Ternary inorganic compound crystal and preparation method and application thereof

Patent metadata

Field	Value
Publication number	US-9957162-B2
Application number	US-201615188964-A
Country	US
Kind code	B2
Filing date	Jun 21, 2016
Priority date	Dec 26, 2013
Publication date	May 1, 2018
Grant date	May 1, 2018

Abstract

Provided is a ternary inorganic compound crystal having a molecular formula of Ca 8 Al 12 P 2 O 31 , and a preparation method thereof comprising the following steps: weighing calcium salts, aluminum salts and phosphate respectively according to the molar ratio of calcium, aluminum and phosphorus in the molecular formula Ca 8 Al 12 P 2 O 31 ; calcining at 1550˜1570° C., cooling, and grinding to obtain the ternary inorganic compound crystal. Also provided is an application of the ternary inorganic compound in gelling materials and molecular sieves, nonlinear optical crystals, and photochromic materials.

First claim

What is claimed is:

1. A ternary inorganic compound crystal having a molecular formula of Ca 8 Al 12 P 2 O 31 , wherein oxide of the Ca 8 Al 12 P 2 O 31 has a composition of 8CaO.6Al 2 O 3 P 2 O 5 and the Ca 8 Al 12 P 2 O 31 is characterized by a powder X-ray diffraction pattern with diffraction peaks at 2θ of 9.62, 13.62, 19.31, 23.71, 33.80, 36.59, and 41.71.

2. A method for preparing a ternary inorganic compound crystal, comprising the steps of:
weighing calcium nitrate, aluminium nitrate, and ammonium dihydrogen phosphate respectively according to the molar ratio among calcium, aluminium, and phosphorus in the molecular formula Ca 8 Al 12 P 2 O 31 ; adding the calcium nitrate, aluminium nitrate, and ammonium dihydrogen phosphate to a water to give a mixed solution; and heating the mixed solution to 70° C.-80° C. with continuously stirring, the mixed solution form a sol and further form a gel after distillation of water, and presintering the gel at 600° C.-800° C., to obtain a presintered product; and
pressing the presintered product into blanks, then calcinating the blanks at 1550° C.-1570° C. for 1.5-2.5 hrs, and cooling them to room temperature, to obtain the ternary inorganic compound crystal.

3. The method according to claim 2 , wherein the presintering temperature is 700° C.

4. A method for preparing a ternary inorganic compound crystal, comprising the steps of:
weighing calcium carbonate, aluminium hydroxide, and calcium hydrophosphate respectively according to the molar ratio among calcium, aluminium, and phosphorus in the molecular formula Ca 8 Al 12 P 2 O 31 , mixing the calcium carbonate, aluminium hydroxide, and calcium hydrophosphate and then pressing them into blanks, calcinating the blanks at 1550° C.-1570° C. for at least 7 hrs, and cooling them to room temperature, to obtain the ternary inorganic compound crystal.

5. The method according to claim 4 , wherein the blanks are calcinated for 7 to 9 hrs.

Assignees

• Univ Shenzhen

Inventors

• Xing Feng
• Zhang Ning
• Ding Zhu
• Liu Biao
• Han Ningxu
• Wang Weilun
• Li Dawang
• Long Wujian
• Dong Biqin
• Wang Xiaodong

Classifications

• C04B2235/6567

  Treatment time · CPC title

• C04B2103/445

  Gelling agents · CPC title

• C04B2235/3217

  Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina · CPC title

• C01B37/065

  the other elements being metals only · CPC title

• C04B35/624

  Sol-gel processing · CPC title