Organic metal compound and organic light-emitting device employing the same
US-2016164006-A1 · Jun 9, 2016 · US
US9954189B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9954189-B2 |
| Application number | US-201514833976-A |
| Country | US |
| Kind code | B2 |
| Filing date | Aug 24, 2015 |
| Priority date | Dec 3, 2014 |
| Publication date | Apr 24, 2018 |
| Grant date | Apr 24, 2018 |
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Organic metal compounds and organic electroluminescence devices employing the same are provided. The organic metal compound has a chemical structure represented below: wherein R 1 , R 2 , R 3 , R 4 , and R 5 are independent and can be hydrogen, halogen, C 1-8 alkyl or C 1-8 alkoxy; L can be acetylacetone ligand, picolinic acid ligand, N, N′-diisopropylbenzamidinate, or N, N′-diisopropyl-diisopropyl-guanidinate.
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What is claimed is: 1. An organic metal compound, having a structure as defined by Formula (I): wherein, R 1 , R 2 , R 3 , R 4 , and R 5 are independently hydrogen, halogen, C 1-8 alkyl group, or C 1-8 alkoxy group; L is acetylacetone ligand, picolinic acid ligand, N, N′-diisopropylbenzamidinate ligand, or N, N′-diisopropyl-diisopropyl-guanidinate ligand. 2. The organic metal compound as claimed in claim 1 , wherein the halogen is fluorine. 3. The organic metal compound as claimed in claim 1 , wherein the C 1-8 alkyl group is tert-butyl group. 4. The organic metal compound as claimed in claim 1 , wherein the organic metal compound has a structure as defined by Formula (II): wherein, R 1 and R 5 are independently hydrogen, halogen, C 1-8 alkyl group, or C 1-8 alkoxy group, R 3 is halogen, C 1-8 alkyl group, or C 1-8 alkoxy group; L is acetylacetone ligand, picolinic acid ligand, N, N′-diisopropylbenzamidinate ligand, or N, N′-diisopropyl-diisopropyl-guanidinate ligand. 5. The organic metal compound as claimed in claim 4 , wherein the halogen is fluorine. 6. The organic metal compound as claimed in claim 4 , wherein the C 1-8 alkyl group is tert-butyl group. 7. The organic metal compound as claimed in claim 1 , wherein the organic metal compound has a structure as defined by Formula (III): wherein, R 1 is hydrogen, halogen, C 1-8 alkyl group, or C 1-8 alkoxy group, R 3 is halogen, C 1-8 alkyl group, or C 1-8 alkoxy group; L is acetylacetone ligand, picolinic acid ligand, N, N′-diisopropylbenzamidinate ligand, or N, N′-diisopropyl-diisopropyl-guanidinate ligand. 8. The organic metal compound as claimed in claim 7 , wherein the halogen is fluorine. 9. The organic metal compound as claimed in claim 7 , wherein the C 1-8 alkyl group is tert-butyl group. 10. An organic light-emitting device, comprising: a pair of electrodes; and an organic light-emitting element disposed between the electrodes, wherein the organic light-emitting element comprises an organic metal compound having a structure as defined by Formula (I): wherein, R 1 , R 2 , R 3 , R 4 , and R 5 are independently hydrogen, halogen, C 1-8 alkyl group, or C 1-8 alkoxy group; L is acetylacetone ligand, picolinic acid ligand, N, N′-diisopropylbenzamidinate ligand, or N, N′-diisopropyl-diisopropyl-guanidinate ligand. 11. The organic light-emitting device as claimed in claim 10 , wherein the organic metal compound has a structure as defined by Formula (II): wherein, R 1 and R 5 are independently hydrogen, halogen, C 1-8 alkyl group, or C 1-8 alkoxy group, R 3 is halogen, C 1-8 alkyl group, or C 1-8 alkoxy group; L is acetylacetone ligand, picolinic acid ligand, N, N′-diisopropylbenzamidinate ligand, or N, N′-diisopropyl-diisopropyl-guanidinate ligand. 12. The organic light-emitting device as claimed in claim 10 , wherein the organic metal compound has a structure as defined by Formula (III): wherein, R 1 is hydrogen, halogen, C 1-8 alkyl group, or C 1-8 alkoxy group; R 3 is halogen, C 1-8 alkyl group, or C 1-8 alkoxy group; L is acetylacetone ligand, picolinic acid ligand, N, N′-diisopropylbenzamidinate ligand, or N, N′-diisopropyl-diisopropyl-guanidinate ligand. 13. The organic light-emitting device as claimed in claim 10 , wherein the halogen is fluorine. 14. The organic light-emitting device as claimed in claim 10 , wherein the C 1-8 alkyl group is tert-butyl group. 15. An organic light-emitting device, comprising: a pair of electrodes; and an organic light-emitting element disposed between the electrodes, wherein the organic light-emitting element comprises a light-emitting layer, and the light-emitting layer comprises a host material and a dopant material, and wherein the dopant material has a structure as defined by Formula (I): wherein, R 1 , R 2 , R 3 , R 4 , and R 5 are independently hydrogen, halogen, C 1-8 alkyl group, or C 1-8 alkoxy group; L is acetylacetone ligand, picolinic acid ligand, N, N′-diisopropylbenzamidinate ligand, or N, N′-diisopropyl-diisopropyl-guanidinate ligand. 16. The organic light-emitting device as claimed in claim 15 , wherein the dopant material has a structure as defined by Formula (II): wherein, R 1 and R 5 are independently hydrogen, halogen, C 1-8 alkyl group, or C 1-8 alkoxy group, R 3 is halogen, C 1-8 alkyl group, or C 1-8 alkoxy group; L is acetylacetone ligand, picolinic acid ligand, N, N′-diisopropylbenzamidinate ligand, or N, N′-diisopropyl-diisopropyl-guanidinate ligand. 17. The organic light-emitting device as claimed in claim 15 , wherein the dopant material has a structure as defined by Formula wherein, R 1 is hydrogen, halogen, C 1-8 alkyl group, or C 1-8 alkoxy group, R 3 is halogen, C 1-8 alkyl group, or C 1-8 alkoxy group; L is acetylacetone ligand, picolinic acid ligand, N, N′-diisopropylbenzamidinate ligand, or N, N′-diisopropyl-diisopropyl-guanidinate ligand. 18. The organic light-emitting device as claimed in claim 15 , wherein the halogen is fluorine. 19. The organic light-emitting device as claimed in claim 15 , wherein the C 1-8 alkyl group is tort-butyl group. 20. The organic light-emitting device as claimed in claim 15 , wherein the organic light-emitting element emits red light or orange light under a bias voltage.
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