5-(5-(2,6-dioxyphenyl)tetrazole containing polymer, membrane containing the same, electrochemical device including the membrane and method for preparing the same

Patent metadata

Field	Value
Publication number	US-9954240-B2
Application number	US-201615132011-A
Country	US
Kind code	B2
Filing date	Apr 18, 2016
Priority date	Apr 20, 2015
Publication date	Apr 24, 2018
Grant date	Apr 24, 2018

Abstract

Disclosed are a 5-(2,6-dioxyphenyl)tetrazole-containing polymer, a method for preparing the same, a membrane containing the same and an electrochemical device, particularly a high temperature polymer electrolyte membrane fuel cell, including the membrane. The membrane containing the 5-(2,6-dioxyphenyl)tetrazole-containing polymer is capable of providing high proton conductivity and exhibiting good mechanical properties, thereby capable of providing superior fuel cell performance. Accordingly, the membrane may be usefully used in an electrochemical device, particularly a fuel cell, more particularly a high temperature polymer electrolyte membrane fuel cell.

First claim

What is claimed is:

1. A 5-(2,6-dioxyphenyl)tetrazole-containing polymer comprising a structural unit represented by [Chemical Formula 1]:

wherein R is H, alkyl (C 1 -C 12 alkyl, linear or branched) or benzyl.

2. The 5-(2,6-dioxyphenyl)tetrazole-containing polymer according to claim 1 , wherein the 5-(2,6-dioxyphenyl)tetrazole-containing polymer is obtained from one or more of the following monomers:

wherein X is Cl, F or OH and Y is H, methyl or SO 3 H.

3. The 5-(2,6-dioxyphenyl)tetrazole-containing polymer according to claim 1 , wherein the 5-(2,6-dioxyphenyl)tetrazole-containing polymer is one or more of the following compounds:

wherein R is H, alkyl (C 1 -C 12 alkyl, linear or branched) or benzyl and R1 is one or more selected from H, methyl or SO 3 H.

4. The 5-(2,6-dioxyphenyl)tetrazole-containing polymer according to claim 3 , wherein unreacted nitrile groups are present in part of the 5-(2,6-dioxyphenyl)tetrazole-containing polymer.

5. The 5-(2,6-dioxyphenyl)tetrazole-containing polymer according to claim 1 , wherein the 5-(2,6-dioxyphenyl)tetrazole-containing polymer is capable of exhibiting resonance stabilization of positive charge as tetrazole groups are protonated to tetrazolium ions.

6. The 5-(2,6-dioxyphenyl)tetrazole-containing polymer according to claim 1 , wherein the 5-(2,6-dioxyphenyl)tetrazole-containing polymer is capable of providing sites for proton hopping in protonated state.

7. A polymer composition comprising the 5-(2,6-dioxyphenyl)tetrazole-containing polymer according to claim 1 .

8. The polymer composition according to claim 7 , wherein the polymer composition is a polymer composition wherein the 5-(2,6-dioxyphenyl)tetrazole-containing polymer is blended with a basic polymer.

9. The polymer composition according to claim 7 , wherein the polymer composition is a polymer composition in which one or more selected from a group consisting of Nafion, a Nafion derivative, sulfonated poly(ether ether ketone) (SPEEK), sulfonated polysulfone, polysulfone, polyether, polyvinyl alcohol (PVA), meta-PBI, para-PBI, ortho-PBI, a PBI derivative, polyvinylphosphonic acid and a polymer containing pyridine or aminopyridine groups in main chain of the polymer or tethered to main chain of the polymer is blended with the 5-(2,6-dioxyphenyl)tetrazole-containing polymer.

10. A membrane formed of: a 5-(2,6-dioxyphenyl)tetrazole-containing polymer comprising a structural unit represented by [Chemical Formula 1]; or a polymer composition comprising the 5-(2,6-dioxyphenyl)tetrazole-containing polymer:

wherein R is H, alkyl (C 1 -C 12 alkyl, linear or branched) or benzyl.

11. The membrane according to claim 10 , wherein the membrane is a phosphoric acid-doped membrane.

12. The membrane according to claim 11 , wherein the membrane has a phosphoric acid (PA) uptake of 20-2000 wt %.

13. An electrochemical device comprising the membrane according to claim 10 .

14. The electrochemical device according to claim 13 , wherein the electrochemical device is a fuel cell.

15. The electrochemical device according to claim 14 , wherein the fuel cell is a high temperature polymer electrolyte membrane fuel cell.

16. The electrochemical device according to claim 15 , wherein the high temperature polymer electrolyte membrane fuel cell is a high temperature polymer electrolyte membrane fuel cell that is capable of operating at 160° C.

Assignees

• Korea Inst Sci & Tech
• Jagiellonian Univ

Inventors

• Henkensmeier Dirk
• Jang Jong Hyun
• Kim Hyoung-Juhn
• Kim Jin Young
• Yoon Sung Pil
• Han Jonghee
• Nam Suk Woo
• Duong Ngoc My Hanh
• Michalak Artur
• Dyduch Karol
• Brela Mateusz

Classifications

• H01M8/1004

  characterised by membrane-electrode assemblies [MEA] (H01M8/12 takes precedence) · CPC title

• H01M8/1027

  having carbon, oxygen and other atoms, e.g. sulfonated polyethersulfones [S-PES] · CPC title

• C08G65/48

  Polymers modified by chemical after-treatment · CPC title

• C08G65/007

  containing fluorine · CPC title

• C08G65/40 Primary

  from phenols (I) and other compounds (II), e.g. OH-Ar-OH + X-Ar-X, where X is halogen atom, i.e. leaving group · CPC title