Water treatment process and water treatment system

Patent metadata

Field	Value
Publication number	US-9950936-B2
Application number	US-201514672807-A
Country	US
Kind code	B2
Filing date	Mar 30, 2015
Priority date	Jul 5, 2013
Publication date	Apr 24, 2018
Grant date	Apr 24, 2018

Abstract

In a water treatment system ( 1 ) and a water treatment process, a scale inhibitor is supplied to water to be treated containing Ca ions, SO 4 ions, carbonate ions, and silica, and the water to be treated is adjusted to a pH at which silica is soluble. The pH-adjusted water to be treated containing the calcium scale inhibitor is separated in a demineralizing section ( 10 ) into concentrated water and treated water. In a crystallizing section ( 20 ), seed crystals of gypsum are supplied to the concentrated water, whereby gypsum is crystallized and removed. Silica in the water to be treated is removed from the concentrated water on the downstream side of the crystallizing section ( 20 ). Calcium carbonate in the water to be treated is removed from the concentrated water on the upstream side of the demineralizing section ( 10 ) or the downstream side of the crystallizing section ( 20 ).

First claim

The invention claimed is:

1. A water treatment process comprising:
a scale inhibitor supplying step of supplying a calcium scale inhibitor which is a scale inhibitor for inhibiting the deposition of a scale containing calcium to water containing Ca 2+ ions, SO 4 2− ions, carbonate ions and silica;
a pH adjusting step of adjusting the water to a pH of 10 or more at which the silica is soluble in the water;
a demineralizing step of separating the water into concentrated water in which the Ca 2+ ions, the SO 4 2− ions, the carbonate ions and the silica are concentrated and treated water after the scale inhibitor supplying step and the pH adjusting step; and
a crystallizing step of supplying seed crystals of gypsum to the concentrated water so that gypsum is crystallized from the concentrated water; and
an upstream side precipitating step of precipitating at least calcium carbonate from the water so that the concentration of the calcium carbonate in the water is reduced, before the scale inhibitor supplying step and the pH adjusting step.

2. The water treatment process according to claim 1 , comprising, after the crystallizing step, a downstream side demineralizing step of performing separation into concentrated water and treated water, and recovering the separated treated water.

3. The water treatment process according to claim 2 , wherein moisture is evaporated from the concentrated water in the downstream side demineralizing step, so that a solid in the concentrated water is recovered.

4. The water treatment process according to claim 1 , comprising a deaerating step of removing CO 2 from the water before the upstream side precipitating step or after the upstream side precipitating step and before the scale inhibitor supplying step and the pH adjusting step.

5. The water treatment process according to claim 1 ,
wherein the water contains metal ions; and
wherein the process comprises a precipitating step of precipitating at least one of calcium carbonate and a metal compound so that the concentration of at least one of the calcium carbonate and the metal ions is reduced from the concentrated water, after the crystallizing step.

6. The water treatment process according to claim 5 , wherein at least one of seed crystals of the silica and a precipitant for the silica is supplied to the concentrated water in the precipitating step.

7. The water treatment process according to claim 6 , wherein, when the water contains Mg 2+ ions, the amount of the precipitant for the silica to be supplied is adjusted according to the concentration of the Mg 2+ ions.

8. The water treatment process according to claim 5 ,
wherein, when the water contains Mg 2+ ions, the concentrated water in the precipitating step is adjusted to a pH of 10 or more at which a magnesium compound is deposited so that the concentration of the Mg 2+ ions is reduced, and
wherein, after the precipitating step, the concentrated water is adjusted to a pH of less than 10 at which the magnesium compound is soluble.

9. The water treatment process according to claim 1 ,
wherein, when the water contains Mg 2+ ions, the water in the upstream side precipitating step is adjusted to a pH of 10 or more at which a magnesium compound is deposited so that the concentration of the Mg 2+ ions is reduced, and
wherein, after the upstream side precipitating step, the water is adjusted to a pH of less than 10 at which the magnesium compound is soluble.

