Porous silicon particulates with micropores and mesopores within macropores

Patent metadata

Field	Value
Publication number	US-9947918-B2
Application number	US-201615147567-A
Country	US
Kind code	B2
Filing date	May 5, 2016
Priority date	Jan 7, 2013
Publication date	Apr 17, 2018
Grant date	Apr 17, 2018

Abstract

Embodiments of the present disclosure pertain to porous silicon particulates and anode materials that contain them. In some embodiments, each of the porous silicon particulates include a plurality of macropores, mesopores and micropores such that the micropores and mesopores are within the macropores. The porous silicon particulates also contain: a coating associated with the porous silicon particulates; and a binding material associated with the porous silicon particulates. The binding material can include binders, carbon materials, polymers, metals, additives, carbohydrates, and combinations thereof.

First claim

What is claimed is:

1. An anode material comprising:
porous silicon particulates,
wherein each of the porous silicon particulates comprise a plurality of macropores, mesopores and micropores,
wherein the micropores and mesopores are within the macropores, and
wherein the micropores and mesopores within the macropores provide a textured surface on the silicon particulates;

a coating associated with the porous silicon particulates; and
a binding material associated with the porous silicon particulates, wherein the binding material is selected from the group consisting of carbon materials, polymers, metals, carbohydrates, and combinations thereof.

2. The anode material of claim 1 , wherein the coating comprises a metal coating.

3. The anode material of claim 2 , wherein the metal is selected from the group consisting of silver, copper, chromium, gold, aluminum, tantalum, lead, zinc, silicon, and combinations thereof.

4. The anode material of claim 2 , wherein the metal is silver.

5. The anode material of claim 1 , wherein the binding material comprises a polymer selected from the group consisting of polyacrylonitrile (PAN), pyrolyzed polyacrylonitrile (PPAN), polyvinylidene difluoride (PVDF), polyacrylic acid (PAA), carboxymethyl cellulose (CMC), and combinations thereof.

6. The anode material of claim 1 , wherein the binding material comprises carbonized polyacrylonitrile.

7. The anode material of claim 1 , wherein the plurality of pores comprise hierarchical pores.

8. The anode material of claim 1 , wherein the porous silicon particulates have thicknesses ranging from about 10 micrometers to about 200 micrometers.

9. The anode material of claim 1 , wherein the porous silicon particulates comprise pores that span at least 50% of a thickness of the porous silicon particulates.

10. The anode material of claim 1 , wherein the porous silicon particulates comprise pores that span an entire thickness of the porous silicon particulates.

11. The anode material of claim 1 , wherein the porous silicon particulates comprise diameters from about 1 μm to about 50 μm.

12. The anode material of claim 1 , wherein the anode material has a discharge capacity of at least about 600 mAh/g over at least 50 cycles.

13. The anode material of claim 1 , wherein the anode material has a discharge capacity of at least about 1000 mAh/g over at least 50 cycles.

14. The anode material of claim 1 , wherein the anode material has a Coulombic efficiency of at least about 90% over at least 50 cycles.

15. The anode material of claim 1 , wherein the anode material is utilized as part of a lithium ion battery.

Assignees

• Univ Rice William M
• Lockheed Corp

Inventors

• Biswal Sibani Lisa
• Wong Michael S
• Thakur Madhuri
• Sinsabaugh Steven L

Classifications

• H01M2004/027

  Negative electrodes · CPC title

• C01P2006/16

  Pore diameter · CPC title

• C25F3/12

  of semiconducting materials · CPC title

• H01M4/1395

  of electrodes based on metals, Si or alloys · CPC title

• H01M10/052

  Li-accumulators · CPC title