Methods for co-processing carbon dioxide and hydrogen sulfide

Patent metadata

Field	Value
Publication number	US-9951430-B2
Application number	US-201514688578-A
Country	US
Kind code	B2
Filing date	Apr 16, 2015
Priority date	Apr 16, 2015
Publication date	Apr 24, 2018
Grant date	Apr 24, 2018

Abstract

A method for co-processing H 2 S and CO 2 in an electrolyzer includes feeding a first gas stream having H 2 S to an anode and feeding a second gas stream having CO 2 to a cathode. The H 2 S is split into hydrogen and elemental sulfur. The hydrogen is transferred from the anode to the cathode, and the CO 2 is hydrogenated with the transferred hydrogen. A method for producing electricity in a fuel cell includes feeding a first gas stream having H 2 S and CO to an anode, and feeding a second gas stream having oxygen to a cathode. The H 2 S and CO forms hydrogen and carbonyl sulfide. The hydrogen is transferred from the anode to the cathode. The transferred hydrogen is oxidized with the oxygen of the second gas stream, and electricity formed from the oxidation is collected.

First claim

What is claimed is:

1. A method for co-processing H 2 S and CO 2 in an electrolyzer that comprises an anode, a cathode, and an electrolyte positioned between and in electrochemical contact with the anode and the cathode, the method comprising:
feeding a first gas stream comprising H 2 S to the anode of the electrolyzer;
feeding a second gas stream comprising CO 2 to the cathode of the electrolyzer;
splitting H 2 S of the first gas stream into hydrogen and elemental sulfur at the anode;
transferring the hydrogen split from the H 2 S of the first gas stream from the anode across the electrolyte to the cathode; and
hydrogenating the CO 2 from the second gas stream with the hydrogen that was transferred from the anode, wherein
the electrolyte is a solid electrolyte; and
the elemental sulfur split from the H 2 S does not migrate into the electrolyte and is substantially removed from the anode from the electrolyzer as an anode exhaust stream.

2. The method of claim 1 , wherein the CO 2 from the second gas stream is hydrogenated according to a reaction as follows:

wherein C x H x O z is selected from the group consisting of methane, ethane, propane, methanol, ethanol, and propanol.

3. The method of claim 2 , wherein the CO 2 from the second gas stream is hydrogenated to form water and one of methane and methanol.

4. The method of claim 1 , wherein the anode comprises a metal sulfide.

5. The method of claim 1 , wherein the anode comprises a member selected from the group consisting of NiS, MoS 2 , WS 2 , CoS, Li 2 S/CoS 135 , FeMoS, NiMoS, CoMoS, VO 5 , LiCoO 2 , Pt/TiO 2 , Pd, Au, Ag, Ru, Rd, Ir, Nb 2 O 5 —Ni, BaO—Ni, Ce 0.8 Sm 0.2 O 2 —Ni, CuFe 2 S 4 , CuNi 2 S 4 , CuCoS 4 , NiCo 2 S 4 , NiFe 2 S 4 , and mixed metal oxides of La, Sr, Mn, Ti, Cr, Ga, Y, V, Fe, Co, Mo, Ce, Mg, Gd, and Ba.

6. The method of claim 1 , wherein the electrolyte comprises a member selected from the group consisting of perovskite materials of the general type ABO 3 and ABMO 3 that exhibit proton conductivity at temperatures from 600° C. to 1000° C., zirconia- and ceria-based proton conducting electrolytes, and solid acids of MHXO 4 and M 3 H(XO 4 ) 2 , where M is Cs, NH 4 , Rb, and X is S or Se.

7. The method of claim 1 , wherein CO is added to the first gas stream, and the method further comprises forming carbonyl sulfide.

8. The method of claim 7 , wherein the method further comprises feeding the carbonyl sulfide to a decomposer where the carbonyl sulfide is split into elemental sulfur and CO.

9. The method of claim 8 , wherein the CO produced in the decomposer by splitting the carbonyl sulfide is the CO added to the first gas stream.

10. The method of claim 1 , wherein the second gas stream comprises CO 2 and an additional hydrogen source.

11. The method of claim 10 , wherein the hydrogen split from the H 2 S of the first gas stream is transferred from the anode across the electrolyte and form promoting species on the cathode.

12. The method of claim 1 , wherein the first gas stream comprises H 2 S and CO 2 and the method further comprises forming SO x and CO after the H 2 S in the first gas stream is split into hydrogen and elemental sulfur.

Assignees

• Saudi Arabian Oil Co

Inventors

• Souentie Stamatios
• Ballesteros Alberto Lozano
• Simeon Fritz

Classifications

• C25B1/00

  Electrolytic production of inorganic compounds or non-metals · CPC title

• C25B5/00

  Electrogenerative processes, i.e. processes for producing compounds in which electricity is generated simultaneously · CPC title

• H01M8/22

  Fuel cells in which the fuel is based on materials comprising carbon or oxygen or hydrogen and other elements; Fuel cells in which the fuel is based on materials comprising only elements other than carbon, oxygen or hydrogen · CPC title

• C07C1/12

  from carbon dioxide with hydrogen · CPC title

• C25B1/02 Primary

  Hydrogen or oxygen · CPC title