Delayed fluorescence compound, and organic light emitting diode and display device using the same

Patent metadata

Field	Value
Publication number	US-9954186-B2
Application number	US-201514938723-A
Country	US
Kind code	B2
Filing date	Nov 11, 2015
Priority date	Nov 12, 2014
Publication date	Apr 24, 2018
Grant date	Apr 24, 2018

Abstract

Embodiments relate to a delayed fluorescence compound of Formula 1:

or Formula 2:

The excitons in the triplet state are engaged in emission such that the emitting efficiency of the delayed fluorescent compound is increased. Embodiments also relate to a display device with an organic light emitting diode (OLED) that includes the delayed fluorescence compound.

First claim

What is claimed is:

1. An organic light emitting diode, comprising:
a first electrode;
a second electrode facing the first electrode; and
an organic emitting layer between the first electrode and the second electrode, the organic emitting layer including a delayed fluorescence compound of Formula 1:

wherein m is 1, and X 1 is selected from Formula 2, wherein L 1 is of Formula 3:

wherein each of R 5 and R 6 in the Formula 3 is independently selected from hydrogen or C1 alkyl through C10 alkyl.

2. The organic light emitting diode according to claim 1 , wherein a difference between a singlet energy of the delayed fluorescence compound and a triplet energy of the delayed fluorescence compound is less than 0.3 eV.

3. The organic light emitting diode according to claim 1 , wherein the organic emitting layer further includes a host, and the delayed fluorescence compound is used as a dopant.

4. The organic light emitting diode according to claim 3 , wherein a difference between a HOMO of the host and a highest occupied molecular orbital (HOMO) of the dopant or a difference between a lowest unoccupied molecular orbital (LUMO) of the host and a LUMO of the dopant is less than 0.5 eV.

5. The organic light emitting diode according to claim 1 , wherein the organic emitting layer further includes a dopant, and the delayed fluorescence compound is used as a host.

6. The organic light emitting diode according to claim 1 , wherein the organic emitting layer further includes a host and a first dopant, and the delayed fluorescence compound is used as a second dopant, and
wherein a triplet energy of the second dopant is smaller than a triplet energy of the host and larger than a triplet energy of the first dopant.

7. The organic light emitting diode according to claim 1 , wherein the organic emitting layer includes a hole injection layer (HIL), a hole transporting layer (HTL), an emitting material layer (EML), an electron transporting layer (ETL), and an electron injection layer (EIL), and
wherein at least one of the HIL, the JTL, the EML, the ETL, and the EIL includes the delayed fluorescence compound.

Assignees

• Lg Display Co Ltd

Inventors

• Yang Joong-Hwan
• Yoon Kyung-Jin
• Noh Hyo-Jin
• Yoon Dae-Wi
• Shin In-Ae
• Kim Jun-Yun

Classifications

• C09K2211/1092

  containing sulfur as the only heteroatom · CPC title

• C09K11/06

  containing organic luminescent materials · CPC title

• C09K2211/1029

  containing one nitrogen atom as the heteroatom · CPC title

• C09K2211/1044

  containing two nitrogen atoms as heteroatoms · CPC title

• C07D471/04

  Ortho-condensed systems · CPC title