Solid polymer power generation or electrolysis method and system

Patent metadata

Field	Value
Publication number	US-9954239-B2
Application number	US-201415021486-A
Country	US
Kind code	B2
Filing date	Sep 10, 2014
Priority date	Sep 12, 2013
Publication date	Apr 24, 2018
Grant date	Apr 24, 2018

Abstract

There are provided: a solid polymer power generation or electrolysis method that does not require injection of energy from the outside and maintenance of a high temperature, and is capable of converting carbon dioxide to a useful hydrocarbon while producing energy, controlling the production amounts of the hydrocarbons or the like and a ratio sorted by kind of the hydrocarbons, improving utilization efficiency of a product, and simplifying equipment for separation and recovery; and a system for implementing the solid polymer power generation or electrolysis method. Carbon dioxide is supplied to the side of one electrode 111 of a reactor 110 having a membrane electrode assembly 113 , hydrogen is supplied to the side of the other electrode 112 , and the amounts of the hydrocarbons produced per unit time and the ratio sorted by kind of the hydrocarbons are changed by controlling a power generation voltage of the reactor 110.

First claim

The invention claimed is:

1. A solid polymer power generation or electrolysis system including a reactor having a membrane electrode assembly provided with a catalyst layer, a carbon dioxide supplier to supply carbon dioxide to one of electrodes of the reactor, a supplier of hydrogen, water vapor, or liquid water to the other electrode, and a gas-liquid separator to separate/recover a product,
the solid polymer power generation or electrolysis system comprising a voltage controller to control a voltage between the electrodes of the reactor.

2. The solid polymer power generation or electrolysis system according to claim 1 , further comprising a temperature controller to control a temperature of the reactor.

3. The solid polymer power generation or electrolysis system according to claim 1 , wherein
a humidifier to supply water for humidification is connected to at least one of the carbon dioxide supplier and hydrogen supplier.

4. The solid polymer power generation or electrolysis system according to claim 1 , wherein
the gas-liquid separator has a circulation path through which an unreacted gas is circulated to at least one of the carbon dioxide supplier and hydrogen supplier.

5. The solid polymer power generation or electrolysis system according to claim 1 , wherein
the reactor, the gas-liquid separator, and the humidifier have their respective temperature controller that are independent of each other, and
the humidifier has humidification controller.

6. The solid polymer power generation or electrolysis system according to claim 1 , wherein
the voltage controller is configured to be capable of producing carbon dioxide and hydrogen using a reverse reaction by supplying electric power.

7. The solid polymer power generation or electrolysis system according to claim 1 , further comprising a central controller to collectively control the voltage controller, humidification controller, and a plurality of temperature controller in accordance with a kind and an amount of a product to be recovered.

8. A regenerative fuel cell system configured by combining the solid polymer power generation or electrolysis system according to claim 1 with a direct methanol fuel cell system and a water electrolysis function.

9. A solid polymer power generation or electrolysis method using the solid polymer power generation or electrolysis system according to claim 1 comprising supplying carbon dioxide to one electrode of a reactor having a membrane electrode assembly provided with a catalyst layer and supplying hydrogen, water vapor, or liquid water to the other electrode to produce a hydrocarbon.

10. The solid polymer power generation or electrolysis method according to claim 9 , comprising:
controlling a voltage generated by power generation between electrodes of the reactor or an electrolysis voltage applied from the outside; and
changing amounts of hydrocarbons produced per unit time and a ratio sorted by kind of the hydrocarbons.

11. The solid polymer power generation or electrolysis method according to claim 9 , further comprising:
controlling a temperature of the reactor; and
changing amounts of hydrocarbons produced per unit time and a ratio sorted by kind of the hydrocarbons.

12. The solid polymer power generation or electrolysis method according to claim 9 , further comprising:
humidifying at least one of the supplied carbon dioxide and the supplied hydrogen with water, and
controlling a degree of the humidification to change amounts of hydrocarbons produced per unit time and a ratio sorted by kind of the hydrocarbons.

13. The solid polymer power generation or electrolysis method according to claim 9 , further comprising continuously supplying the carbon dioxide and the hydrogen.

14. The solid polymer power generation or electrolysis method according to claim 9 , further comprising:
setting a temperature of the reactor to 200° C. or less; and
producing at least one component among methane, methanol, ethanol, propanol, formaldehyde, and acetaldehyde.

15. The solid polymer power generation or electrolysis method according to claim 9 , further comprising:
supplying carbon dioxide to one of the electrodes and supplying water or water vapor to the other electrode; and
controlling a voltage applied between the electrodes of the reactor to produce at least one component among methane, methanol, ethanol, propanol, formaldehyde, and acetaldehyde.

Assignees

• Japan Aerospace Exploration

Inventors

• Sone Yoshitsugu
• Sakurai Masato
• Shima Asuka
• Umeda Minoru
• Nakabeppu Tetsuya
• Shinozaki Ryota
• Kinoshita Toru

Classifications

• C25B9/10

  Chemistry & Metallurgy · mapped topic

• H01M8/0656

  by electrochemical means (H01M8/065 takes precedence) · CPC title

• H01M2008/1095

  Fuel cells with polymeric electrolytes · CPC title

• H01M8/1018

  Polymeric electrolyte materials · CPC title

• C25B3/02

  Chemistry & Metallurgy · mapped topic