Reactive ionic liquid, and ion-immobilized metal oxide particle, ion-immobilized elastomer, and transducer using same

Patent metadata

Field	Value
Publication number	US-9954162-B2
Application number	US-201414573658-A
Country	US
Kind code	B2
Filing date	Dec 17, 2014
Priority date	Mar 25, 2013
Publication date	Apr 24, 2018
Grant date	Apr 24, 2018

Abstract

A reactive ionic liquid to be used as an ionic component that is contained in an ion-containing layer in a transducer arranged in contact with a high-resistance layer as a dielectric layer of the transducer, and is restrained from migrating from the ion-containing layer to the high-resistance layer on application of a voltage is provided. The reactive ionic liquid comprises an ion pair that consists of an anion and a cation. (a) The cation (a1) is an imidazolium or quaternary ammonium cation, and (a2) comprises a reactive group that consists of an alkoxysilyl or phosphonate group. (b) The anion (b1) is a sulfonate, sulfonylimide, or nitrobenzoate anion.

First claim

The invention claimed is:

1. An ion-immobilized metal oxide particle that is prepared by a process comprising reacting a metal oxide particle with a reactive ionic liquid comprising an ion pair that consists of an anion and a cation,
(a) the cation:
(a1) being an imidazolium or quaternary ammonium cation; and
(a2) comprising a reactive group that consists of an alkoxysilyl or phosphonate group;

(b) the anion:
(b1) being a sulfonate or nitrobenzoate anion;

the ion-immobilized metal oxide particle comprising:
the cation; and
a metal oxide particle comprising a hydroxyl group,

the cation being immobilized to the metal oxide particle via an Si—O or P—O bond between the reactive group of the cation and the hydroxyl group of the metal oxide particle.

2. An ion-immobilized elastomer comprising:
the ion-immobilized metal oxide particle according to claim 1 ; and
an elastomer that comprises a functional group that is reactive with a hydroxyl group,
the ion-immobilized metal oxide particle being immobilized to the elastomer via a bond between a hydroxyl group contained in the ion-immobilized metal oxide particle and the functional group contained in the elastomer.

3. A transducer comprising:
a high-resistance dielectric layer that comprises an elastomer and has a volume resistivity of 10 13 Ω·cm or higher;
a pair of positive and negative electrodes that are arranged on front and back sides of the high-resistance dielectric layer; and
an ion-immobilized layer arranged between the high-resistance dielectric layer and the positive electrode, the ion-immobilized layer comprising the ion-immobilized elastomer according to claim 2 .

4. The ion-immobilized metal oxide particle according to claim 1 ,
wherein the cation having a structure represented by one selected from formulae (1) to (3):

where, in formulae (1) to (3), R 1 to R 11 are straight-chain or branched alkyl groups that either comprise or do not comprise heteroatoms, and at least a part of the plurality of R 4 are either identical to or different from one another.

5. An ion-immobilized elastomer comprising
the ion-immobilized metal oxide particle according to claim 4 , and
an elastomer that comprises a functional group that is reactive with a hydroxyl group,
the ion-immobilized metal oxide particle being immobilized to the elastomer via a bond between a hydroxyl group contained in the ion-immobilized metal oxide particle and the functional group contained in the elastomer.

6. A transducer comprising:
a high-resistance dielectric layer that comprises an elastomer and has a volume resistivity of 10 13 Ω·cm or higher;
a pair of positive and negative electrodes that are arranged on front and back sides of the high-resistance dielectric layer; and
an ion-immobilized layer arranged between the high-resistance dielectric layer and the positive electrode, the ion-immobilized layer comprising the ion-immobilized elastomer according to claim 5 .

7. The ion-immobilized metal oxide particle according to claim 1 ,
wherein the anion is one selected from CH 3 SO 3 − , CH 3 C 6 H 4 SO 3 − , C 6 H 5 SO 3 − , 3-nitrobenzoate anion, and 4-nitrobenzoate anion.

8. The ion-immobilized metal oxide particle according to claim 1 ,
wherein the cation having a structure represented by one selected from formulae (1) to (3):

where, in formulae (1) to (3), R 1 to R 11 are straight-chain or branched alkyl groups that either comprise or do not comprise heteroatoms, and at least a part of the plurality of R 4 are either identical to or different from one another; and
wherein the anion is one selected from CH 3 SO 3 − , CH 3 C 6 H 4 SO 3 − , C 6 H 5 SO 3 − , 3-nitrobenzoate anion, and 4-nitrobenzoate anion.

9. An ion-immobilized elastomer comprising:
the ion-immobilized metal oxide particle according to claim 8 ; and
an elastomer that comprises a functional group that is reactive with a hydroxyl group,
the ion-immobilized metal oxide particle being immobilized to the elastomer via a bond between a hydroxyl group contained in the ion-immobilized metal oxide particle and the functional group contained in the elastomer.

10. A transducer comprising:
a high-resistance dielectric layer that comprises an elastomer and has a volume resistivity of 10 13 Ω·cm or higher;
a pair of positive and negative electrodes that are arranged on front and back sides of the high-resistance dielectric layer; and

an ion-immobilized layer arranged between the high-resistance dielectric layer and the positive electrode, the ion-immobilized layer comprising the ion-immobilized elastomer according to claim 9 .

Assignees

• Sumitomo Riko Co Ltd
• Univ Kyushu

Inventors

• Takamatsu Shigeaki
• Kokubo Yota
• Hashimoto Kazunobu
• Yoshikawa Hitoshi
• Takahara Atsushi
• Matsuno Ryousuke
• Otsuka Hideyuki

Classifications

• C07F7/28

  Titanium compounds · CPC title

• C07C317/04

  of an acyclic saturated carbon skeleton · CPC title

• C07C53/10

  Salts thereof · CPC title

• C08F220/46

  with carboxylic acids, sulfonic acids or salts thereof · CPC title

• C07F9/6506

  having the nitrogen atoms in positions 1 and 3 · CPC title