Method of manufacturing hexagonal ferrite powder, hexagonal ferrite powder, magnetic recording medium and method of manufacturing magnetic recording medium

Patent metadata

Field	Value
Publication number	US-9957167-B2
Application number	US-201615196859-A
Country	US
Kind code	B2
Filing date	Jun 29, 2016
Priority date	Jun 30, 2015
Publication date	May 1, 2018
Grant date	May 1, 2018

Abstract

The method of manufacturing hexagonal ferrite powder includes preparing a hexagonal ferrite precursor by mixing an iron salt and a divalent metal salt in a water-based solution, and converting the hexagonal ferrite precursor into hexagonal ferrite within a reaction flow passage, within which a fluid flowing therein is subjected to heating and pressurizing, by continuously feeding a water-based solution containing the hexagonal ferrite precursor and gelatin to the reaction flow passage.

First claim

What is claimed is:

1. A method of manufacturing hexagonal ferrite powder,
which comprises:
preparing a hexagonal ferrite precursor by mixing an iron salt and a divalent metal salt in a water-based solution; and
converting the hexagonal ferrite precursor into hexagonal ferrite within a reaction flow passage, within which a fluid flowing therein is subjected to heating and pressurizing, by continuously feeding a water-based solution comprising the hexagonal ferrite precursor and gelatin to the reaction flow passage.

2. The method of manufacturing hexagonal ferrite powder according to claim 1 ,
which comprises preparing the hexagonal ferrite precursor in the presence of gelatin.

3. The method of manufacturing hexagonal ferrite powder according to claim 2 ,
wherein a concentration of gelatin in the water-based solution comprising the iron salt and the divalent metal salt ranges from 0.3 g/L to 35.0 g/L.

4. The method of manufacturing hexagonal ferrite powder according to claim 1 ,
which comprises preparing the water-based solution comprising the hexagonal ferrite precursor and gelatin by sequentially merging a feed passage to which a water-based solution comprising the hexagonal ferrite precursor is being fed and a feed passage to which a water-based solution comprising gelatin is being fed with a feed passage to which heated and pressurized water is being fed.

5. The method of manufacturing hexagonal ferrite powder according to claim 4 ,
wherein a concentration of gelatin in the water-based solution comprising gelatin ranges from 0.3 g/L to 35.0 g/L.

6. The method of manufacturing hexagonal ferrite powder according to claim 1 ,
which comprises converting the hexagonal ferrite precursor to hexagonal ferrite within the reaction flow passage by continuously feeding the water-based solution comprising the hexagonal ferrite precursor and gelatin while heating to greater than or equal to 300° C. and pressurizing to greater than or equal to 20 MPa.

7. The method of manufacturing hexagonal ferrite powder according to claim 2 ,
which comprises converting the hexagonal ferrite precursor to hexagonal ferrite within the reaction flow passage by continuously feeding the water-based solution comprising the hexagonal ferrite precursor and gelatin while heating to greater than or equal to 300° C. and pressurizing to greater than or equal to 20 MPa.

8. The method of manufacturing hexagonal ferrite powder according to claim 3 ,
which comprises converting the hexagonal ferrite precursor to hexagonal ferrite within the reaction flow passage by continuously feeding the water-based solution comprising the hexagonal ferrite precursor and gelatin while heating to greater than or equal to 300° C. and pressurizing to greater than or equal to 20 MPa.

9. The method of manufacturing hexagonal ferrite powder according to claim 4 ,
which comprises converting the hexagonal ferrite precursor to hexagonal ferrite within the reaction flow passage by continuously feeding the water-based solution comprising the hexagonal ferrite precursor and gelatin while heating to greater than or equal to 300° C. and pressurizing to greater than or equal to 20 MPa.

10. The method of manufacturing hexagonal ferrite powder according to claim 5 ,
which comprises converting the hexagonal ferrite precursor to hexagonal ferrite within the reaction flow passage by continuously feeding the water-based solution comprising the hexagonal ferrite precursor and gelatin while heating to greater than or equal to 300° C. and pressurizing to greater than or equal to 20 MPa.

11. The method of manufacturing hexagonal ferrite powder according to claim 1 ,
wherein the hexagonal ferrite that is obtained by the conversion comprises 1.0 weight % to 60.0 weight % gelatin.

12. The method of manufacturing hexagonal ferrite powder according to claim 1 ,
wherein the divalent metal salt is one or more divalent metal salt selected from the group consisting of barium salts and strontium salts.

13. The method of manufacturing hexagonal ferrite powder according to claim 1 ,
wherein an average particle size of the hexagonal ferrite powder that is manufactured ranges from 5 nm to 30 nm.

14. The method of manufacturing hexagonal ferrite powder according to claim 1 ,
wherein a coefficient of variation in particle size of the hexagonal ferrite powder that is manufactured ranges from 5% to 35%.

15. The method of manufacturing hexagonal ferrite powder according to claim 1 ,
which manufactures hexagonal ferrite powder that is employed as magnetic powder for magnetic recording.

16. Hexagonal ferrite powder, which is manufactured by the method of manufacturing according to claim 1 .

17. A magnetic recording medium,
which comprises a magnetic layer comprising ferromagnetic powder and binder,
wherein the ferromagnetic powder is hexagonal ferrite powder according to claim 16 .

18. A method of manufacturing a magnetic recording medium,
which comprises:
manufacturing hexagonal ferrite powder by the method of manufacturing according to claim 1 ;
subjecting a mixture of the hexagonal ferrite powder that has been manufactured, organic solvent, and binder to a dispersion processing to prepare a magnetic layer-forming composition; and
forming a magnetic layer with the magnetic layer-forming composition that has been prepared.

Assignees

• Fujifilm Corp

Inventors

• Shirata Masashi

Classifications

• C01G49/0036 Primary

  containing one alkaline earth metal, magnesium or lead · CPC title

• C04B2235/5454

  nanometer sized, i.e. below 100 nm · CPC title

• C04B2235/3215

  Barium oxides or oxide-forming salts thereof · CPC title

• G11B5/70678

  Ferrites · CPC title

• C04B2235/767

  Hexagonal symmetry, e.g. beta-Si3N4, beta-Sialon, alpha-SiC or hexa-ferrites · CPC title