratio of CO to acetylene in the second mixture is in the range of from 0.005 to 0.2, and wherein the carbon monoxide is added in an amount up to and including 20 wt. % based on the weight of the second mixture.

2. The process of claim 1 , wherein the first mixture comprises ≥20.0 wt. % methane and ≥10.0 ppmw methyl mercaptan based on the weight of the first mixture; the first mixture being obtained from a natural gas with no intervening mercaptan-removal steps, and wherein the second mixture comprises ≤0.05 ppmw methyl mercaptan based on the weight of the second mixture.

3. The process of claim 1 , wherein the first mixture further comprises hydrogen sulfide in an amount in the range of 50.0 ppmw to 5 wt. % based on the weight of the first mixture.

4. The process of claim 1 , wherein the first mixture is exposed to a temperature≥1.45×10 3 ° C. during the pyrolysing.

5. The process of claim 3 , further comprising (c) separating hydrogen sulfide from the second mixture to produce a third mixture.

6. The process of claim 5 , further comprising:
(d) combining first and second reactants in a second region to produce a fourth mixture, the first and second regions being at least partially coextensive; and
(e) at least partially oxidizing the fourth mixture in the second region to produce a fifth mixture; wherein
(i) the pyrolysing and the oxidizing occur at substantially different times, and
(ii) at least a portion of the temperature of the first region during the pyrolysing is derived from heat generated during the oxidizing in the second region.

7. The process of claim 6 , wherein
(i) step (e) further comprises oxidizing at least a portion of any combustible non-volatiles located in the first region; and
(ii) the fifth mixture comprises ≤10.0 ppmw SO y , y being in the range of from 2 to 4; the ppmw being based on the weight of the fifth mixture.

8. The process of claim 1 , wherein ≥95.0 wt. % of the first mixture's mercaptan is converted to non-thiophenic, non-mercaptan sulfur compounds during the pyrolysis.

9. The process of claim 1 , further comprising converting at least a portion of the second mixture's acetylene to ethylene.

10. The process of claim 9 , further comprising polymerizing at least a portion of the ethylene.

11. The process of claim 1 , wherein the hydrocarbon has a hydrogen content in the range of from 8 wt. % to 20 wt. %.

12. The process of claim 1 , wherein the hydrocarbon is not natural gas.

Assignees

• Exxonmobil Chemical Patents Inc

Inventors

• Keusenkothen Paul F
• Hershkowitz Frank
• Denton Robert D
• Mohr Gary D

Classifications

• C08F110/02

  Ethene · CPC title

• C10G50/00

  Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation · CPC title

• C07C7/005

  Processes comprising at least two steps in series · CPC title

• C07C2/78 Primary

  Processes with partial combustion · CPC title

• C07C7/148

  by treatment giving rise to a chemical modification of at least one compound · CPC title