10. A water treatment system comprising:
a scale inhibitor supplying section that supplies a calcium scale inhibitor which is a scale inhibitor for inhibiting the deposition of a scale containing calcium to water containing Ca 2+ ions, SO 4 2− ions, carbonate ions and silica;
a pH adjusting section that supplies a pH adjuster to the water to adjust the pH of the water to 10 or more such that the silica is soluble in the water;
a demineralizing section that is positioned on a downstream side of the scale inhibitor supplying section and the pH adjusting section and separates the water into concentrated water in which the Ca 2+ ions, the SO 4 2− ions, the carbonate ions and the silica are concentrated and treated water;
a crystallizing section including a crystallizing tank that is positioned on a downstream side of the demineralizing section and crystallizes gypsum from the concentrated water and a seed crystal supplying section that supplies seed crystals of gypsum to the crystallizing tank; and
an upstream side precipitating section, on an upstream side of the scale inhibitor supplying section and the pH adjusting section, that precipitates at least calcium carbonate from the water so that the concentration of the calcium carbonate in the water is reduced.

11. The water treatment system according to claim 10 , comprising, on a downstream side of the crystallizing section, a downstream side demineralizing section that separates the concentrated water discharged from the crystallizing section into concentrated water and treated water.

12. The water treatment system according to claim 11 , comprising, on a downstream side of the concentrated water in the downstream side demineralizing section, an evaporator that evaporates moisture from the concentrated water to recover the solids in the concentrated water.

13. The water treatment system according to claim 10 , comprising a deaerating section that removes CO 2 from the water on an upstream side of the upstream side precipitating section or on a downstream side of the upstream side precipitating section and on an upstream side of the scale inhibitor supplying section and the pH adjusting section.

14. The water treatment system according to claim 10 ,
wherein the water contains metal ions; and
wherein the system comprises, on a downstream side of the crystallizing section, a precipitating section that precipitates at least one of calcium carbonate and a metal compound so that the concentration of at least one of the calcium carbonate and the metal ions in the concentrated water is reduced.

15. The water treatment system according to claim 14 , wherein at least one of seed crystals of the silica and a precipitant for the silica is supplied to the precipitating section.

16. The water treatment system according to claim 15 , wherein, when the water contains Mg 2+ ions, the amount of the precipitant for the silica to be supplied is adjusted according to the concentration of the Mg 2+ ions in the precipitating section.

17. The water treatment system according to claim 14 , wherein, when the water contains Mg 2+ ions, the concentrated water in the precipitating section is adjusted to a pH of 10 or more at which a magnesium compound is deposited so that the concentration of the Mg 2+ ions is reduced, and
wherein, on a downstream side of the precipitating section, the concentrated water is adjusted to a pH of less than 10 at which the magnesium compound is soluble.

18. The water treatment system according to claim 10 ,
wherein, when the water contains Mg 2+ ions, the water to be treated in the upstream side precipitating section is adjusted to a pH of 10 or more at which a magnesium compound is deposited so that the concentration of the Mg 2+ ions is reduced, and
wherein, on a downstream side of the upstream side precipitating section, the water is adjusted to a pH of less than 10 at which the magnesium compound is soluble.

Assignees

• Mitsubishi Heavy Ind Ltd

Inventors

• Eda Masayuki
• Okino Susumu
• Yoshiyama Ryuji
• Sakurai Hideaki
• Ukai Nobuyuki
• Suzuki Hideo
• Nakashoji Hiroshi
• Yoshioka Shigeru

Classifications

• B01D2311/18

  pH control · CPC title

• C02F1/52 Primary

  by flocculation or precipitation of suspended impurities {(C02F1/463 takes precedence)} · CPC title

• C02F5/10

  using organic substances · CPC title

• B01D61/42

  Electrodialysis; Electro-osmosis {; Electro-ultrafiltration; Membrane capacitive deionization} · CPC title

• B01D2311/04

  Specific process operations in the feed stream; Feed pretreatment · CPC title