Cathode active material for non-aqueous electrolyte secondary battery manufacturing method thereof, and non-aqueous electrolyte secondary battery

Patent metadata

Field	Value
Publication number	US-9947916-B2
Application number	US-201113577670-A
Country	US
Kind code	B2
Filing date	Feb 9, 2011
Priority date	Feb 9, 2010
Publication date	Apr 17, 2018
Grant date	Apr 17, 2018

Abstract

A non-aqueous electrolyte secondary battery is provided that has both good safety and durability characteristics while at the same time has high charge/discharge capacity. The cathode active material for a non-aqueous electrolyte secondary battery of the present invention is a lithium nickel composite oxide to which at least two or more kinds of metal elements including aluminum are added, and comprises secondary particles that are composed of fine secondary particles having an average particle size of 2 μm to 4 μm, and rough secondary particles having an average particle size of 6 μm to 15 μm, with an overall average particle size of 5 μm to 15 μm; where the aluminum content of fine secondary particles (metal mole ratio: SA) is greater than the aluminum content of rough secondary particles (metal mole ratio: LA), and preferably the aluminum concentration ratio (SA/LA) is within the range 1.2 to 2.6.

First claim

What is claimed is:

1. A cathode active material for a non-aqueous electrolyte secondary battery that is a lithium nickel composite oxide represented by the general formula: Li w Ni 1-x-y-z Co x Al y M z O 2 (M is at least one kind of element selected from the group of Mn, Ti, Ca, Mg, Nb, Si, Zr and W (Tungsten), and 0.99≤w≤1.10, 0.05≤x≤0.20, 0.035≤y≤0.1, 0≤z≤0.01), and the lithium nickel composite oxide comprising secondary particles composed of fine secondary particles having an average particle size of 2 μm to 4 μm and rough secondary particles having an average particle size of 6 μm to 9 μm, with the secondary particles having an overall average particle size of 5 μm to 15 μm,
wherein a particle size distribution of the fine secondary particles according to laser diffraction scattering measurement is in a range of 0.5 μm to 6 μm, and a particle size distribution of the rough secondary particles according to the laser diffraction scattering measurement is in a range of 3 μm to 9 μm,
wherein a ratio of aluminum content of the fine secondary particles, expressed as a metal molar ratio representing the amount of aluminum with respect to the total amount of metal other than lithium included in the fine secondary particles, to aluminum content of the rough secondary particles, expressed as a metal molar ratio representing the amount of aluminum with respect to the total amount of metal other than lithium included in the rough secondary particles, is within a range of 1.12 to 2.6, and
wherein a volume ratio of mixed fine secondary particles is 1% to 4% by volume with respect to the overall lithium nickel composite oxide.

2. The cathode active material for a non-aqueous electrolyte secondary battery according to claim 1 , wherein the ratio is within a range of 1.2 to 2.6.

3. The cathode active material for a non-aqueous electrolyte secondary battery according to claim 1 , wherein the value “y” of composition ratio of Al is within a range of 0.039 to 0.1.

4. The cathode active material for a non-aqueous electrolyte secondary battery according to claim 1 , wherein the value “x” of composition ratio of Co is within a range of 0.05 to 0.151.

5. A non-aqueous electrolyte secondary battery that uses the cathode active material for a non-aqueous electrolyte secondary battery according to claim 1 as a cathode material thereof.

Assignees

• Oda Syuhei
• Toya Hiroyuki
• Kase Katsuya
• Oyama Yutaka
• Sumitomo Metal Mining Co
• Toyota Motor Co Ltd

Inventors

• Oda Syuhei
• Toya Hiroyuki
• Kase Katsuya
• Oyama Yutaka

Classifications

• H01B1/08

  oxides · CPC title

• C01P2006/40

  Electric properties · CPC title

• C01P2004/61

  Micrometer sized, i.e. from 1-100 micrometer · CPC title

• C01P2004/53

  bimodal size distribution · CPC title

• C01G53/42

  containing alkali metals, e.g. LiNiO2 · CPC title