Rubber composition for tire and studless winter tire

Patent metadata

Field	Value
Publication number	US-9951210-B2
Application number	US-201415024793-A
Country	US
Kind code	B2
Filing date	Sep 22, 2014
Priority date	Sep 26, 2013
Publication date	Apr 24, 2018
Grant date	Apr 24, 2018

Abstract

The present technology provides a rubber composition for a tire with which it is possible to produce a tire having excellent on-ice performance and excellent wear resistance, and a studless winter tire using the rubber composition. The rubber composition for a tire of the present technology is a rubber composition for a tire comprising: 100 parts by mass of a diene rubber (A); from 30 to 100 parts by mass of carbon black and/or a white filler (B); and from 0.3 to 30 parts by mass of a cured product (C) prepared by curing a crosslinkable oligomer or polymer (c1) incompatible with the diene rubber (A); a JIS A hardness of the cured product (C) being from 3 to 45.

First claim

The invention claimed is:

1. A rubber composition for a tire comprising: 100 parts by mass of a diene rubber (A); from 30 to 100 parts by mass of carbon black and/or a white filler (B); and
from 0.3 to 30 parts by mass of a cured product (C) prepared by curing a crosslinkable oligomer or polymer (c1) which is incompatible with the diene rubber (A); a JIS A hardness of the cured product (C) being from 3 to 45;
wherein the cured product (C) is a particulate having an average particle size of from 5 to 250 μm; and the crosslinkable oligomer or polymer (c1) is a polyether-based polymer or copolymer.

2. The rubber composition for a tire according to claim 1 further comprising from 0.1 to 12 parts by mass of three-dimensionally crosslinked microparticles (D) having an average particle size of from 0.5 to 50 μm; wherein the microparticles (D) are present inside the cured product (C).

3. The rubber composition for a tire according to claim 1 , wherein a JIS A hardness of the cured product (C) is from 3 to 30.

4. The rubber composition for a tire according to claim 2 , wherein the microparticles (D) are microparticles prepared by three-dimensionally crosslinking an oligomer or polymer (d1) which is incompatible with the crosslinkable oligomer or polymer (c1).

5. The rubber composition for a tire according to claim 1 , wherein the crosslinkable oligomer or polymer (c1) has a silane functional group.

6. The rubber composition for a tire according to claim 1 , wherein the diene rubber (A) contains at least 30 mass % of at least one type rubber selected from the group consisting of natural rubber (NR), isoprene rubber (IR), butadiene rubber (BR), acrylonitrile-butadiene rubber (NBR), styrene-butadiene rubber (SBR), styrene-isoprene rubber (SIR), styrene-isoprene-butadiene rubber (SIBR), and derivatives of each of these rubbers.

7. The rubber composition for a tire according to claim 4 , wherein the oligomer or polymer (d1) is an aliphatic, polymer or copolymer.

8. The rubber composition for a tire according to claim 4 , wherein the crosslinkable oligomer or polymer (c1) has at least one reactive functional group selected from the group consisting of hydroxyl groups, silane functional groups, isocyanate groups, (meth) acryloyl groups, allyl groups, carboxy groups, acid anhydride groups, and epoxy groups.

9. The rubber composition for a tire according to claim 8 , wherein the oligomer or polymer (d1) has at least one reactive functional group selected from the group consisting of hydroxyl groups, mercapto groups, silane functional groups, isocyanate groups, (meth) acryloyl groups, allyl groups, carboxy groups, acid anhydride groups, and epoxy groups, the reactive functional group differing from the reactive functional group of the crosslinkable oligomer or polymer (c1).

10. The rubber composition for a tire according to claim 9 , wherein the microparticles (D) are prepared by three-dimensional crosslinking using the reactive functional group of the oligomer or polymer (d1) in the crosslinkable oligomer or polymer (c1); and the cured product (C) is prepared by curing the crosslinkable oligomer or polymer (c1) using at least one type of catalyst selected from the group consisting of acid catalysts, alkali catalysts, metal catalysts, and amine catalysts after three-dimensionally crosslinking the oligomer or polymer (d1) in the crosslinkable oligomer or polymer (c1).

11. A studless winter tire using the rubber composition for a tire described in claim 1 for a tire tread.

12. A studless winter tire using the rubber composition for a tire described in claim 2 for a tire tread.

Assignees

• Yokohama Rubber Co Ltd

Inventors

• Kakubo Takashi
• Kimura Kazushi
• Maejima Keisuke

Classifications

• C08L101/02

  characterised by the presence of specified groups {, e.g. terminal or pendant functional groups} · CPC title

• B60C11/14

  Anti-skid inserts, e.g. vulcanised into the tread band · CPC title

• C08K3/00

  Use of inorganic substances as compounding ingredients · CPC title

• B60C1/00

  Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition · CPC title

• B60C1/0016

  Compositions of the tread · CPC title